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- Publisher Website: 10.1016/j.memsci.2011.07.013
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Article: Synthesis of high flux forward osmosis membranes by chemically crosslinked layer-by-layer polyelectrolytes
Title | Synthesis of high flux forward osmosis membranes by chemically crosslinked layer-by-layer polyelectrolytes |
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Authors | |
Keywords | Chemical Crosslinking Forward Osmosis (Fo) Internal Concentration Polarization Layer-By-Layer (Lbl) Assembly Polyelectrolyte Deposition |
Issue Date | 2011 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/memsci |
Citation | Journal Of Membrane Science, 2011, v. 381 n. 1-2, p. 74-80 How to Cite? |
Abstract | Forward osmosis (FO) membranes were successfully fabricated using layer-by-layer (LbL) assembly of poly(allylamine hydrochloride) (PAH) and poly(sodium 4-styrene-sulfonate) (PSS) on a porous polyacrylonitrile (PAN) substrate. In addition, chemical crosslinking of LbL polyelectrolyte layers was performed with glutaraldehyde (GA). The resultant crosslinked (the xLbL series) and non-crosslinked (the LbL series) membranes were characterized in terms of the substrate morphology and structure, the separation layer water permeability and salt rejection, and the FO water flux and solute flux performance. Both LbL and xLbL membranes had relatively high water permeability (∼ or >7.0L/m 2hbar). On the other hand, the crosslinked xLbL membranes showed better and more stable MgCl 2 rejection, leading to a relatively low FO solute reverse transport (the solute flux over water flux ratio<6mM regardless of draw solution (DS) concentration and membrane orientation). High FO water fluxes were achieved for both crosslinked and non-crosslinked membranes, where a thin substrate with finger-like pores were adopted to minimize internal concentration polarization in the porous support layer. The crosslinked membrane xLbL3 (with 3 PAH/PSS deposition layers) had an FO water flux of ∼100L/m 2h in the active-layer-facing-DS orientation using a 2 or 3M MgCl 2 draw solution and distilled water as the feed water, which clearly demonstrates the potential of LbL membranes for high flux FO applications. © 2011 Elsevier B.V. |
Persistent Identifier | http://hdl.handle.net/10722/185407 |
ISSN | 2023 Impact Factor: 8.4 2023 SCImago Journal Rankings: 1.848 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Qiu, C | en_US |
dc.contributor.author | Qi, S | en_US |
dc.contributor.author | Tang, CY | en_US |
dc.date.accessioned | 2013-07-30T07:32:19Z | - |
dc.date.available | 2013-07-30T07:32:19Z | - |
dc.date.issued | 2011 | en_US |
dc.identifier.citation | Journal Of Membrane Science, 2011, v. 381 n. 1-2, p. 74-80 | en_US |
dc.identifier.issn | 0376-7388 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/185407 | - |
dc.description.abstract | Forward osmosis (FO) membranes were successfully fabricated using layer-by-layer (LbL) assembly of poly(allylamine hydrochloride) (PAH) and poly(sodium 4-styrene-sulfonate) (PSS) on a porous polyacrylonitrile (PAN) substrate. In addition, chemical crosslinking of LbL polyelectrolyte layers was performed with glutaraldehyde (GA). The resultant crosslinked (the xLbL series) and non-crosslinked (the LbL series) membranes were characterized in terms of the substrate morphology and structure, the separation layer water permeability and salt rejection, and the FO water flux and solute flux performance. Both LbL and xLbL membranes had relatively high water permeability (∼ or >7.0L/m 2hbar). On the other hand, the crosslinked xLbL membranes showed better and more stable MgCl 2 rejection, leading to a relatively low FO solute reverse transport (the solute flux over water flux ratio<6mM regardless of draw solution (DS) concentration and membrane orientation). High FO water fluxes were achieved for both crosslinked and non-crosslinked membranes, where a thin substrate with finger-like pores were adopted to minimize internal concentration polarization in the porous support layer. The crosslinked membrane xLbL3 (with 3 PAH/PSS deposition layers) had an FO water flux of ∼100L/m 2h in the active-layer-facing-DS orientation using a 2 or 3M MgCl 2 draw solution and distilled water as the feed water, which clearly demonstrates the potential of LbL membranes for high flux FO applications. © 2011 Elsevier B.V. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/memsci | en_US |
dc.relation.ispartof | Journal of Membrane Science | en_US |
dc.subject | Chemical Crosslinking | en_US |
dc.subject | Forward Osmosis (Fo) | en_US |
dc.subject | Internal Concentration Polarization | en_US |
dc.subject | Layer-By-Layer (Lbl) Assembly | en_US |
dc.subject | Polyelectrolyte Deposition | en_US |
dc.title | Synthesis of high flux forward osmosis membranes by chemically crosslinked layer-by-layer polyelectrolytes | en_US |
dc.type | Article | en_US |
dc.identifier.email | Tang, CY: tangc@hku.hk | en_US |
dc.identifier.authority | Tang, CY=rp01765 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/j.memsci.2011.07.013 | en_US |
dc.identifier.scopus | eid_2-s2.0-80052028969 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-80052028969&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 381 | en_US |
dc.identifier.issue | 1-2 | en_US |
dc.identifier.spage | 74 | en_US |
dc.identifier.epage | 80 | en_US |
dc.identifier.isi | WOS:000295564600008 | - |
dc.publisher.place | Netherlands | en_US |
dc.identifier.scopusauthorid | Qiu, C=36019493600 | en_US |
dc.identifier.scopusauthorid | Qi, S=48461816800 | en_US |
dc.identifier.scopusauthorid | Tang, CY=35489259800 | en_US |
dc.identifier.issnl | 0376-7388 | - |