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Article: Synthesis and crystal structure of a manganese complex with 3-methyl-4-(p-bromophenyl)-5-(2-pyridyl)-l,2,4-triazole

TitleSynthesis and crystal structure of a manganese complex with 3-methyl-4-(p-bromophenyl)-5-(2-pyridyl)-l,2,4-triazole
基于3-甲基-4-对溴苯基-5-(2-吡啶基)-1,2,4-三氮唑的锰配合物的合成和晶体结构
Authors
Keywords1 2 4-Triazole (三氮唑)
Crystal Structure (晶体结构)
Mn(Ii) Complex (锰配合物)
Issue Date2011
Citation
Chinese Journal Of Inorganic Chemistry, 2011, v. 27 n. 4, p. 743-746 How to Cite?
无机化学学报, 2011, v. 27 n. 4, p. 743-746 How to Cite?
AbstractA new manganese(H) complex, cis-[MnL 2(NCS) 2], (L=3-methyl-4-(p-bromophenyl)-5-(2-pyridyl)-1,2,4- triazole), was synthesized and characterized by X-ray crystallography, FTIR and ESI-MS spectra. The complex crystallizes in monoclinic system with space group P2 1ln, a =1.648 0(2), b =0.907 07(13), c=2.191 9(3) nm, β= 97.454(2)°, 1=3.248 8(8) nm 3, Z=4 with final R =0.043 9. The manganese atom lies in a distorted octahedral environment with two NCS ions in the cis positions. The ligand L coordinates via one triazole nitrogen and one pyridine nitrogen atom. CCDC: 790351.
以3-甲基-4-对溴苯基-5-(2-吡啶基)-1,2,4-三氮唑作为配体(L),合成了1个新的锰配合物[MnL2(NCS)2],对其进行了红外、电喷雾质谱和单晶结构表征,该配合物属于单斜晶系,空间群P21/n,a=1.648 0(2) nm,b=0.907 07(13) nm,c=2.191 9(3) nm,β=97.454(2)°,V=3.248 8(8) nm3,Z=4,R1=0.043 9。单晶结构表明,锰离子处于1个扭曲的八面体配位环境中,2个硫氰根离子呈顺式配位,每个配体L通过三氮唑上1个氮原子和吡啶上1个氮原子参与配位。
Persistent Identifierhttp://hdl.handle.net/10722/168520
ISSN
2015 Impact Factor: 0.488
2015 SCImago Journal Rankings: 0.161
References

 

DC FieldValueLanguage
dc.contributor.authorZhao, Jen_US
dc.contributor.authorLu, Wen_US
dc.contributor.authorChen, Len_US
dc.contributor.authorShen, Xen_US
dc.contributor.authorXu, Yen_US
dc.contributor.authorZhu, DRen_US
dc.date.accessioned2012-10-08T03:19:57Z-
dc.date.available2012-10-08T03:19:57Z-
dc.date.issued2011en_US
dc.identifier.citationChinese Journal Of Inorganic Chemistry, 2011, v. 27 n. 4, p. 743-746en_US
dc.identifier.citation无机化学学报, 2011, v. 27 n. 4, p. 743-746-
dc.identifier.issn1001-4861en_US
dc.identifier.urihttp://hdl.handle.net/10722/168520-
dc.description.abstractA new manganese(H) complex, cis-[MnL 2(NCS) 2], (L=3-methyl-4-(p-bromophenyl)-5-(2-pyridyl)-1,2,4- triazole), was synthesized and characterized by X-ray crystallography, FTIR and ESI-MS spectra. The complex crystallizes in monoclinic system with space group P2 1ln, a =1.648 0(2), b =0.907 07(13), c=2.191 9(3) nm, β= 97.454(2)°, 1=3.248 8(8) nm 3, Z=4 with final R =0.043 9. The manganese atom lies in a distorted octahedral environment with two NCS ions in the cis positions. The ligand L coordinates via one triazole nitrogen and one pyridine nitrogen atom. CCDC: 790351.en_US
dc.description.abstract以3-甲基-4-对溴苯基-5-(2-吡啶基)-1,2,4-三氮唑作为配体(L),合成了1个新的锰配合物[MnL2(NCS)2],对其进行了红外、电喷雾质谱和单晶结构表征,该配合物属于单斜晶系,空间群P21/n,a=1.648 0(2) nm,b=0.907 07(13) nm,c=2.191 9(3) nm,β=97.454(2)°,V=3.248 8(8) nm3,Z=4,R1=0.043 9。单晶结构表明,锰离子处于1个扭曲的八面体配位环境中,2个硫氰根离子呈顺式配位,每个配体L通过三氮唑上1个氮原子和吡啶上1个氮原子参与配位。-
dc.languagechien_US
dc.relation.ispartofChinese Journal of Inorganic Chemistryen_US
dc.relation.ispartof无机化学学报-
dc.subject1 2 4-Triazole (三氮唑)en_US
dc.subjectCrystal Structure (晶体结构)en_US
dc.subjectMn(Ii) Complex (锰配合物)en_US
dc.titleSynthesis and crystal structure of a manganese complex with 3-methyl-4-(p-bromophenyl)-5-(2-pyridyl)-l,2,4-triazoleen_US
dc.title基于3-甲基-4-对溴苯基-5-(2-吡啶基)-1,2,4-三氮唑的锰配合物的合成和晶体结构-
dc.typeArticleen_US
dc.identifier.emailLu, W:luwei@hku.hken_US
dc.identifier.authorityLu, W=rp00754en_US
dc.description.naturelink_to_OA_fulltexten_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-79954463155&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume27en_US
dc.identifier.issue4en_US
dc.identifier.spage743en_US
dc.identifier.epage746en_US
dc.identifier.scopusauthoridZhao, J=36524577700en_US
dc.identifier.scopusauthoridLu, W=27868087600en_US
dc.identifier.scopusauthoridChen, L=37088243200en_US
dc.identifier.scopusauthoridShen, X=24741250500en_US
dc.identifier.scopusauthoridXu, Y=15833286300en_US
dc.identifier.scopusauthoridZhu, DR=7403599162en_US

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