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Article: {M3S2} heterometallic aggregates derived from Pt2(PPh3)4(μ-S)2: Structural analysis of [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) by X-ray single-crystal crystallography

Title{M3S2} heterometallic aggregates derived from Pt2(PPh3)4(μ-S)2: Structural analysis of [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) by X-ray single-crystal crystallography
Authors
KeywordsSulfide
Triangular
X-ray single-crystal crystallography
Aggregate
Carbon monoxide
Heterometallic
Platinum
Issue Date1999
Citation
Journal of Organometallic Chemistry, 1999, v. 575, n. 2, p. 223-231 How to Cite?
AbstractHeterometallic addition of d8 complexes of Pd(II), Pt(II), Rh(I) and Ir(I) to Pt2(PPh3)4(μ-S)2 results in triangular aggregates [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) characterized by 31P-NMR spectroscopy and X-ray single-crystal crystallography. They show a trigonal bipyramidal {MPt2S2} core with three d8 sq-planar metal atoms aligned at close proximity but without direct M-M bonds. Unlike their d10 counterparts [Ag(I) and Cu(I)], these aggregates resist desulfurization under ambient pressure of CO. © 1999 Elsevier Science S.A.
Persistent Identifierhttp://hdl.handle.net/10722/219403
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorLi, Zhaohui-
dc.contributor.authorLiu, Huang-
dc.contributor.authorMok, K. F.-
dc.contributor.authorBatsanov, Andrei S.-
dc.contributor.authorHoward, Judith A K-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:56:59Z-
dc.date.available2015-09-23T02:56:59Z-
dc.date.issued1999-
dc.identifier.citationJournal of Organometallic Chemistry, 1999, v. 575, n. 2, p. 223-231-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219403-
dc.description.abstractHeterometallic addition of d8 complexes of Pd(II), Pt(II), Rh(I) and Ir(I) to Pt2(PPh3)4(μ-S)2 results in triangular aggregates [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) characterized by 31P-NMR spectroscopy and X-ray single-crystal crystallography. They show a trigonal bipyramidal {MPt2S2} core with three d8 sq-planar metal atoms aligned at close proximity but without direct M-M bonds. Unlike their d10 counterparts [Ag(I) and Cu(I)], these aggregates resist desulfurization under ambient pressure of CO. © 1999 Elsevier Science S.A.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectSulfide-
dc.subjectTriangular-
dc.subjectX-ray single-crystal crystallography-
dc.subjectAggregate-
dc.subjectCarbon monoxide-
dc.subjectHeterometallic-
dc.subjectPlatinum-
dc.title{M3S2} heterometallic aggregates derived from Pt2(PPh3)4(μ-S)2: Structural analysis of [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) by X-ray single-crystal crystallography-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-0005824832-
dc.identifier.volume575-
dc.identifier.issue2-
dc.identifier.spage223-
dc.identifier.epage231-

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