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Article: Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands

TitleUnusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands
Authors
Issue Date2007
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2007, v. 46 n. 19, p. 7695-7697 How to Cite?
AbstractThe coordination chemistry of the N-substituted arylamido ligands [N(R)(C6H3R'2-2,6)] [R = SiMe3, R' = Me (L1); R = CH2But, R' = Pri (L2)] toward FeII and CoII ions was studied. The monoamido complexes [M(L1)(Cl)(tmeda)] [M = Fe (1), Co (2)] react readily with MeLi, affording the mononuclear, paramagnetic iron(II) and cobalt(II) methyl-arylamido complexes [M(L1)(Me)(tmeda)] [M = Fe (3), Co (4)]. Treatment of 2:1 [Li(L2)(THF)2]/FeCl2 affords the unusual two-coordinate iron(II) bis(arylamide) [Fe(L2)2] (5).
Persistent Identifierhttp://hdl.handle.net/10722/192351
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorAu Yeung, HY-
dc.contributor.authorChung, HL-
dc.contributor.authorLam, CK-
dc.contributor.authorWong, WY-
dc.contributor.authorHung, KL-
dc.date.accessioned2013-10-24T08:00:27Z-
dc.date.available2013-10-24T08:00:27Z-
dc.date.issued2007-
dc.identifier.citationInorganic Chemistry, 2007, v. 46 n. 19, p. 7695-7697-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10722/192351-
dc.description.abstractThe coordination chemistry of the N-substituted arylamido ligands [N(R)(C6H3R'2-2,6)] [R = SiMe3, R' = Me (L1); R = CH2But, R' = Pri (L2)] toward FeII and CoII ions was studied. The monoamido complexes [M(L1)(Cl)(tmeda)] [M = Fe (1), Co (2)] react readily with MeLi, affording the mononuclear, paramagnetic iron(II) and cobalt(II) methyl-arylamido complexes [M(L1)(Me)(tmeda)] [M = Fe (3), Co (4)]. Treatment of 2:1 [Li(L2)(THF)2]/FeCl2 affords the unusual two-coordinate iron(II) bis(arylamide) [Fe(L2)2] (5).-
dc.languageeng-
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic-
dc.relation.ispartofInorganic Chemistry-
dc.titleUnusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligandsen_US
dc.typeArticleen_US
dc.identifier.emailAu Yeung, HY: hoyuay@hku.hk-
dc.identifier.doi10.1021/ic700850e-
dc.identifier.pmid17705369-
dc.identifier.scopuseid_2-s2.0-34948890498-
dc.identifier.volume46-
dc.identifier.issue19-
dc.identifier.spage7695-
dc.identifier.epage7697-
dc.identifier.isiWOS:000249371500004-
dc.publisher.placeUnited States-

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