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Article: Very-low-bandgap metallopolyynes of platinum with a cyclopentadithiophenone ring for organic solar cells absorbing down to the near-infrared spectral region a

TitleVery-low-bandgap metallopolyynes of platinum with a cyclopentadithiophenone ring for organic solar cells absorbing down to the near-infrared spectral region a
Authors
KeywordsConjugated polymers
Crystal structure
Cyclopentadithiophenone
Donor-acceptor compounds
Metallopolymers
Platinum(ii) polyynes
Solar cells
Issue Date2010
Citation
Macromolecular Rapid Communications, 2010, v. 31 n. 9-10, p. 861-867 How to Cite?
Abstract(Figure Presented) Two solution-processable metallopolyynes of platinum functionalized with the electrondeficient 4H-cyclopenta[2,1-b:3,4-b'] dithiophen-4-one spacer and their model molecular complexes were synthesized and developed for the applications of polymer solar cells. These metallated polymers possess extremely low bandgaps of 1.44-1.53 eV which extend toward the near-infrared (NIR) range of the solar spectrum, and represent the lowest optical bandgap yet reported for platinum(II) metallopolyynes to date. The structural flexibility, processibility, and good photovoltaic performance make cyclopentadithiophenone-containing polymers prominent candidates for NIR photovoltaic applications. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA.
Persistent Identifierhttp://hdl.handle.net/10722/168459
ISSN
2015 Impact Factor: 4.638
2015 SCImago Journal Rankings: 1.869
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorWang, XZen_HK
dc.contributor.authorWang, Qen_HK
dc.contributor.authorYan, Len_HK
dc.contributor.authorWong, WYen_HK
dc.contributor.authorCheung, KYen_HK
dc.contributor.authorNg, Aen_HK
dc.contributor.authorDjurišić, ABen_HK
dc.contributor.authorChan, WKen_HK
dc.date.accessioned2012-10-08T03:19:11Z-
dc.date.available2012-10-08T03:19:11Z-
dc.date.issued2010en_HK
dc.identifier.citationMacromolecular Rapid Communications, 2010, v. 31 n. 9-10, p. 861-867en_HK
dc.identifier.issn1022-1336en_HK
dc.identifier.urihttp://hdl.handle.net/10722/168459-
dc.description.abstract(Figure Presented) Two solution-processable metallopolyynes of platinum functionalized with the electrondeficient 4H-cyclopenta[2,1-b:3,4-b'] dithiophen-4-one spacer and their model molecular complexes were synthesized and developed for the applications of polymer solar cells. These metallated polymers possess extremely low bandgaps of 1.44-1.53 eV which extend toward the near-infrared (NIR) range of the solar spectrum, and represent the lowest optical bandgap yet reported for platinum(II) metallopolyynes to date. The structural flexibility, processibility, and good photovoltaic performance make cyclopentadithiophenone-containing polymers prominent candidates for NIR photovoltaic applications. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA.en_HK
dc.languageengen_US
dc.relation.ispartofMacromolecular Rapid Communicationsen_HK
dc.subjectConjugated polymersen_HK
dc.subjectCrystal structureen_HK
dc.subjectCyclopentadithiophenoneen_HK
dc.subjectDonor-acceptor compoundsen_HK
dc.subjectMetallopolymersen_HK
dc.subjectPlatinum(ii) polyynesen_HK
dc.subjectSolar cellsen_HK
dc.titleVery-low-bandgap metallopolyynes of platinum with a cyclopentadithiophenone ring for organic solar cells absorbing down to the near-infrared spectral region aen_HK
dc.typeArticleen_HK
dc.identifier.emailDjurišić, AB: dalek@hku.hken_HK
dc.identifier.emailChan, WK: waichan@hku.hken_HK
dc.identifier.authorityDjurišić, AB=rp00690en_HK
dc.identifier.authorityChan, WK=rp00667en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/marc.200900885en_HK
dc.identifier.pmid21590980-
dc.identifier.scopuseid_2-s2.0-77952666336en_HK
dc.identifier.hkuros170668-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-77952666336&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume31en_HK
dc.identifier.issue9-10en_HK
dc.identifier.spage861en_HK
dc.identifier.epage867en_HK
dc.identifier.isiWOS:000278436300012-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridWang, XZ=8907969400en_HK
dc.identifier.scopusauthoridWang, Q=7408171607en_HK
dc.identifier.scopusauthoridYan, L=47761733100en_HK
dc.identifier.scopusauthoridWong, WY=7403972153en_HK
dc.identifier.scopusauthoridCheung, KY=25229974800en_HK
dc.identifier.scopusauthoridNg, A=13806222700en_HK
dc.identifier.scopusauthoridDjurišić, AB=7004904830en_HK
dc.identifier.scopusauthoridChan, WK=13310083000en_HK
dc.identifier.citeulike8787485-

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