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Article: [Pt2(PPh3)4(μ-S)2] as a metalloligand towards main-group Lewis acids. Evidence of a sulfide-linked {BiPt4} aggregate by 1/2 addition on BiCl3

Title[Pt2(PPh3)4(μ-S)2] as a metalloligand towards main-group Lewis acids. Evidence of a sulfide-linked {BiPt4} aggregate by 1/2 addition on BiCl3
Authors
Issue Date1996
Citation
Polyhedron, 1996, v. 15, n. 10, p. 1737-1741 How to Cite?
AbstractChloride dissociation of [(PPh3)4Pt2(μ3-S) 2BiCl3] (2) followed by addition of [Pt2(PPh3)4(μ-S)2] (1) gave a bis-bidentate complex [{(PPh3)4Pt2(μ3-S) 2}2BiCl2]Cl (4), which regenerated 2 in CH2Cl2. Complex 4 represents the first example of a main-group complex incorporating two bulky thio ligands of 1.
Persistent Identifierhttp://hdl.handle.net/10722/219356
ISSN
2015 Impact Factor: 2.108
2015 SCImago Journal Rankings: 0.592

 

DC FieldValueLanguage
dc.contributor.authorZhou, Meisheng-
dc.contributor.authorLeung, Pak Hing-
dc.contributor.authorMok, K. F.-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:56:52Z-
dc.date.available2015-09-23T02:56:52Z-
dc.date.issued1996-
dc.identifier.citationPolyhedron, 1996, v. 15, n. 10, p. 1737-1741-
dc.identifier.issn0277-5387-
dc.identifier.urihttp://hdl.handle.net/10722/219356-
dc.description.abstractChloride dissociation of [(PPh3)4Pt2(μ3-S) 2BiCl3] (2) followed by addition of [Pt2(PPh3)4(μ-S)2] (1) gave a bis-bidentate complex [{(PPh3)4Pt2(μ3-S) 2}2BiCl2]Cl (4), which regenerated 2 in CH2Cl2. Complex 4 represents the first example of a main-group complex incorporating two bulky thio ligands of 1.-
dc.languageeng-
dc.relation.ispartofPolyhedron-
dc.title[Pt2(PPh3)4(μ-S)2] as a metalloligand towards main-group Lewis acids. Evidence of a sulfide-linked {BiPt4} aggregate by 1/2 addition on BiCl3-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/0277-5387(95)00519-6-
dc.identifier.scopuseid_2-s2.0-0003013250-
dc.identifier.volume15-
dc.identifier.issue10-
dc.identifier.spage1737-
dc.identifier.epage1741-

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