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Article: Syntheses, characterization, and photochromic studies of spirooxazine-containing 2,2′-bipyridine ligands and their zinc(II) thiolate complexes

TitleSyntheses, characterization, and photochromic studies of spirooxazine-containing 2,2′-bipyridine ligands and their zinc(II) thiolate complexes
Authors
Issue Date2008
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2008, v. 47 n. 19, p. 8912-8920 How to Cite?
AbstractA series of photochrome spirooxazine-containing zinc(II) diimine bis-thiolate complexes were successfully synthesized, and their photophysical and photochromic properties were studied. The X-ray crystal structure of complex 1a has also been determined. Upon excitation by UV light at 330 nm, all the ligands and complexes exhibit photochromic behavior. The thermal bleaching kinetics of the ligands and the complexes were studied in dimethylformamide at various temperatures. The photochemical quantum yields for the photochromic reactions of the ligands and complexes were also determined. © 2008 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/168335
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorBao, Zen_HK
dc.contributor.authorNg, KYen_HK
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorKo, CCen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorWu, Len_HK
dc.date.accessioned2012-10-08T03:17:42Z-
dc.date.available2012-10-08T03:17:42Z-
dc.date.issued2008en_HK
dc.identifier.citationInorganic Chemistry, 2008, v. 47 n. 19, p. 8912-8920en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/168335-
dc.description.abstractA series of photochrome spirooxazine-containing zinc(II) diimine bis-thiolate complexes were successfully synthesized, and their photophysical and photochromic properties were studied. The X-ray crystal structure of complex 1a has also been determined. Upon excitation by UV light at 330 nm, all the ligands and complexes exhibit photochromic behavior. The thermal bleaching kinetics of the ligands and the complexes were studied in dimethylformamide at various temperatures. The photochemical quantum yields for the photochromic reactions of the ligands and complexes were also determined. © 2008 American Chemical Society.en_HK
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.subject.mesh2,2'-Dipyridyl - Chemistryen_US
dc.subject.meshAbsorptionen_US
dc.subject.meshLigandsen_US
dc.subject.meshMagnetic Resonance Spectroscopyen_US
dc.subject.meshOrganometallic Compounds - Chemical Synthesis - Chemistryen_US
dc.subject.meshOxazines - Chemistryen_US
dc.subject.meshSulfhydryl Compounds - Chemistryen_US
dc.subject.meshZinc - Chemistryen_US
dc.titleSyntheses, characterization, and photochromic studies of spirooxazine-containing 2,2′-bipyridine ligands and their zinc(II) thiolate complexesen_HK
dc.typeArticleen_HK
dc.identifier.emailYam, VWW: wwyam@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ic8009755en_HK
dc.identifier.pmid18729356-
dc.identifier.scopuseid_2-s2.0-54149115476en_HK
dc.identifier.hkuros155665-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-54149115476&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume47en_HK
dc.identifier.issue19en_HK
dc.identifier.spage8912en_HK
dc.identifier.epage8920en_HK
dc.identifier.isiWOS:000259603800063-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridBao, Z=25959521600en_HK
dc.identifier.scopusauthoridNg, KY=25959658600en_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridKo, CC=7202596455en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridWu, L=7404902949en_HK

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