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Article: Highly enantioselective ketone-ene reactions of trifluoropyruvate: Significant counterion effect of the in(III)-pybox complex

TitleHighly enantioselective ketone-ene reactions of trifluoropyruvate: Significant counterion effect of the in(III)-pybox complex
Authors
Issue Date2009
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html
Citation
Organic Letters, 2009, v. 11 n. 24, p. 5714-5716 How to Cite?
Abstract[Chemical Equation Presented] A chiral indium(III)-pybox complex catalyzed asymmetric ketone-ene reaction of trifluoropyruvate is described. Both aromatic and aliphatic 1,1-disubstituted alkenes reacted smoothly to give the enantioenriched tertiary homoallylic alcohols in good to excellent yields (up to 99%) and with excellent enantioselectivities (up to 98% ee). © 2009 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/182337
ISSN
2015 Impact Factor: 6.732
2015 SCImago Journal Rankings: 3.187
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZhao, JFen_US
dc.contributor.authorTjan, TBWen_US
dc.contributor.authorTan, BHen_US
dc.contributor.authorLoh, TPen_US
dc.date.accessioned2013-04-23T08:19:00Z-
dc.date.available2013-04-23T08:19:00Z-
dc.date.issued2009en_US
dc.identifier.citationOrganic Letters, 2009, v. 11 n. 24, p. 5714-5716en_US
dc.identifier.issn1523-7060en_US
dc.identifier.urihttp://hdl.handle.net/10722/182337-
dc.description.abstract[Chemical Equation Presented] A chiral indium(III)-pybox complex catalyzed asymmetric ketone-ene reaction of trifluoropyruvate is described. Both aromatic and aliphatic 1,1-disubstituted alkenes reacted smoothly to give the enantioenriched tertiary homoallylic alcohols in good to excellent yields (up to 99%) and with excellent enantioselectivities (up to 98% ee). © 2009 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.htmlen_US
dc.relation.ispartofOrganic Lettersen_US
dc.titleHighly enantioselective ketone-ene reactions of trifluoropyruvate: Significant counterion effect of the in(III)-pybox complexen_US
dc.typeArticleen_US
dc.identifier.emailZhao, JF: zhao0065@e.ntu.edu.sgen_US
dc.identifier.authorityZhao, JF=rp01745en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ol902507xen_US
dc.identifier.pmid19911807-
dc.identifier.scopuseid_2-s2.0-72849122521en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-72849122521&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume11en_US
dc.identifier.issue24en_US
dc.identifier.spage5714en_US
dc.identifier.epage5716en_US
dc.identifier.isiWOS:000272461800037-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridZhao, JF=8393022100en_US
dc.identifier.scopusauthoridTjan, TBW=35243601000en_US
dc.identifier.scopusauthoridTan, BH=35244029100en_US
dc.identifier.scopusauthoridLoh, TP=35234192600en_US

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