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Article: Luminescent 1D chain of platinum(II) terpyridyl units with p-dithiobenzoquinone organometallic linker: Self-aggregation imparted from Pt⋯Pt/π-π interactions

TitleLuminescent 1D chain of platinum(II) terpyridyl units with p-dithiobenzoquinone organometallic linker: Self-aggregation imparted from Pt⋯Pt/π-π interactions
Authors
Issue Date2007
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Dalton Transactions, 2007 n. 32, p. 3526-3530 How to Cite?
AbstractUnlike p-dithiobenzoquinone (1), which is extremely reactive and has never been isolated, the metal-stabilised p-dithiobenzoquinone [Cp*Ir(η4-C6H4S2)] (2c) was prepared and used as an efficient organometallic linker to construct novel supramolecular assemblies. Treatment of 2c with the electrophilic Pt(ii)(terpy) building blocks produced the supramolecular assembly {[Pt(terpy){Cp*Ir-p- (η4-C6H4S2)}Pt(terpy)][OTf] 4}n (3), which was fully characterised and its molecular structure was determined by X-ray crystallography. The structure of 3 revealed the presence of π-π and Pt⋯Pt interactions among individual molecules describing a 1D chain. Complex 3 showed unusual UV/Vis absorption and luminescence behaviour at low temperature, imparted from self-aggregation mediated by π-π and Pt⋯Pt interactions. © The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/168134
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorMoussa, Jen_US
dc.contributor.authorManChung Wong, Ken_US
dc.contributor.authorChamoreau, LMen_US
dc.contributor.authorAmouri, Hen_US
dc.contributor.authorWingWah Yam, Ven_US
dc.date.accessioned2012-10-08T03:15:31Z-
dc.date.available2012-10-08T03:15:31Z-
dc.date.issued2007en_US
dc.identifier.citationDalton Transactions, 2007 n. 32, p. 3526-3530en_US
dc.identifier.issn1477-9226en_US
dc.identifier.urihttp://hdl.handle.net/10722/168134-
dc.description.abstractUnlike p-dithiobenzoquinone (1), which is extremely reactive and has never been isolated, the metal-stabilised p-dithiobenzoquinone [Cp*Ir(η4-C6H4S2)] (2c) was prepared and used as an efficient organometallic linker to construct novel supramolecular assemblies. Treatment of 2c with the electrophilic Pt(ii)(terpy) building blocks produced the supramolecular assembly {[Pt(terpy){Cp*Ir-p- (η4-C6H4S2)}Pt(terpy)][OTf] 4}n (3), which was fully characterised and its molecular structure was determined by X-ray crystallography. The structure of 3 revealed the presence of π-π and Pt⋯Pt interactions among individual molecules describing a 1D chain. Complex 3 showed unusual UV/Vis absorption and luminescence behaviour at low temperature, imparted from self-aggregation mediated by π-π and Pt⋯Pt interactions. © The Royal Society of Chemistry.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofDalton Transactionsen_US
dc.titleLuminescent 1D chain of platinum(II) terpyridyl units with p-dithiobenzoquinone organometallic linker: Self-aggregation imparted from Pt⋯Pt/π-π interactionsen_US
dc.typeArticleen_US
dc.identifier.emailManChung Wong, K:wongmc@hku.hken_US
dc.identifier.emailWingWah Yam, V:wwyam@hku.hken_US
dc.identifier.authorityManChung Wong, K=rp00809en_US
dc.identifier.authorityWingWah Yam, V=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/b708922hen_US
dc.identifier.pmid17680042-
dc.identifier.scopuseid_2-s2.0-34547818153en_US
dc.identifier.hkuros136475-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-34547818153&selection=ref&src=s&origin=recordpageen_US
dc.identifier.issue32en_US
dc.identifier.spage3526en_US
dc.identifier.epage3530en_US
dc.identifier.isiWOS:000248583500010-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridMoussa, J=10640761700en_US
dc.identifier.scopusauthoridManChung Wong, K=8061067200en_US
dc.identifier.scopusauthoridChamoreau, LM=15839002100en_US
dc.identifier.scopusauthoridAmouri, H=7003923512en_US
dc.identifier.scopusauthoridWingWah Yam, V=18539304700en_US

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