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Article: Novel osmium-(V) and -(IV) dioxo complexes of macrocyclic tetradentate tertiary amines: Spectroscopic studies and reactivity of trans-[Os V(tmc)(O)2]+ (tmc = 1,4,8,11 -tetramethyl-1,4,8,11-tetra-azacyclotetradecane)

TitleNovel osmium-(V) and -(IV) dioxo complexes of macrocyclic tetradentate tertiary amines: Spectroscopic studies and reactivity of trans-[Os V(tmc)(O)2]+ (tmc = 1,4,8,11 -tetramethyl-1,4,8,11-tetra-azacyclotetradecane)
Authors
Issue Date1986
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1986 n. 20, p. 1519-1521 How to Cite?
Abstracttrans-[OsV(tmc)(O)2]+ (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) was generated by the electrochemical reduction of trans-[OsVI(tmc)(O)2] 2+ in MeCN with an £4 of the MeCN with an E1/2 of the OsVI/OsVcouple of -0-73 V vs. ferrocenium-ferrocene; the OsV complex displayed two vibronic structured d-d bands in the 300-450 nm region.
Persistent Identifierhttp://hdl.handle.net/10722/168249
ISSN
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorCheng, WKen_US
dc.date.accessioned2012-10-08T03:16:40Z-
dc.date.available2012-10-08T03:16:40Z-
dc.date.issued1986en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1986 n. 20, p. 1519-1521en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/168249-
dc.description.abstracttrans-[OsV(tmc)(O)2]+ (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) was generated by the electrochemical reduction of trans-[OsVI(tmc)(O)2] 2+ in MeCN with an £4 of the MeCN with an E1/2 of the OsVI/OsVcouple of -0-73 V vs. ferrocenium-ferrocene; the OsV complex displayed two vibronic structured d-d bands in the 300-450 nm region.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleNovel osmium-(V) and -(IV) dioxo complexes of macrocyclic tetradentate tertiary amines: Spectroscopic studies and reactivity of trans-[Os V(tmc)(O)2]+ (tmc = 1,4,8,11 -tetramethyl-1,4,8,11-tetra-azacyclotetradecane)en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39860001519-
dc.identifier.scopuseid_2-s2.0-37049089049en_US
dc.identifier.issue20en_US
dc.identifier.spage1519en_US
dc.identifier.epage1521en_US
dc.identifier.isiWOS:A1986E558200014-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridCheng, WK=7402169559en_US

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