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Article: Facile complexation of 1,1′-bis(diphenylphosphino) ruthenocene (dppr) to ruthenium(II) - Simple entry to stable bimetallic ruthenoruthenocenyl system

TitleFacile complexation of 1,1′-bis(diphenylphosphino) ruthenocene (dppr) to ruthenium(II) - Simple entry to stable bimetallic ruthenoruthenocenyl system
Authors
KeywordsGroup 8
Ruthenium
Ruthenecene
Phosphine
Heterobimetallics
Carbonyl
Issue Date1997
Citation
Journal of Organometallic Chemistry, 1997, v. 527, n. 1-2, p. 133-136 How to Cite?
AbstractPhosphine exchange occurs rapidly between RuCl2(PPh3)n (n = 3, 4) and Ru(C5H4PPh2)2 (dppr) at room temperature to give RuCl2(dppr)(PPh3), 1. Triphenylphosphine is more substitutionally labile than dppr in 1; selective phosphine substitution of 1 with CO and CH3CN gives [RuCl2(CO)(dppr)] and two geometric isomers of [RuCl2(NCCH3)2(dppr)] respectively.
Persistent Identifierhttp://hdl.handle.net/10722/219426
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorWei, Bing-
dc.contributor.authorLi, Sihai-
dc.contributor.authorLee, Hian Kee-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:02Z-
dc.date.available2015-09-23T02:57:02Z-
dc.date.issued1997-
dc.identifier.citationJournal of Organometallic Chemistry, 1997, v. 527, n. 1-2, p. 133-136-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219426-
dc.description.abstractPhosphine exchange occurs rapidly between RuCl2(PPh3)n (n = 3, 4) and Ru(C5H4PPh2)2 (dppr) at room temperature to give RuCl2(dppr)(PPh3), 1. Triphenylphosphine is more substitutionally labile than dppr in 1; selective phosphine substitution of 1 with CO and CH3CN gives [RuCl2(CO)(dppr)] and two geometric isomers of [RuCl2(NCCH3)2(dppr)] respectively.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectGroup 8-
dc.subjectRuthenium-
dc.subjectRuthenecene-
dc.subjectPhosphine-
dc.subjectHeterobimetallics-
dc.subjectCarbonyl-
dc.titleFacile complexation of 1,1′-bis(diphenylphosphino) ruthenocene (dppr) to ruthenium(II) - Simple entry to stable bimetallic ruthenoruthenocenyl system-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-0031564477-
dc.identifier.volume527-
dc.identifier.issue1-2-
dc.identifier.spage133-
dc.identifier.epage136-

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