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Article: A luminescent trinuclear platinum(II) Pt3C2 system with a "naked" C = C2- ligand that fluctuates amongst three unsupported platinum(II) moieties

TitleA luminescent trinuclear platinum(II) Pt3C2 system with a "naked" C = C2- ligand that fluctuates amongst three unsupported platinum(II) moieties
Authors
Issue Date2008
PublisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry
Citation
Chemistry - A European Journal, 2008, v. 14 n. 35, p. 10928-10931 How to Cite?
AbstractA study was conducted the isolation and structural characterization of a trinuclear platinum(II) terpyridyl complex in which three discrete unsupported [Pt(trpy)] fragments are linked by a 'naked' C≡C2- alkynyl rod in σ- and π-coordination modes. The study also focused on investigating and explaining the photophysical and fluxional behavior and correlated with theoretical calculations. It was found that the three platinum(II) ions are coplanar with isosceles-triangle geometry, while the C≡C2- rod unit lies in the plane, with one carbon above and another below it. The three trinuclear platinum(II) terpyridyl planes were twisted with the dihedral angle between the σ- and π-coordinated trinuclear platinum(II) terpyridyl planes.
Persistent Identifierhttp://hdl.handle.net/10722/168347
ISSN
2015 Impact Factor: 5.771
2015 SCImago Journal Rankings: 2.323
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorWong, KMCen_US
dc.contributor.authorLam, WHen_US
dc.contributor.authorZhou, ZYen_US
dc.contributor.authorYam, VWWen_US
dc.date.accessioned2012-10-08T03:17:51Z-
dc.date.available2012-10-08T03:17:51Z-
dc.date.issued2008en_US
dc.identifier.citationChemistry - A European Journal, 2008, v. 14 n. 35, p. 10928-10931en_US
dc.identifier.issn0947-6539en_US
dc.identifier.urihttp://hdl.handle.net/10722/168347-
dc.description.abstractA study was conducted the isolation and structural characterization of a trinuclear platinum(II) terpyridyl complex in which three discrete unsupported [Pt(trpy)] fragments are linked by a 'naked' C≡C2- alkynyl rod in σ- and π-coordination modes. The study also focused on investigating and explaining the photophysical and fluxional behavior and correlated with theoretical calculations. It was found that the three platinum(II) ions are coplanar with isosceles-triangle geometry, while the C≡C2- rod unit lies in the plane, with one carbon above and another below it. The three trinuclear platinum(II) terpyridyl planes were twisted with the dihedral angle between the σ- and π-coordinated trinuclear platinum(II) terpyridyl planes.en_US
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistryen_US
dc.relation.ispartofChemistry - A European Journalen_US
dc.subject.meshAlkynes - Chemical Synthesis - Chemistryen_US
dc.subject.meshCrystallography, X-Rayen_US
dc.subject.meshLigandsen_US
dc.subject.meshLuminescenceen_US
dc.subject.meshMolecular Structureen_US
dc.subject.meshPlatinum Compounds - Chemical Synthesis - Chemistryen_US
dc.titleA luminescent trinuclear platinum(II) Pt3C2 system with a "naked" C = C2- ligand that fluctuates amongst three unsupported platinum(II) moietiesen_US
dc.typeArticleen_US
dc.identifier.emailWong, KMC:wongmc@hku.hken_US
dc.identifier.emailLam, WH:chsue@hku.hken_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityWong, KMC=rp00809en_US
dc.identifier.authorityLam, WH=rp00719en_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/chem.200801842en_US
dc.identifier.pmid18988244-
dc.identifier.scopuseid_2-s2.0-57149137208en_US
dc.identifier.hkuros156122-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-57149137208&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume14en_US
dc.identifier.issue35en_US
dc.identifier.spage10928en_US
dc.identifier.epage10931en_US
dc.identifier.eissn1521-3765-
dc.identifier.isiWOS:000261933000011-
dc.publisher.placeGermanyen_US
dc.identifier.scopusauthoridWong, KMC=8061067200en_US
dc.identifier.scopusauthoridLam, WH=26642862800en_US
dc.identifier.scopusauthoridZhou, ZY=7406096262en_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US

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