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Article: Binuclear complexes of palladium(II) containing 1,8-diisocyano-p-menthane

TitleBinuclear complexes of palladium(II) containing 1,8-diisocyano-p-menthane
Authors
Issue Date1984
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 1984, v. 23 n. 17, p. 2572-2575 How to Cite?
AbstractWell-characterized binuclear isocyano complexes of palladium(II) are obtained with the bridging ligand 1,8-diisocyano-p-menthane (DMB). The ion [Pd2(DMB)4]4+ reacts with X (Cl- or Br-) to give [Pd2(DMB)4X]3+, where the X is positioned between the metal atoms, encapsulated in the complex. Reaction with I- leads to an entirely different product, Pd2(DMB)2I4, which has been characterized by X-ray crystallography: Pd2C24N4H36I4 crystallizes in the monoclinic space group P21/n with a = 11.766 (4) Å, b = 15.123 (8) Å, c = 9.703 (2) Å, β = 93.93 (2)°, and Z = 2. The Pd atoms are square-planar coordinated to two CN groups and two I atoms; the DMB ligands are disordered across a center of symmetry. The coordination planes of the Pd atoms are tilted 35° from the perpendicular to the Pd-Pd vector, and a fifth (axial) site is occupied by an I atom from the other half of the dimer. The Pd⋯Pd distance, 4.582 (1) Å, is such that the ion [Pd2(DMB)4]4+ can accommodate a Br- or Cl- ion between the Pd atoms. © 1984 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/168084
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorHerbstein, FHen_US
dc.contributor.authorSchaefer, WPen_US
dc.contributor.authorMarsh, REen_US
dc.contributor.authorGray, HBen_US
dc.date.accessioned2012-10-08T03:14:54Z-
dc.date.available2012-10-08T03:14:54Z-
dc.date.issued1984en_US
dc.identifier.citationInorganic Chemistry, 1984, v. 23 n. 17, p. 2572-2575en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/10722/168084-
dc.description.abstractWell-characterized binuclear isocyano complexes of palladium(II) are obtained with the bridging ligand 1,8-diisocyano-p-menthane (DMB). The ion [Pd2(DMB)4]4+ reacts with X (Cl- or Br-) to give [Pd2(DMB)4X]3+, where the X is positioned between the metal atoms, encapsulated in the complex. Reaction with I- leads to an entirely different product, Pd2(DMB)2I4, which has been characterized by X-ray crystallography: Pd2C24N4H36I4 crystallizes in the monoclinic space group P21/n with a = 11.766 (4) Å, b = 15.123 (8) Å, c = 9.703 (2) Å, β = 93.93 (2)°, and Z = 2. The Pd atoms are square-planar coordinated to two CN groups and two I atoms; the DMB ligands are disordered across a center of symmetry. The coordination planes of the Pd atoms are tilted 35° from the perpendicular to the Pd-Pd vector, and a fifth (axial) site is occupied by an I atom from the other half of the dimer. The Pd⋯Pd distance, 4.582 (1) Å, is such that the ion [Pd2(DMB)4]4+ can accommodate a Br- or Cl- ion between the Pd atoms. © 1984 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_US
dc.relation.ispartofInorganic Chemistryen_US
dc.titleBinuclear complexes of palladium(II) containing 1,8-diisocyano-p-menthaneen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-33845470117en_US
dc.identifier.volume23en_US
dc.identifier.issue17en_US
dc.identifier.spage2572en_US
dc.identifier.epage2575en_US
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridHerbstein, FH=7004252854en_US
dc.identifier.scopusauthoridSchaefer, WP=7103192229en_US
dc.identifier.scopusauthoridMarsh, RE=7202654544en_US
dc.identifier.scopusauthoridGray, HB=36047602600en_US

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