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Article: Metalloporphyrin-catalyzed hydroxylation of cyclohexane with molecular oxygen

TitleMetalloporphyrin-catalyzed hydroxylation of cyclohexane with molecular oxygen
Authors
Issue Date1991
Citation
Journal of Molecular Catalysis, 1991, v. 70, n. 2, p. 247-257 How to Cite?
AbstractThe selective oxidation of cyclohexane to cyclohexanol and cyclohexanone was realized in the model system of cytochromes P-450 consisting of chlorotetraphenylporphyrinato-Mn(III), Fe(III) or Co(II) complexes, molecular oxygen and ascorbic acid as coreductant. The catalytic efficiency was found to be sensitive to the peripheral phenyl substitution pattern of the porphyrinato ring in the complexes. The effects of the metal centre, axial ligand [substrate]/[catalyst] ratio and pH of mixture were examined and discussed with reference to oxidation mechanism. © 1991.
Persistent Identifierhttp://hdl.handle.net/10722/219416
ISSN

 

DC FieldValueLanguage
dc.contributor.authorJi, Liang Nian-
dc.contributor.authorLiu, Min-
dc.contributor.authorHsieh, An Kong-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:01Z-
dc.date.available2015-09-23T02:57:01Z-
dc.date.issued1991-
dc.identifier.citationJournal of Molecular Catalysis, 1991, v. 70, n. 2, p. 247-257-
dc.identifier.issn0304-5102-
dc.identifier.urihttp://hdl.handle.net/10722/219416-
dc.description.abstractThe selective oxidation of cyclohexane to cyclohexanol and cyclohexanone was realized in the model system of cytochromes P-450 consisting of chlorotetraphenylporphyrinato-Mn(III), Fe(III) or Co(II) complexes, molecular oxygen and ascorbic acid as coreductant. The catalytic efficiency was found to be sensitive to the peripheral phenyl substitution pattern of the porphyrinato ring in the complexes. The effects of the metal centre, axial ligand [substrate]/[catalyst] ratio and pH of mixture were examined and discussed with reference to oxidation mechanism. © 1991.-
dc.languageeng-
dc.relation.ispartofJournal of Molecular Catalysis-
dc.titleMetalloporphyrin-catalyzed hydroxylation of cyclohexane with molecular oxygen-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/0304-5102(91)80166-Z-
dc.identifier.scopuseid_2-s2.0-0026405735-
dc.identifier.volume70-
dc.identifier.issue2-
dc.identifier.spage247-
dc.identifier.epage257-

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