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Article: Synthesis, structure and luminescence studies of heterometallic gold(I)-copper(I) and -silver(I) alkynyl clusters/aggregates

TitleSynthesis, structure and luminescence studies of heterometallic gold(I)-copper(I) and -silver(I) alkynyl clusters/aggregates
Authors
Issue Date2007
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/pps
Citation
Photochemical And Photobiological Sciences, 2007, v. 6 n. 4, p. 365-371 How to Cite?
AbstractA series of pentanuclear gold(i)-copper(i) and -silver(i) mixed-metal alkynyl complexes, [nBu4N][Au3M 2(C≡CC6H4R-p)6] [M = Cu, R = OMe, OnBu, OnHex, Me, Et; M = Ag, R = Et, O nHex] have been synthesized. The complexes were found to be emissive both in the solid state and in fluid solutions. DFT calculations at the B3LYP level of theory were performed on [Au3M2(C≡CC 6H4Me-p)6]- (M = Cu, Ag) to provide an understanding on the electronic structure of the complexes. © The Royal Society of Chemistry and Owner Societies.
Persistent Identifierhttp://hdl.handle.net/10722/168100
ISSN
2015 Impact Factor: 2.235
2015 SCImago Journal Rankings: 0.829
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYip, SKen_US
dc.contributor.authorChan, CLen_US
dc.contributor.authorLam, WHen_US
dc.contributor.authorCheung, KKen_US
dc.contributor.authorYam, VWWen_US
dc.date.accessioned2012-10-08T03:15:05Z-
dc.date.available2012-10-08T03:15:05Z-
dc.date.issued2007en_US
dc.identifier.citationPhotochemical And Photobiological Sciences, 2007, v. 6 n. 4, p. 365-371en_US
dc.identifier.issn1474-905Xen_US
dc.identifier.urihttp://hdl.handle.net/10722/168100-
dc.description.abstractA series of pentanuclear gold(i)-copper(i) and -silver(i) mixed-metal alkynyl complexes, [nBu4N][Au3M 2(C≡CC6H4R-p)6] [M = Cu, R = OMe, OnBu, OnHex, Me, Et; M = Ag, R = Et, O nHex] have been synthesized. The complexes were found to be emissive both in the solid state and in fluid solutions. DFT calculations at the B3LYP level of theory were performed on [Au3M2(C≡CC 6H4Me-p)6]- (M = Cu, Ag) to provide an understanding on the electronic structure of the complexes. © The Royal Society of Chemistry and Owner Societies.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/ppsen_US
dc.relation.ispartofPhotochemical and Photobiological Sciencesen_US
dc.subject.meshAlkynes - Chemistryen_US
dc.subject.meshCopper - Chemistryen_US
dc.subject.meshCrystallography, X-Rayen_US
dc.subject.meshElectronsen_US
dc.subject.meshGold - Chemistryen_US
dc.subject.meshLuminescent Measurements - Methodsen_US
dc.subject.meshModels, Chemicalen_US
dc.subject.meshModels, Molecularen_US
dc.subject.meshOrganometallic Compounds - Chemical Synthesis - Chemistryen_US
dc.subject.meshSilver - Chemistryen_US
dc.subject.meshSolutions - Chemistryen_US
dc.titleSynthesis, structure and luminescence studies of heterometallic gold(I)-copper(I) and -silver(I) alkynyl clusters/aggregatesen_US
dc.typeArticleen_US
dc.identifier.emailLam, WH:chsue@hku.hken_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityLam, WH=rp00719en_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/b612334aen_US
dc.identifier.pmid17404630-
dc.identifier.scopuseid_2-s2.0-34047263783en_US
dc.identifier.hkuros131669-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-34047263783&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume6en_US
dc.identifier.issue4en_US
dc.identifier.spage365en_US
dc.identifier.epage371en_US
dc.identifier.isiWOS:000245380400005-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridYip, SK=7102133674en_US
dc.identifier.scopusauthoridChan, CL=7404813631en_US
dc.identifier.scopusauthoridLam, WH=26642862800en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US

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