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- Publisher Website: 10.1055/s-0032-1317322
- Scopus: eid_2-s2.0-84867530184
- WOS: WOS:000311492100006
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Article: Stereoselective Intramolecular Carbene C–H Insertion Catalyzed by Rhodium(III) Porphyrin Complexes
Title | Stereoselective Intramolecular Carbene C–H Insertion Catalyzed by Rhodium(III) Porphyrin Complexes |
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Authors | |
Keywords | Rhodium porphyrin Carbene C–H insertion Stereoselectivity Intramolecular cyclization Lactams |
Issue Date | 2012 |
Publisher | Georg Thieme Verlag. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml |
Citation | Synlett, 2012, v. 23 n. 19, p. 2753-2757 How to Cite? |
Abstract | Rhodium(III) porphyrin complexes [Rh(Por)Me] are catalytically active towards stereoselective intramolecular carbene C–H insertions of α-diazoacetamides to give cis-β-lactams or trans-γ-lactams in yields up to 99% with regioselectivities up to 100% and cis/trans ratios up to 83:17 for β-lactams. |
Persistent Identifier | http://hdl.handle.net/10722/184472 |
ISSN | 2023 Impact Factor: 1.7 2023 SCImago Journal Rankings: 0.450 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Lo, VKY | - |
dc.contributor.author | Thu, HY | - |
dc.contributor.author | Chan, YM | - |
dc.contributor.author | Lam, TL | - |
dc.contributor.author | Yu, WY | - |
dc.contributor.author | Che, CM | - |
dc.date.accessioned | 2013-07-15T09:49:03Z | - |
dc.date.available | 2013-07-15T09:49:03Z | - |
dc.date.issued | 2012 | - |
dc.identifier.citation | Synlett, 2012, v. 23 n. 19, p. 2753-2757 | - |
dc.identifier.issn | 0936-5214 | - |
dc.identifier.uri | http://hdl.handle.net/10722/184472 | - |
dc.description.abstract | Rhodium(III) porphyrin complexes [Rh(Por)Me] are catalytically active towards stereoselective intramolecular carbene C–H insertions of α-diazoacetamides to give cis-β-lactams or trans-γ-lactams in yields up to 99% with regioselectivities up to 100% and cis/trans ratios up to 83:17 for β-lactams. | - |
dc.language | eng | - |
dc.publisher | Georg Thieme Verlag. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml | - |
dc.relation.ispartof | Synlett | - |
dc.subject | Rhodium porphyrin | - |
dc.subject | Carbene C–H insertion | - |
dc.subject | Stereoselectivity | - |
dc.subject | Intramolecular cyclization | - |
dc.subject | Lactams | - |
dc.title | Stereoselective Intramolecular Carbene C–H Insertion Catalyzed by Rhodium(III) Porphyrin Complexes | - |
dc.type | Article | - |
dc.identifier.email | Lo, VKY: vanessal@hkusua.hku.hk | - |
dc.identifier.email | Thu, HY: ahyat@graduate.hku.hk | - |
dc.identifier.email | Lam, TL: joeltl@hku.hk | - |
dc.identifier.email | Yu, WY: wyyu@hkusua.hku.hk | - |
dc.identifier.email | Che, CM: cmche@hku.hk | - |
dc.identifier.authority | Lam, TL=rp02782 | - |
dc.identifier.authority | Che, CM=rp00670 | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1055/s-0032-1317322 | - |
dc.identifier.scopus | eid_2-s2.0-84867530184 | - |
dc.identifier.hkuros | 215155 | - |
dc.identifier.volume | 23 | - |
dc.identifier.issue | 19 | - |
dc.identifier.spage | 2753 | - |
dc.identifier.epage | 2757 | - |
dc.identifier.isi | WOS:000311492100006 | - |
dc.publisher.place | Germany | - |
dc.identifier.issnl | 0936-5214 | - |