Article: Design, synthesis, characterization, luminescence and non-linear optical (NLO) properties of multinuclear platinum(ii) alkynyl complexes

File Download

No File Attached
The HKU Scholars Hub has contact details for these author(s).

Links for fulltext
(May Require Subscription)

Publisher Website: 10.1039/c1dt10784d
Scopus: eid_2-s2.0-80053467656
PMID: 21858294

Supplementary

Citations:
- Scopus:
- Web of Science:
- PubMed Central:
Item Statistics (The Hub)
Appears in Collections:
- Chemistry: Journal/Magazine Articles

Title	Design, synthesis, characterization, luminescence and non-linear optical (NLO) properties of multinuclear platinum(ii) alkynyl complexes
Authors	Chan, CKM1 Tao, CH1 Li, KF2 Wong, KMC1 Zhu, N1 Cheah, KW2 Yam, VWW1
Keywords	Benzene solution Buta-1,3-diyne Electronic absorption Nanosecond transient absorption Nonlinear optical properties
Issue Date	2011
Publisher	Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation	Dalton Transactions, 2011, v. 40 n. 40, p. 10670-10685 [How to Cite?] DOI: http://dx.doi.org/10.1039/c1dt10784d
Abstract	A series of luminescent multinuclear platinum(ii) alkynyl complexes containing triethynylbenzene or 1,4-bis(3,5-diethynylphenyl)buta-1,3-diyne as cores has been successfully synthesized and characterized. The electronic absorption, emission, nanosecond transient absorption and electrochemical properties of these complexes have been reported. These complexes show long-lived emissions in degassed benzene solution and in alcoholic glass at 77 K. Moreover, they are found to exhibit two-photon absorption (2PA) and two-photon induced luminescence (TPIL) properties, and their two-photon absorption cross-sections have been determined to be 6-191 GM upon excitation at 720 nm. Through a systematic comparison, it has been found that tetra- and hexanuclear platinum(ii) complexes show better 2PA and TPIL properties than their di- and trinuclear counterparts. © 2011 The Royal Society of Chemistry.
ISSN	1477-9226 2011 Impact Factor: 3.838 2011 SCImago Journal Rankings: 0.254
DOI	http://dx.doi.org/10.1039/c1dt10784d
References	References in Scopus

DC Field	Value
dc.contributor.author	Chan, CKM
dc.contributor.author	Tao, CH
dc.contributor.author	Li, KF
dc.contributor.author	Wong, KMC
dc.contributor.author	Zhu, N
dc.contributor.author	Cheah, KW
dc.contributor.author	Yam, VWW
dc.date.accessioned	2012-10-08T03:20:54Z
dc.date.available	2012-10-08T03:20:54Z
dc.date.issued	2011
dc.description.abstract	A series of luminescent multinuclear platinum(ii) alkynyl complexes containing triethynylbenzene or 1,4-bis(3,5-diethynylphenyl)buta-1,3-diyne as cores has been successfully synthesized and characterized. The electronic absorption, emission, nanosecond transient absorption and electrochemical properties of these complexes have been reported. These complexes show long-lived emissions in degassed benzene solution and in alcoholic glass at 77 K. Moreover, they are found to exhibit two-photon absorption (2PA) and two-photon induced luminescence (TPIL) properties, and their two-photon absorption cross-sections have been determined to be 6-191 GM upon excitation at 720 nm. Through a systematic comparison, it has been found that tetra- and hexanuclear platinum(ii) complexes show better 2PA and TPIL properties than their di- and trinuclear counterparts. © 2011 The Royal Society of Chemistry.
dc.description.nature	Link_to_subscribed_fulltext
dc.identifier.citation	Dalton Transactions, 2011, v. 40 n. 40, p. 10670-10685 [How to Cite?] DOI: http://dx.doi.org/10.1039/c1dt10784d
dc.identifier.doi	http://dx.doi.org/10.1039/c1dt10784d
dc.identifier.epage	10685
dc.identifier.hkuros	204447
dc.identifier.issn	1477-9226 2011 Impact Factor: 3.838 2011 SCImago Journal Rankings: 0.254
dc.identifier.issue	40
dc.identifier.pmid	21858294
dc.identifier.scopus	eid_2-s2.0-80053467656
dc.identifier.spage	10670
dc.identifier.uri	http://hdl.handle.net/10722/168570
dc.identifier.volume	40
dc.language	eng
dc.publisher	Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
dc.publisher.place	United Kingdom
dc.relation.ispartof	Dalton Transactions
dc.relation.references	References in Scopus
dc.subject	Benzene solution
dc.subject	Buta-1,3-diyne
dc.subject	Electronic absorption
dc.subject	Nanosecond transient absorption
dc.subject	Nonlinear optical properties
dc.title	Design, synthesis, characterization, luminescence and non-linear optical (NLO) properties of multinuclear platinum(ii) alkynyl complexes
dc.type	Article

<?xml encoding="utf-8" version="1.0"?><item><contributor.author>Chan, CKM</contributor.author><contributor.author>Tao, CH</contributor.author><contributor.author>Li, KF</contributor.author><contributor.author>Wong, KMC</contributor.author><contributor.author>Zhu, N</contributor.author><contributor.author>Cheah, KW</contributor.author><contributor.author>Yam, VWW</contributor.author><date.accessioned>2012-10-08T03:20:54Z</date.accessioned><date.available>2012-10-08T03:20:54Z</date.available><date.issued>2011</date.issued><identifier.citation>Dalton Transactions, 2011, v. 40 n. 40, p. 10670-10685</identifier.citation><identifier.issn>1477-9226</identifier.issn><identifier.uri>http://hdl.handle.net/10722/168570</identifier.uri><description.abstract>A series of luminescent multinuclear platinum(ii) alkynyl complexes containing triethynylbenzene or 1,4-bis(3,5-diethynylphenyl)buta-1,3-diyne as cores has been successfully synthesized and characterized. The electronic absorption, emission, nanosecond transient absorption and electrochemical properties of these complexes have been reported. These complexes show long-lived emissions in degassed benzene solution and in alcoholic glass at 77 K. Moreover, they are found to exhibit two-photon absorption (2PA) and two-photon induced luminescence (TPIL) properties, and their two-photon absorption cross-sections have been determined to be 6-191 GM upon excitation at 720 nm. Through a systematic comparison, it has been found that tetra- and hexanuclear platinum(ii) complexes show better 2PA and TPIL properties than their di- and trinuclear counterparts. &#169; 2011 The Royal Society of Chemistry.</description.abstract><language>eng</language><publisher>Royal Society of Chemistry. The Journal&apos;s web site is located at http://www.rsc.org/dalton</publisher><relation.ispartof>Dalton Transactions</relation.ispartof><subject>Benzene solution</subject><subject>Buta-1,3-diyne</subject><subject>Electronic absorption</subject><subject>Nanosecond transient absorption</subject><subject>Nonlinear optical properties</subject><title>Design, synthesis, characterization, luminescence and non-linear optical (NLO) properties of multinuclear platinum(ii) alkynyl complexes</title><type>Article</type><description.nature>Link_to_subscribed_fulltext</description.nature><identifier.doi>10.1039/c1dt10784d</identifier.doi><identifier.pmid>21858294</identifier.pmid><identifier.scopus>eid_2-s2.0-80053467656</identifier.scopus><identifier.hkuros>204447</identifier.hkuros><relation.references>http://www.scopus.com/mlt/select.url?eid=2-s2.0-80053467656&amp;selection=ref&amp;src=s&amp;origin=recordpage</relation.references><identifier.volume>40</identifier.volume><identifier.issue>40</identifier.issue><identifier.spage>10670</identifier.spage><identifier.epage>10685</identifier.epage><publisher.place>United Kingdom</publisher.place></item>

Author Affiliations

The University of Hong Kong
Hong Kong Baptist University

Article: Design, synthesis, characterization, luminescence and non-linear optical (NLO) properties of multinuclear platinum(ii) alkynyl complexes

The HKU Scholars Hub has contact details for these author(s).