File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Ruthenium oxo complexes of macrocyclic tertiary amines. Synthesis, electrochemistry, and reactivities of ruthenium oxo complexes of meso-2,3,7,11,12-pentamethyl-3,7,11,17-tetra-azabicyclo[11.3.1]heptadeca-1(17), 13,15-triene (L1), and X-ray crystal structure of trans-[RuIVL1(O)(NCO)]ClO4

TitleRuthenium oxo complexes of macrocyclic tertiary amines. Synthesis, electrochemistry, and reactivities of ruthenium oxo complexes of meso-2,3,7,11,12-pentamethyl-3,7,11,17-tetra-azabicyclo[11.3.1]heptadeca-1(17), 13,15-triene (L1), and X-ray crystal structure of trans-[RuIVL1(O)(NCO)]ClO4
Authors
Issue Date1989
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1989 n. 10, p. 2011-2016 How to Cite?
AbstractThe new complexes trans-[RuIIIL1Cl2]Cl, trans-[RuIVL1(O)(NCO)]ClO4, and trans-[RuVI-L1(O)2][ClO4] 2{L1 = meso-2,3,7,11,12-pentamethyl-3,7,11,17-tetra-azabicyclo[1 1.3.1] heptadeca-1 (17),13,15-triene} have been prepared. Their redox chemistry was studied in comparison with the related Ru-L2-oxo system (L2 = 1,4,8,11-tetramethyl-1,4,8,11 -tetra-azacyclotetradecane). At pH 1.1, the E°, of the trans-[RuVIL1(O)2]2+/trans-[Ru IVL1(O)(H2O)]2+ couple occurs at 0.76 V vs. saturated calomel electrode. The complex cation trans-[RuIVL1(O)(NCO)]+ [space group P1, a = 7.765(1), b = 10.714(1), c = 14.076(1) Å, α = 80.49(1), β = 86.03(1), γ = 88.11(1)°, Z = 2, and R = 0.034 for 3 629 observed MO-Kα, data] has been determined by X-ray crystallography. The Ru=O distance is 1.777(2) Å. The N-Me groups all lie on the same side of the macrocyclic ring. The complex trans-[RuVIL1(O)2]2+ is capable of oxidizing alcohols, styrene, and toluene at room temperature.
Persistent Identifierhttp://hdl.handle.net/10722/168199
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_HK
dc.contributor.authorTang, WTen_HK
dc.contributor.authorLee, WOen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorLai, TFen_HK
dc.date.accessioned2012-10-08T03:16:12Z-
dc.date.available2012-10-08T03:16:12Z-
dc.date.issued1989en_HK
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1989 n. 10, p. 2011-2016en_HK
dc.identifier.issn1472-7773en_HK
dc.identifier.urihttp://hdl.handle.net/10722/168199-
dc.description.abstractThe new complexes trans-[RuIIIL1Cl2]Cl, trans-[RuIVL1(O)(NCO)]ClO4, and trans-[RuVI-L1(O)2][ClO4] 2{L1 = meso-2,3,7,11,12-pentamethyl-3,7,11,17-tetra-azabicyclo[1 1.3.1] heptadeca-1 (17),13,15-triene} have been prepared. Their redox chemistry was studied in comparison with the related Ru-L2-oxo system (L2 = 1,4,8,11-tetramethyl-1,4,8,11 -tetra-azacyclotetradecane). At pH 1.1, the E°, of the trans-[RuVIL1(O)2]2+/trans-[Ru IVL1(O)(H2O)]2+ couple occurs at 0.76 V vs. saturated calomel electrode. The complex cation trans-[RuIVL1(O)(NCO)]+ [space group P1, a = 7.765(1), b = 10.714(1), c = 14.076(1) Å, α = 80.49(1), β = 86.03(1), γ = 88.11(1)°, Z = 2, and R = 0.034 for 3 629 observed MO-Kα, data] has been determined by X-ray crystallography. The Ru=O distance is 1.777(2) Å. The N-Me groups all lie on the same side of the macrocyclic ring. The complex trans-[RuVIL1(O)2]2+ is capable of oxidizing alcohols, styrene, and toluene at room temperature.en_HK
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_HK
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_HK
dc.titleRuthenium oxo complexes of macrocyclic tertiary amines. Synthesis, electrochemistry, and reactivities of ruthenium oxo complexes of meso-2,3,7,11,12-pentamethyl-3,7,11,17-tetra-azabicyclo[11.3.1]heptadeca-1(17), 13,15-triene (L1), and X-ray crystal structure of trans-[RuIVL1(O)(NCO)]ClO4en_HK
dc.typeArticleen_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9890002011en_HK
dc.identifier.scopuseid_2-s2.0-37049073823en_HK
dc.identifier.issue10en_HK
dc.identifier.spage2011en_HK
dc.identifier.epage2016en_HK
dc.identifier.isiWOS:A1989AU59900018-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridTang, WT=15121154000en_HK
dc.identifier.scopusauthoridLee, WO=7407087172en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridLai, TF=7202203523en_HK

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats