Article: One-pot solvothermal synthesis of Pd/Fe 3O 4 nanocomposite and its magnetically recyclable and efficient catalysis for Suzuki reactions

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TitleOne-pot solvothermal synthesis of Pd/Fe 3O 4 nanocomposite and its magnetically recyclable and efficient catalysis for Suzuki reactions
AuthorsLi, S2
Zhang, W2
So, MH1
Che, CM1
Wang, R2
Chen, R2
KeywordsCatalysis
Nanocomposite
Pd/Fe 3O 4
Recyclable
Suzuki Reaction
Issue Date2012
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/molcata
CitationJournal Of Molecular Catalysis A: Chemical, 2012, v. 359, p. 81-87 [How to Cite?]
DOI: http://dx.doi.org/10.1016/j.molcata.2012.03.025
AbstractA facile solvothermal synthetic route has been successfully developed to fabricate Pd/Fe 3O 4 nanocomposite with the assistance of polyvinylpyrrolidone (PVP) in N,N-dimethylformamide (DMF) solution. The as-prepared Pd/Fe 3O 4 nanocomposite was composed of uniform 5 nm-sized Pd nanoparticles and Fe 3O 4 nanocrystals with dimension of 40 nm. In this fabrication, PVP played an important role as a capping agent. The as-prepared Pd/Fe 3O 4 nanocomposite exhibited superior catalytic performance and stability for various Suzuki coupling reactions, compared with single-component Pd nanoparticles under the same reaction conditions. More importantly, it displayed good magnetic property and could be easily separated from the reaction mixture by using a magnet and recycled for 10 times without losing its catalytic activity. © 2012 Elsevier B.V. All rights reserved.
ISSN1381-1169
2011 Impact Factor: 2.947
2011 SCImago Journal Rankings: 0.183
DOIhttp://dx.doi.org/10.1016/j.molcata.2012.03.025
ReferencesReferences in Scopus
DC Field
Value
dc.contributor.authorLi, S
dc.contributor.authorZhang, W
dc.contributor.authorSo, MH
dc.contributor.authorChe, CM
dc.contributor.authorWang, R
dc.contributor.authorChen, R
dc.date.accessioned2012-10-08T03:21:45Z
dc.date.available2012-10-08T03:21:45Z
dc.date.issued2012
dc.description.abstractA facile solvothermal synthetic route has been successfully developed to fabricate Pd/Fe 3O 4 nanocomposite with the assistance of polyvinylpyrrolidone (PVP) in N,N-dimethylformamide (DMF) solution. The as-prepared Pd/Fe 3O 4 nanocomposite was composed of uniform 5 nm-sized Pd nanoparticles and Fe 3O 4 nanocrystals with dimension of 40 nm. In this fabrication, PVP played an important role as a capping agent. The as-prepared Pd/Fe 3O 4 nanocomposite exhibited superior catalytic performance and stability for various Suzuki coupling reactions, compared with single-component Pd nanoparticles under the same reaction conditions. More importantly, it displayed good magnetic property and could be easily separated from the reaction mixture by using a magnet and recycled for 10 times without losing its catalytic activity. © 2012 Elsevier B.V. All rights reserved.
dc.description.natureLink_to_subscribed_fulltext
dc.identifier.citationJournal Of Molecular Catalysis A: Chemical, 2012, v. 359, p. 81-87 [How to Cite?]
DOI: http://dx.doi.org/10.1016/j.molcata.2012.03.025
dc.identifier.citeulike10545112
dc.identifier.doihttp://dx.doi.org/10.1016/j.molcata.2012.03.025
dc.identifier.epage87
dc.identifier.issn1381-1169
2011 Impact Factor: 2.947
2011 SCImago Journal Rankings: 0.183
dc.identifier.scopuseid_2-s2.0-84860841556
dc.identifier.spage81
dc.identifier.urihttp://hdl.handle.net/10722/168626
dc.identifier.volume359
dc.languageeng
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/molcata
dc.publisher.placeNetherlands
dc.relation.ispartofJournal of Molecular Catalysis A: Chemical
dc.relation.referencesReferences in Scopus
dc.subjectCatalysis
dc.subjectNanocomposite
dc.subjectPd/Fe 3O 4
dc.subjectRecyclable
dc.subjectSuzuki Reaction
dc.titleOne-pot solvothermal synthesis of Pd/Fe 3O 4 nanocomposite and its magnetically recyclable and efficient catalysis for Suzuki reactions
dc.typeArticle
Author Affiliations
  1. The University of Hong Kong
  2. Ministry of Education China