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Article: Ruthenium catalysed oxidation of alkanes with alkylhydroperoxides

TitleRuthenium catalysed oxidation of alkanes with alkylhydroperoxides
Authors
Issue Date1988
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1988 n. 21, p. 1406-1407 How to Cite?
AbstractThe cis-[RuII(L)2(OH2)2] 2+ complexes (L = substituted 2,2′-bipyridines or 1,10-phenanthrolines) catalyse oxidation of saturated hydrocarbons to alcohols and ketones by t-butylhydroperoxide; the low values of kinetic isotope effect (kH/kD = 3.5 for cyclohexane) and tertiary of secondary C-H bond relative reactivities (ktert/ksec ca. 6.5 for adamantane) are in a range expected for hydrogen atom abstraction by radical species.
Persistent Identifierhttp://hdl.handle.net/10722/168211
ISSN
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLau, TCen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorLee, WOen_US
dc.contributor.authorPoon, CKen_US
dc.date.accessioned2012-10-08T03:16:19Z-
dc.date.available2012-10-08T03:16:19Z-
dc.date.issued1988en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1988 n. 21, p. 1406-1407en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/168211-
dc.description.abstractThe cis-[RuII(L)2(OH2)2] 2+ complexes (L = substituted 2,2′-bipyridines or 1,10-phenanthrolines) catalyse oxidation of saturated hydrocarbons to alcohols and ketones by t-butylhydroperoxide; the low values of kinetic isotope effect (kH/kD = 3.5 for cyclohexane) and tertiary of secondary C-H bond relative reactivities (ktert/ksec ca. 6.5 for adamantane) are in a range expected for hydrogen atom abstraction by radical species.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleRuthenium catalysed oxidation of alkanes with alkylhydroperoxidesen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39880001406en_US
dc.identifier.scopuseid_2-s2.0-37049076667en_US
dc.identifier.issue21en_US
dc.identifier.spage1406en_US
dc.identifier.epage1407en_US
dc.identifier.isiWOS:A1988Q886600006-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridLau, TC=7102222310en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridLee, WO=7407087172en_US
dc.identifier.scopusauthoridPoon, CK=7202673504en_US

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