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Article: Kinetics of electron transfer between metal hexacyanide complexes

TitleKinetics of electron transfer between metal hexacyanide complexes
Authors
Issue Date1990
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1990, v. 168 n. 3-4, p. 361-364 How to Cite?
AbstractThe electron transfer reactions between three isomorphic hexacyanides complexes, Fe(CN)6 3- 4-, Os(CN)6 3- 4- and Ru(CN)6 3- 4- have been studied using the method of photoexcitation. The electron transfer rate constants between any two complexes increase by about a factor of 60 as the ionic strength is increased from 30 to 440 mM. An ionic-strength-independent reorganization energy of 1.1 eV was found for the hexacyanide self-exchange reaction when the data were analyzed according to the theory of Marcus. © 1990.
Persistent Identifierhttp://hdl.handle.net/10722/168293
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorCho, KCen_US
dc.contributor.authorCham, PMen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:17:09Z-
dc.date.available2012-10-08T03:17:09Z-
dc.date.issued1990en_US
dc.identifier.citationChemical Physics Letters, 1990, v. 168 n. 3-4, p. 361-364en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://hdl.handle.net/10722/168293-
dc.description.abstractThe electron transfer reactions between three isomorphic hexacyanides complexes, Fe(CN)6 3- 4-, Os(CN)6 3- 4- and Ru(CN)6 3- 4- have been studied using the method of photoexcitation. The electron transfer rate constants between any two complexes increase by about a factor of 60 as the ionic strength is increased from 30 to 440 mM. An ionic-strength-independent reorganization energy of 1.1 eV was found for the hexacyanide self-exchange reaction when the data were analyzed according to the theory of Marcus. © 1990.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_US
dc.relation.ispartofChemical Physics Lettersen_US
dc.titleKinetics of electron transfer between metal hexacyanide complexesen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/0009-2614(90)85625-M-
dc.identifier.pmid2536552-
dc.identifier.scopuseid_2-s2.0-4243338601en_US
dc.identifier.volume168en_US
dc.identifier.issue3-4en_US
dc.identifier.spage361en_US
dc.identifier.epage364en_US
dc.identifier.isiWOS:A1990DE08800024-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridCho, KC=15129672200en_US
dc.identifier.scopusauthoridCham, PM=36964387800en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US

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