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- Publisher Website: 10.1021/ic700850e
- Scopus: eid_2-s2.0-34948890498
- PMID: 17705369
- WOS: WOS:000249371500004
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Article: Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands
| Title | Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands |
|---|---|
| Authors | |
| Issue Date | 2007 |
| Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic |
| Citation | Inorganic Chemistry, 2007, v. 46 n. 19, p. 7695-7697 How to Cite? |
| Abstract | The coordination chemistry of the N-substituted arylamido ligands [N(R)(C6H3R'2-2,6)] [R = SiMe3, R' = Me (L1); R = CH2But, R' = Pri (L2)] toward FeII and CoII ions was studied. The monoamido complexes [M(L1)(Cl)(tmeda)] [M = Fe (1), Co (2)] react readily with MeLi, affording the mononuclear, paramagnetic iron(II) and cobalt(II) methyl-arylamido complexes [M(L1)(Me)(tmeda)] [M = Fe (3), Co (4)]. Treatment of 2:1 [Li(L2)(THF)2]/FeCl2 affords the unusual two-coordinate iron(II) bis(arylamide) [Fe(L2)2] (5). |
| Persistent Identifier | http://hdl.handle.net/10722/192351 |
| ISSN | 2021 Impact Factor: 5.436 2020 SCImago Journal Rankings: 1.348 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Au Yeung, HY | - |
| dc.contributor.author | Chung, HL | - |
| dc.contributor.author | Lam, CK | - |
| dc.contributor.author | Wong, WY | - |
| dc.contributor.author | Hung, KL | - |
| dc.date.accessioned | 2013-10-24T08:00:27Z | - |
| dc.date.available | 2013-10-24T08:00:27Z | - |
| dc.date.issued | 2007 | - |
| dc.identifier.citation | Inorganic Chemistry, 2007, v. 46 n. 19, p. 7695-7697 | - |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/192351 | - |
| dc.description.abstract | The coordination chemistry of the N-substituted arylamido ligands [N(R)(C6H3R'2-2,6)] [R = SiMe3, R' = Me (L1); R = CH2But, R' = Pri (L2)] toward FeII and CoII ions was studied. The monoamido complexes [M(L1)(Cl)(tmeda)] [M = Fe (1), Co (2)] react readily with MeLi, affording the mononuclear, paramagnetic iron(II) and cobalt(II) methyl-arylamido complexes [M(L1)(Me)(tmeda)] [M = Fe (3), Co (4)]. Treatment of 2:1 [Li(L2)(THF)2]/FeCl2 affords the unusual two-coordinate iron(II) bis(arylamide) [Fe(L2)2] (5). | - |
| dc.language | eng | - |
| dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | - |
| dc.relation.ispartof | Inorganic Chemistry | - |
| dc.title | Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands | en_US |
| dc.type | Article | en_US |
| dc.identifier.email | Au Yeung, HY: hoyuay@hku.hk | - |
| dc.identifier.doi | 10.1021/ic700850e | - |
| dc.identifier.pmid | 17705369 | - |
| dc.identifier.scopus | eid_2-s2.0-34948890498 | - |
| dc.identifier.volume | 46 | - |
| dc.identifier.issue | 19 | - |
| dc.identifier.spage | 7695 | - |
| dc.identifier.epage | 7697 | - |
| dc.identifier.isi | WOS:000249371500004 | - |
| dc.publisher.place | United States | - |
| dc.identifier.issnl | 0020-1669 | - |