Article: One-pot solvothermal synthesis of Pd/Fe 3O 4 nanocomposite and its magnetically recyclable and efficient catalysis for Suzuki reactions
| Title | One-pot solvothermal synthesis of Pd/Fe 3O 4 nanocomposite and its magnetically recyclable and efficient catalysis for Suzuki reactions |
|---|---|
| Authors | Li, S2 Zhang, W2 So, MH1 Che, CM1 Wang, R2 Chen, R2 |
| Keywords | Catalysis Nanocomposite Pd/Fe 3O 4 Recyclable Suzuki Reaction |
| Issue Date | 2012 |
| Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/molcata |
| Citation | Journal Of Molecular Catalysis A: Chemical, 2012, v. 359, p. 81-87 [How to Cite?] DOI: http://dx.doi.org/10.1016/j.molcata.2012.03.025 |
| Abstract | A facile solvothermal synthetic route has been successfully developed to fabricate Pd/Fe 3O 4 nanocomposite with the assistance of polyvinylpyrrolidone (PVP) in N,N-dimethylformamide (DMF) solution. The as-prepared Pd/Fe 3O 4 nanocomposite was composed of uniform 5 nm-sized Pd nanoparticles and Fe 3O 4 nanocrystals with dimension of 40 nm. In this fabrication, PVP played an important role as a capping agent. The as-prepared Pd/Fe 3O 4 nanocomposite exhibited superior catalytic performance and stability for various Suzuki coupling reactions, compared with single-component Pd nanoparticles under the same reaction conditions. More importantly, it displayed good magnetic property and could be easily separated from the reaction mixture by using a magnet and recycled for 10 times without losing its catalytic activity. © 2012 Elsevier B.V. All rights reserved. |
| ISSN | 1381-1169 2011 Impact Factor: 2.947 2011 SCImago Journal Rankings: 0.183 |
| DOI | http://dx.doi.org/10.1016/j.molcata.2012.03.025 |
| References | References in Scopus |
| dc.contributor.author | Li, S |
|---|---|
| dc.contributor.author | Zhang, W |
| dc.contributor.author | So, MH |
| dc.contributor.author | Che, CM |
| dc.contributor.author | Wang, R |
| dc.contributor.author | Chen, R |
| dc.date.accessioned | 2012-10-08T03:21:45Z |
| dc.date.available | 2012-10-08T03:21:45Z |
| dc.date.issued | 2012 |
| dc.description.abstract | A facile solvothermal synthetic route has been successfully developed to fabricate Pd/Fe 3O 4 nanocomposite with the assistance of polyvinylpyrrolidone (PVP) in N,N-dimethylformamide (DMF) solution. The as-prepared Pd/Fe 3O 4 nanocomposite was composed of uniform 5 nm-sized Pd nanoparticles and Fe 3O 4 nanocrystals with dimension of 40 nm. In this fabrication, PVP played an important role as a capping agent. The as-prepared Pd/Fe 3O 4 nanocomposite exhibited superior catalytic performance and stability for various Suzuki coupling reactions, compared with single-component Pd nanoparticles under the same reaction conditions. More importantly, it displayed good magnetic property and could be easily separated from the reaction mixture by using a magnet and recycled for 10 times without losing its catalytic activity. © 2012 Elsevier B.V. All rights reserved. |
| dc.description.nature | Link_to_subscribed_fulltext |
| dc.identifier.citation | Journal Of Molecular Catalysis A: Chemical, 2012, v. 359, p. 81-87 [How to Cite?] DOI: http://dx.doi.org/10.1016/j.molcata.2012.03.025 |
| dc.identifier.citeulike | 10545112 |
| dc.identifier.doi | http://dx.doi.org/10.1016/j.molcata.2012.03.025 |
| dc.identifier.epage | 87 |
| dc.identifier.issn | 1381-1169 2011 Impact Factor: 2.947 2011 SCImago Journal Rankings: 0.183 |
| dc.identifier.scopus | eid_2-s2.0-84860841556 |
| dc.identifier.spage | 81 |
| dc.identifier.uri | http://hdl.handle.net/10722/168626 |
| dc.identifier.volume | 359 |
| dc.language | eng |
| dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/molcata |
| dc.publisher.place | Netherlands |
| dc.relation.ispartof | Journal of Molecular Catalysis A: Chemical |
| dc.relation.references | References in Scopus |
| dc.subject | Catalysis |
| dc.subject | Nanocomposite |
| dc.subject | Pd/Fe 3O 4 |
| dc.subject | Recyclable |
| dc.subject | Suzuki Reaction |
| dc.title | One-pot solvothermal synthesis of Pd/Fe 3O 4 nanocomposite and its magnetically recyclable and efficient catalysis for Suzuki reactions |
| dc.type | Article |
Author Affiliations
- The University of Hong Kong
- Ministry of Education China

