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Article: Synthesis and photophysics of luminescent rhenium(I) acetylides-precursors for organometallic rigid-rod materials. X-ray crystal structures of [Re(tBu2bpy)(CO)3(tBuC≡C)] and [Re(tBu2bpy)(CO)3Cl]

TitleSynthesis and photophysics of luminescent rhenium(I) acetylides-precursors for organometallic rigid-rod materials. X-ray crystal structures of [Re(tBu2bpy)(CO)3(tBuC≡C)] and [Re(tBu2bpy)(CO)3Cl]
Authors
Issue Date1995
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 1995, v. 14 n. 6, p. 2749-2753 How to Cite?
AbstractA series of rhenium(I) diimine acetylide complexes [Re(tBu2bpy)(CO)3(RC≡C)] (R = tBu (2), Me3Si (3), Ph (4)) have been synthesized and shown to exhibit rich photoluminescent behavior at room temperature. The X-ray crystal structures of [Re(tBu2bpy)(CO)3(tBuC≡C)] and its precursor complex [Re(tBu2bpy)(CO)3Cl] have also been determined. Both 1 and 2 crystallize in the monoclinic space group P21/n with a = 16.814(1) Å, b =12.195(1) Å, c = 22.599(2) Å, and β = 100.87(1)° for 1 and a = 11.116(1) Å, b = 13.128(1) Å, c = 18.328(2) Å, and β = 94.49(1)° for 2. © 1995 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/168063
ISSN
2015 Impact Factor: 4.186
2015 SCImago Journal Rankings: 2.043
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorLau, VCYen_US
dc.contributor.authorCheung, KKen_US
dc.date.accessioned2012-10-08T03:14:41Z-
dc.date.available2012-10-08T03:14:41Z-
dc.date.issued1995en_US
dc.identifier.citationOrganometallics, 1995, v. 14 n. 6, p. 2749-2753en_US
dc.identifier.issn0276-7333en_US
dc.identifier.urihttp://hdl.handle.net/10722/168063-
dc.description.abstractA series of rhenium(I) diimine acetylide complexes [Re(tBu2bpy)(CO)3(RC≡C)] (R = tBu (2), Me3Si (3), Ph (4)) have been synthesized and shown to exhibit rich photoluminescent behavior at room temperature. The X-ray crystal structures of [Re(tBu2bpy)(CO)3(tBuC≡C)] and its precursor complex [Re(tBu2bpy)(CO)3Cl] have also been determined. Both 1 and 2 crystallize in the monoclinic space group P21/n with a = 16.814(1) Å, b =12.195(1) Å, c = 22.599(2) Å, and β = 100.87(1)° for 1 and a = 11.116(1) Å, b = 13.128(1) Å, c = 18.328(2) Å, and β = 94.49(1)° for 2. © 1995 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_US
dc.relation.ispartofOrganometallicsen_US
dc.titleSynthesis and photophysics of luminescent rhenium(I) acetylides-precursors for organometallic rigid-rod materials. X-ray crystal structures of [Re(tBu2bpy)(CO)3(tBuC≡C)] and [Re(tBu2bpy)(CO)3Cl]en_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/om00006a022-
dc.identifier.scopuseid_2-s2.0-33750548190en_US
dc.identifier.hkuros15519-
dc.identifier.volume14en_US
dc.identifier.issue6en_US
dc.identifier.spage2749en_US
dc.identifier.epage2753en_US
dc.identifier.isiWOS:A1995RD85600022-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridLau, VCY=7005811453en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US

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