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- Scopus: eid_2-s2.0-0000964477
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Article: Facile reductive excision of sulfur from a {Pt2S2} core in [Pt2(PPh3)4(μ-S)2] to a {Pt2S} triangle by carbon monoxide
Title | Facile reductive excision of sulfur from a {Pt2S2} core in [Pt2(PPh3)4(μ-S)2] to a {Pt2S} triangle by carbon monoxide |
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Authors | |
Keywords | Carbonyl sulfide Sulfide Reductive carbonylation Platinum Desulfurization Carbon monoxide |
Issue Date | 1996 |
Citation | Journal of Organometallic Chemistry, 1996, v. 509, n. 1, p. 101-104 How to Cite? |
Abstract | A synthetic path is established in which [Pt2(CO)x(PPh3)4-x(μ-S)] (x = 0-2) can be prepared from [Pt2(PPh3)4(μ-S)2] under CO at low pressure whereby reductive desulfurization of a {Pt2 11S2} core gives way to a Pt-Pt bonded {Pt2 1S} triangle with extrusion of COS gas. |
Persistent Identifier | http://hdl.handle.net/10722/219395 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Chin, Choon Hong | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2015-09-23T02:56:58Z | - |
dc.date.available | 2015-09-23T02:56:58Z | - |
dc.date.issued | 1996 | - |
dc.identifier.citation | Journal of Organometallic Chemistry, 1996, v. 509, n. 1, p. 101-104 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.uri | http://hdl.handle.net/10722/219395 | - |
dc.description.abstract | A synthetic path is established in which [Pt2(CO)x(PPh3)4-x(μ-S)] (x = 0-2) can be prepared from [Pt2(PPh3)4(μ-S)2] under CO at low pressure whereby reductive desulfurization of a {Pt2 11S2} core gives way to a Pt-Pt bonded {Pt2 1S} triangle with extrusion of COS gas. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Organometallic Chemistry | - |
dc.subject | Carbonyl sulfide | - |
dc.subject | Sulfide | - |
dc.subject | Reductive carbonylation | - |
dc.subject | Platinum | - |
dc.subject | Desulfurization | - |
dc.subject | Carbon monoxide | - |
dc.title | Facile reductive excision of sulfur from a {Pt2S2} core in [Pt2(PPh3)4(μ-S)2] to a {Pt2S} triangle by carbon monoxide | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.scopus | eid_2-s2.0-0000964477 | - |
dc.identifier.volume | 509 | - |
dc.identifier.issue | 1 | - |
dc.identifier.spage | 101 | - |
dc.identifier.epage | 104 | - |
dc.identifier.isi | WOS:A1996TW76900015 | - |
dc.identifier.issnl | 0022-328X | - |