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Article: Suzuki coupling catalyzed by a homoleptic Pd(I)-Pd(I) solvento complex

TitleSuzuki coupling catalyzed by a homoleptic Pd(I)-Pd(I) solvento complex
Authors
KeywordsCatalyst
Suzuki coupling
Palladium
Homoleptic
Dinuclear
Issue Date2007
Citation
Journal of Organometallic Chemistry, 2007, v. 692, n. 26, p. 5690-5696 How to Cite?
AbstractThe PdI-PdI bonded complex [Pd2(CH3CN)6][SbF6] 2 is catalytically active towards Suzuki cross-coupling reactions of aryl bromides or chlorides with various arylboronic acids under mild conditions giving good to excellent yields. Its performance is enhanced by the introduction of stoichiometric or limited phosphines. The effects of different ligands, metal oxidation states [Pd(II), Pd(I) Pd(0)], bases and solvents have been examined. © 2007 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/219367
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorHan, Xiaoyan-
dc.contributor.authorWeng, Zhiqiang-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:56:54Z-
dc.date.available2015-09-23T02:56:54Z-
dc.date.issued2007-
dc.identifier.citationJournal of Organometallic Chemistry, 2007, v. 692, n. 26, p. 5690-5696-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219367-
dc.description.abstractThe PdI-PdI bonded complex [Pd2(CH3CN)6][SbF6] 2 is catalytically active towards Suzuki cross-coupling reactions of aryl bromides or chlorides with various arylboronic acids under mild conditions giving good to excellent yields. Its performance is enhanced by the introduction of stoichiometric or limited phosphines. The effects of different ligands, metal oxidation states [Pd(II), Pd(I) Pd(0)], bases and solvents have been examined. © 2007 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectCatalyst-
dc.subjectSuzuki coupling-
dc.subjectPalladium-
dc.subjectHomoleptic-
dc.subjectDinuclear-
dc.titleSuzuki coupling catalyzed by a homoleptic Pd(I)-Pd(I) solvento complex-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.jorganchem.2007.09.029-
dc.identifier.scopuseid_2-s2.0-36348973933-
dc.identifier.volume692-
dc.identifier.issue26-
dc.identifier.spage5690-
dc.identifier.epage5696-

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