File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Nitrato displacement in [Ag2(NO3)2(μ-dppf)2]. Molecular structure of a homoleptic dppf complex, [Ag2(μ-dppf)(dppf)2] (PF6)2 (dppf = 1,1′-bis(diphenylphosphino)ferrocene)

TitleNitrato displacement in [Ag2(NO3)2(μ-dppf)2]. Molecular structure of a homoleptic dppf complex, [Ag2(μ-dppf)(dppf)2] (PF6)2 (dppf = 1,1′-bis(diphenylphosphino)ferrocene)
Authors
KeywordsSilver
Nitrate
Ferrocene
Issue Date1994
Citation
Journal of Organometallic Chemistry, 1994, v. 464, n. 1, p. 113-119 How to Cite?
AbstractAddition of 1,1′-bis(diphenylphosphino)ferrocene (dppf) to AgNO3 or [Ag2(NO3)2(μ-dppf)2] at room temperature gives rise to a homoleptic dppf complex [Ag2(μ-dppf)(dppf)2]2+ 1. Single-crystal X-ray diffractometric analysis of its PF6 - salt revealed a dinuclear structure with dppf singly and symmetrically bridging two trigonal planar AgI centres each of which contains a chelating dppf. The chelate angle [105.6(2)°] is significantly more acute than the PAgP angles subtended between the chelate and the bridging ligands [127.2(2)°]. Complex 1 reacts further with dppf to yield a bis(chelate) complex [Ag(dppf)2](PF6). Metathetic reactions of [Ag2(NO3)2(μ-dppf)2] with Na+ or K+ salts of X- (X Cl, OCN, SCN, Et2NCS2) at room temperature readily give good yields of, respectively, [Ag(μ-Cl)(μ-dppf)]4, [Ag2(μ-NCO,N)2(μ-dppf)2], [Ag2(μ-SCN- S,N)2(dppf)2], and [Ag2(S2CNEt2)2(μ-dppf)2]. © 1994.
Persistent Identifierhttp://hdl.handle.net/10722/219398
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorNeo, Soh Ping-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorZhou, Zhong Yuan-
dc.contributor.authorMak, Thomas C W-
dc.date.accessioned2015-09-23T02:56:58Z-
dc.date.available2015-09-23T02:56:58Z-
dc.date.issued1994-
dc.identifier.citationJournal of Organometallic Chemistry, 1994, v. 464, n. 1, p. 113-119-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219398-
dc.description.abstractAddition of 1,1′-bis(diphenylphosphino)ferrocene (dppf) to AgNO3 or [Ag2(NO3)2(μ-dppf)2] at room temperature gives rise to a homoleptic dppf complex [Ag2(μ-dppf)(dppf)2]2+ 1. Single-crystal X-ray diffractometric analysis of its PF6 - salt revealed a dinuclear structure with dppf singly and symmetrically bridging two trigonal planar AgI centres each of which contains a chelating dppf. The chelate angle [105.6(2)°] is significantly more acute than the PAgP angles subtended between the chelate and the bridging ligands [127.2(2)°]. Complex 1 reacts further with dppf to yield a bis(chelate) complex [Ag(dppf)2](PF6). Metathetic reactions of [Ag2(NO3)2(μ-dppf)2] with Na+ or K+ salts of X- (X Cl, OCN, SCN, Et2NCS2) at room temperature readily give good yields of, respectively, [Ag(μ-Cl)(μ-dppf)]4, [Ag2(μ-NCO,N)2(μ-dppf)2], [Ag2(μ-SCN- S,N)2(dppf)2], and [Ag2(S2CNEt2)2(μ-dppf)2]. © 1994.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectSilver-
dc.subjectNitrate-
dc.subjectFerrocene-
dc.titleNitrato displacement in [Ag2(NO3)2(μ-dppf)2]. Molecular structure of a homoleptic dppf complex, [Ag2(μ-dppf)(dppf)2] (PF6)2 (dppf = 1,1′-bis(diphenylphosphino)ferrocene)-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/0022-328X(94)87018-7-
dc.identifier.scopuseid_2-s2.0-0001015432-
dc.identifier.volume464-
dc.identifier.issue1-
dc.identifier.spage113-
dc.identifier.epage119-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats