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Article: Facile reductive excision of sulfur from a {Pt2S2} core in [Pt2(PPh3)4(μ-S)2] to a {Pt2S} triangle by carbon monoxide

TitleFacile reductive excision of sulfur from a {Pt2S2} core in [Pt2(PPh3)4(μ-S)2] to a {Pt2S} triangle by carbon monoxide
Authors
KeywordsCarbonyl sulfide
Sulfide
Reductive carbonylation
Platinum
Desulfurization
Carbon monoxide
Issue Date1996
Citation
Journal of Organometallic Chemistry, 1996, v. 509, n. 1, p. 101-104 How to Cite?
AbstractA synthetic path is established in which [Pt2(CO)x(PPh3)4-x(μ-S)] (x = 0-2) can be prepared from [Pt2(PPh3)4(μ-S)2] under CO at low pressure whereby reductive desulfurization of a {Pt2 11S2} core gives way to a Pt-Pt bonded {Pt2 1S} triangle with extrusion of COS gas.
Persistent Identifierhttp://hdl.handle.net/10722/219395
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorChin, Choon Hong-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:56:58Z-
dc.date.available2015-09-23T02:56:58Z-
dc.date.issued1996-
dc.identifier.citationJournal of Organometallic Chemistry, 1996, v. 509, n. 1, p. 101-104-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219395-
dc.description.abstractA synthetic path is established in which [Pt2(CO)x(PPh3)4-x(μ-S)] (x = 0-2) can be prepared from [Pt2(PPh3)4(μ-S)2] under CO at low pressure whereby reductive desulfurization of a {Pt2 11S2} core gives way to a Pt-Pt bonded {Pt2 1S} triangle with extrusion of COS gas.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectCarbonyl sulfide-
dc.subjectSulfide-
dc.subjectReductive carbonylation-
dc.subjectPlatinum-
dc.subjectDesulfurization-
dc.subjectCarbon monoxide-
dc.titleFacile reductive excision of sulfur from a {Pt2S2} core in [Pt2(PPh3)4(μ-S)2] to a {Pt2S} triangle by carbon monoxide-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-0000964477-
dc.identifier.volume509-
dc.identifier.issue1-
dc.identifier.spage101-
dc.identifier.epage104-

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