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Article: Metal-metal interaction in a binuclear palladium(II) system. The (dσ* → pσ) transition and the X-ray crystal structure of [Pd2(dppm)2(CN)4] [dppm = bis(diphenylphosphino)methane]

TitleMetal-metal interaction in a binuclear palladium(II) system. The (dσ* → pσ) transition and the X-ray crystal structure of [Pd2(dppm)2(CN)4] [dppm = bis(diphenylphosphino)methane]
Authors
Issue Date1991
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1991 n. 6, p. 1639-1641 How to Cite?
AbstractThe complex [Pd2(dppm)2(CN)4] [dppm = bis(diphenylphosphino)methane] displays an intense absorption band at 272 nm (εmax = 5.2 × 104 dm3 mol-1 cm-1) attributed to the dσ* → pσ transition. Crystals of the complex are monoclinic, space group P21/n (no. 14, non-standard) with a = 11.476(2), b = 17.565(2), c = 13.964(2) Å, β = 95.07(1)° and Z = 2. The measured intramolecular Pd ⋯ Pd distance is 3.276(1) Å.
Persistent Identifierhttp://hdl.handle.net/10722/168191
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorYip, HKen_US
dc.contributor.authorLai, TFen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:16:06Z-
dc.date.available2012-10-08T03:16:06Z-
dc.date.issued1991en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1991 n. 6, p. 1639-1641en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168191-
dc.description.abstractThe complex [Pd2(dppm)2(CN)4] [dppm = bis(diphenylphosphino)methane] displays an intense absorption band at 272 nm (εmax = 5.2 × 104 dm3 mol-1 cm-1) attributed to the dσ* → pσ transition. Crystals of the complex are monoclinic, space group P21/n (no. 14, non-standard) with a = 11.476(2), b = 17.565(2), c = 13.964(2) Å, β = 95.07(1)° and Z = 2. The measured intramolecular Pd ⋯ Pd distance is 3.276(1) Å.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleMetal-metal interaction in a binuclear palladium(II) system. The (dσ* → pσ) transition and the X-ray crystal structure of [Pd2(dppm)2(CN)4] [dppm = bis(diphenylphosphino)methane]en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9910001639en_US
dc.identifier.scopuseid_2-s2.0-37049073241en_US
dc.identifier.issue6en_US
dc.identifier.spage1639en_US
dc.identifier.epage1641en_US
dc.identifier.isiWOS:A1991FR22300043-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridYip, HK=15068942100en_US
dc.identifier.scopusauthoridLai, TF=7202203523en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US

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