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Article: Structural and mechanistic studies of co-ordination compounds. Part 38. Syntheses and characterization of several quadridentate macrocyclic amine complexes of iridium(III)

TitleStructural and mechanistic studies of co-ordination compounds. Part 38. Syntheses and characterization of several quadridentate macrocyclic amine complexes of iridium(III)
Authors
Issue Date1983
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1983 n. 8, p. 1647-1651 How to Cite?
AbstractSeveral macrocyclic amine complexes of the type cis-[IrL3(A)X]+ [L3 = 1,4,8,11-tetra-azacyclotetradecane, (A)X = Cl2, Br2, or (Cl)Br], trans-[IrLX2]+ [L = L3, X = Cl or NO2; L4 (1,4,8,1 2-tetra-azacyclopentadecane) or L5 (C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane), X = Cl or Br; and L6 (C-rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, X = Cl], and trans-[IrL(Cl)Br]+ (L = L4 or L5) have been prepared and characterized. All these complexes are diamagnetic monomeric species. The i.r. and electronic absorption spectra of the complexes are discussed.
Persistent Identifierhttp://hdl.handle.net/10722/168265
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorPoon, CKen_US
dc.contributor.authorTang, Ten_US
dc.contributor.authorChe, Cen_US
dc.date.accessioned2012-10-08T03:16:49Z-
dc.date.available2012-10-08T03:16:49Z-
dc.date.issued1983en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1983 n. 8, p. 1647-1651en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168265-
dc.description.abstractSeveral macrocyclic amine complexes of the type cis-[IrL3(A)X]+ [L3 = 1,4,8,11-tetra-azacyclotetradecane, (A)X = Cl2, Br2, or (Cl)Br], trans-[IrLX2]+ [L = L3, X = Cl or NO2; L4 (1,4,8,1 2-tetra-azacyclopentadecane) or L5 (C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane), X = Cl or Br; and L6 (C-rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, X = Cl], and trans-[IrL(Cl)Br]+ (L = L4 or L5) have been prepared and characterized. All these complexes are diamagnetic monomeric species. The i.r. and electronic absorption spectra of the complexes are discussed.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleStructural and mechanistic studies of co-ordination compounds. Part 38. Syntheses and characterization of several quadridentate macrocyclic amine complexes of iridium(III)en_US
dc.typeArticleen_US
dc.identifier.emailChe, C:cmche@hku.hken_US
dc.identifier.authorityChe, C=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9830001647en_US
dc.identifier.scopuseid_2-s2.0-37049108269en_US
dc.identifier.issue8en_US
dc.identifier.spage1647en_US
dc.identifier.epage1651en_US
dc.identifier.isiWOS:A1983RD71300025-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridPoon, CK=7202673504en_US
dc.identifier.scopusauthoridTang, T=15222800500en_US
dc.identifier.scopusauthoridChe, C=7102442791en_US

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