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Article: Mechanistic investigations of the phosphine-mediated nitrone deoxygenation reaction and its application in cyclic imine synthesis

TitleMechanistic investigations of the phosphine-mediated nitrone deoxygenation reaction and its application in cyclic imine synthesis
Authors
KeywordsImines
Iminosugars
Mp2 Calculations
Nitrone Deoxygenation
Phosphines
Issue Date2009
PublisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetlet
Citation
Tetrahedron Letters, 2009, v. 50 n. 50, p. 7038-7042 How to Cite?
AbstractCarbohydrate-derived cyclic nitrones were deoxygenated to form the corresponding imines using tributylphosphine. Experimental and theoretical investigations by the way of MP2 calculations suggest a revision of the mechanism initially proposed by Kurtzweil and Beak for the triarylphosphine-mediated deoxygenation of nitrones. © 2009 Elsevier Ltd. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/168413
ISSN
2015 Impact Factor: 2.347
2015 SCImago Journal Rankings: 0.782
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorCividino, Pen_US
dc.contributor.authorDheuAndries, MLen_US
dc.contributor.authorOu, Jen_US
dc.contributor.authorMilet, Aen_US
dc.contributor.authorPy, Sen_US
dc.contributor.authorToy, PHen_US
dc.date.accessioned2012-10-08T03:18:39Z-
dc.date.available2012-10-08T03:18:39Z-
dc.date.issued2009en_US
dc.identifier.citationTetrahedron Letters, 2009, v. 50 n. 50, p. 7038-7042en_US
dc.identifier.issn0040-4039en_US
dc.identifier.urihttp://hdl.handle.net/10722/168413-
dc.description.abstractCarbohydrate-derived cyclic nitrones were deoxygenated to form the corresponding imines using tributylphosphine. Experimental and theoretical investigations by the way of MP2 calculations suggest a revision of the mechanism initially proposed by Kurtzweil and Beak for the triarylphosphine-mediated deoxygenation of nitrones. © 2009 Elsevier Ltd. All rights reserved.en_US
dc.languageengen_US
dc.publisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetleten_US
dc.relation.ispartofTetrahedron Lettersen_US
dc.subjectIminesen_US
dc.subjectIminosugarsen_US
dc.subjectMp2 Calculationsen_US
dc.subjectNitrone Deoxygenationen_US
dc.subjectPhosphinesen_US
dc.titleMechanistic investigations of the phosphine-mediated nitrone deoxygenation reaction and its application in cyclic imine synthesisen_US
dc.typeArticleen_US
dc.identifier.emailToy, PH:phtoy@hkucc.hku.hken_US
dc.identifier.authorityToy, PH=rp00791en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/j.tetlet.2009.09.175en_US
dc.identifier.scopuseid_2-s2.0-70350754541en_US
dc.identifier.hkuros170478-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-70350754541&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume50en_US
dc.identifier.issue50en_US
dc.identifier.spage7038en_US
dc.identifier.epage7042en_US
dc.identifier.isiWOS:000271841900029-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridCividino, P=7801585572en_US
dc.identifier.scopusauthoridDheuAndries, ML=6504154520en_US
dc.identifier.scopusauthoridOu, J=35234687200en_US
dc.identifier.scopusauthoridMilet, A=6701366879en_US
dc.identifier.scopusauthoridPy, S=6602523031en_US
dc.identifier.scopusauthoridToy, PH=7006579247en_US
dc.identifier.citeulike5913446-

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