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Article: Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4]

TitleDinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4]
Authors
KeywordsSulfido complexes
Crystal structure
Alkylation reactions
Platinum complexes
Thiolate complexes
Issue Date2010
Citation
Inorganica Chimica Acta, 2010, v. 363, n. 13, p. 3558-3568 How to Cite?
AbstractAlkylation reactions of the nucleophilic platinum(II) sulfide complex [Pt2(μ-S)2(PPh3)4] with functionalised alkylating agents have been investigated as a versatile synthetic route to dinuclear, cationic sulfide-thiolate complexes of the type [Pt 2(μ-S)(μ-SR)(PPh3)4]+, extending the range of thiolate complexes that can be prepared using this methodology. A wide range of functional groups can be incorporated, using appropriate alkylating agents, and include ketone, ester, amide, hydrazone, semicarbazone, thiosemicarbazone, oxime, guanidine, urea and thiourea groups. © 2010 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/219373
ISSN
2015 Impact Factor: 1.918
2015 SCImago Journal Rankings: 0.584

 

DC FieldValueLanguage
dc.contributor.authorUjam, Oguejiofo T.-
dc.contributor.authorDevoy, Sarah M.-
dc.contributor.authorHenderson, William-
dc.contributor.authorNicholson, Brian K.-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:56:55Z-
dc.date.available2015-09-23T02:56:55Z-
dc.date.issued2010-
dc.identifier.citationInorganica Chimica Acta, 2010, v. 363, n. 13, p. 3558-3568-
dc.identifier.issn0020-1693-
dc.identifier.urihttp://hdl.handle.net/10722/219373-
dc.description.abstractAlkylation reactions of the nucleophilic platinum(II) sulfide complex [Pt2(μ-S)2(PPh3)4] with functionalised alkylating agents have been investigated as a versatile synthetic route to dinuclear, cationic sulfide-thiolate complexes of the type [Pt 2(μ-S)(μ-SR)(PPh3)4]+, extending the range of thiolate complexes that can be prepared using this methodology. A wide range of functional groups can be incorporated, using appropriate alkylating agents, and include ketone, ester, amide, hydrazone, semicarbazone, thiosemicarbazone, oxime, guanidine, urea and thiourea groups. © 2010 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofInorganica Chimica Acta-
dc.subjectSulfido complexes-
dc.subjectCrystal structure-
dc.subjectAlkylation reactions-
dc.subjectPlatinum complexes-
dc.subjectThiolate complexes-
dc.titleDinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4]-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.ica.2010.07.011-
dc.identifier.scopuseid_2-s2.0-77957706600-
dc.identifier.volume363-
dc.identifier.issue13-
dc.identifier.spage3558-
dc.identifier.epage3568-

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