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Article: Metal scrambling in the trinuclear Pt-Se-M (M=Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of two Pt-Se-Pt hexafluorophosphine complexes (see abstract) with the cycloocta-1,5-diene ligand (cod)

TitleMetal scrambling in the trinuclear Pt-Se-M (M=Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of two Pt-Se-Pt hexafluorophosphine complexes (see abstract) with the cycloocta-1,5-diene ligand (cod)
Authors
Issue Date2002
Citation
Inorganic Chemistry, 2002, v. 41, n. 5, p. 1194-1198 How to Cite?
AbstractPt2(μ-Se)2(PPh3)4 reacts with PtCl2(cod) to give {Pt2(μ3-Se)2(PPh3) 4[Pt(cod)]}2+ and an unexpected cod-rich product that arises from metal scrambling, viz. {Pt(μ3-Se)2(PPh3)2[Pt(cod)] 2}2+. The formation of these species was detected and followed by electrospray mass spectrometry (ESMS) and subsequently verified by batch synthesis and crystallographic characterization. Other metal-scrambled aggregate products were successfully detected.
Persistent Identifierhttp://hdl.handle.net/10722/219365
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873

 

DC FieldValueLanguage
dc.contributor.authorYeo, Jeremy S L-
dc.contributor.authorVittal, Jagadese J.-
dc.contributor.authorHenderson, William-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:56:53Z-
dc.date.available2015-09-23T02:56:53Z-
dc.date.issued2002-
dc.identifier.citationInorganic Chemistry, 2002, v. 41, n. 5, p. 1194-1198-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10722/219365-
dc.description.abstractPt2(μ-Se)2(PPh3)4 reacts with PtCl2(cod) to give {Pt2(μ3-Se)2(PPh3) 4[Pt(cod)]}2+ and an unexpected cod-rich product that arises from metal scrambling, viz. {Pt(μ3-Se)2(PPh3)2[Pt(cod)] 2}2+. The formation of these species was detected and followed by electrospray mass spectrometry (ESMS) and subsequently verified by batch synthesis and crystallographic characterization. Other metal-scrambled aggregate products were successfully detected.-
dc.languageeng-
dc.relation.ispartofInorganic Chemistry-
dc.titleMetal scrambling in the trinuclear Pt-Se-M (M=Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of two Pt-Se-Pt hexafluorophosphine complexes (see abstract) with the cycloocta-1,5-diene ligand (cod)-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic010905t-
dc.identifier.pmid11874355-
dc.identifier.scopuseid_2-s2.0-0037060802-
dc.identifier.volume41-
dc.identifier.issue5-
dc.identifier.spage1194-
dc.identifier.epage1198-

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