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Article: Synthesis and molecular structures of novel seven-co-ordinated oxo- and nitrido-rhenium(V) complexes of 2,2′:6′,2″:6″,2‴-quaterpyridine

TitleSynthesis and molecular structures of novel seven-co-ordinated oxo- and nitrido-rhenium(V) complexes of 2,2′:6′,2″:6″,2‴-quaterpyridine
Authors
Issue Date1992
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1992 n. 18, p. 2675-2677 How to Cite?
AbstractReaction of [ReO2(PPh3)2I] and [ReNCl2(PPh3)2] with 2,2′:6′,2″:6″,2‴-quaterpyridine (L) in methanol gave [ReO(L)(OMe)2]ClO4 and [ReN(L)(PPh3)Cl]ClO4 respectively. The structures determined by X-ray crystallography revealed seven-co-ordination around rhenium with Re=O and Re=N distances of 1.666(4) and 1.647(6) Å respectively. Intense metal-to-ligand charge-transfer transitions in the visible region and reversible ReVI-ReV redox couples have been observed for both complexes in acetonitrile.
Persistent Identifierhttp://hdl.handle.net/10722/168217
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorWang, YPen_US
dc.contributor.authorYeung, KSen_US
dc.contributor.authorWong, KYen_US
dc.contributor.authorPeng, SMen_US
dc.date.accessioned2012-10-08T03:16:23Z-
dc.date.available2012-10-08T03:16:23Z-
dc.date.issued1992en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1992 n. 18, p. 2675-2677en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168217-
dc.description.abstractReaction of [ReO2(PPh3)2I] and [ReNCl2(PPh3)2] with 2,2′:6′,2″:6″,2‴-quaterpyridine (L) in methanol gave [ReO(L)(OMe)2]ClO4 and [ReN(L)(PPh3)Cl]ClO4 respectively. The structures determined by X-ray crystallography revealed seven-co-ordination around rhenium with Re=O and Re=N distances of 1.666(4) and 1.647(6) Å respectively. Intense metal-to-ligand charge-transfer transitions in the visible region and reversible ReVI-ReV redox couples have been observed for both complexes in acetonitrile.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleSynthesis and molecular structures of novel seven-co-ordinated oxo- and nitrido-rhenium(V) complexes of 2,2′:6′,2″:6″,2‴-quaterpyridineen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9920002675en_US
dc.identifier.scopuseid_2-s2.0-37049078764en_US
dc.identifier.issue18en_US
dc.identifier.spage2675en_US
dc.identifier.epage2677en_US
dc.identifier.isiWOS:A1992JQ03100004-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridWang, YP=23069213200en_US
dc.identifier.scopusauthoridYeung, KS=36775309100en_US
dc.identifier.scopusauthoridWong, KY=7404760030en_US
dc.identifier.scopusauthoridPeng, SM=35464852200en_US

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