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Article: Co-ordination chemistry of the organometallic tridentate ligand trans-[Ru(2-Ph2PC5H4N-P)2(CO)3] and crystal structures of metal complex derivatives

TitleCo-ordination chemistry of the organometallic tridentate ligand trans-[Ru(2-Ph2PC5H4N-P)2(CO)3] and crystal structures of metal complex derivatives
Authors
Issue Date1998
Citation
Journal Of The Chemical Society - Dalton Transactions, 1998 n. 5, p. 803-809 How to Cite?
AbstractThe complex trans-[Ru(2-Ph 2PC 5H 4N-P) 2(CO) 3] 1 reacted with Lewis acids such as ZnCl 2, CdCl 2, Cd(ClO 4) 2 and HgCl 2 to give a series of heterometallic [RuM(μ-2-Ph 2PC 5H 4N) 2X(X′)] (M = Zn, Cd or Hg; X = Cl; X′ = Cl, ClO 4 or HgCl 3). Crystal structures of [RuZn(μ-2-Ph 2PC 5H 4N) 2(CO) 3Cl 2] 2, [RuCd(μ-2-Ph 2PC 5H 4N)2(CO) 3Cl 2]·MeOH 3· MeOH, [RuCd(μ-2-Ph 2PC 5H 4N) 2(CO) 3(ClO 4) 2]·CHCl 3 4·CHCl 3 and [RuHg(μ-Ph 2PC 5H 4N) 2(CO) 3Cl][HgCl 3] 5 were determined with Ru-Zn (2), Ru-Cd (3), Ru-Cd (4) and Ru-Hg (5) distances being 2.659(1), 2.771(1), 2.705(1) and 2.622(1) Å, respectively. Different co-ordination modes are present in these heterometallic complexes and their spectroscopic properties were studied. The donor-acceptor bonding interactions of complexes 2-5 are discussed.
Persistent Identifierhttp://hdl.handle.net/10722/168055
ISSN
1999 Impact Factor: 2.31
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorChan, WHen_US
dc.contributor.authorZhang, ZZen_US
dc.contributor.authorMak, TCWen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:14:36Z-
dc.date.available2012-10-08T03:14:36Z-
dc.date.issued1998en_US
dc.identifier.citationJournal Of The Chemical Society - Dalton Transactions, 1998 n. 5, p. 803-809en_US
dc.identifier.issn0300-9246en_US
dc.identifier.urihttp://hdl.handle.net/10722/168055-
dc.description.abstractThe complex trans-[Ru(2-Ph 2PC 5H 4N-P) 2(CO) 3] 1 reacted with Lewis acids such as ZnCl 2, CdCl 2, Cd(ClO 4) 2 and HgCl 2 to give a series of heterometallic [RuM(μ-2-Ph 2PC 5H 4N) 2X(X′)] (M = Zn, Cd or Hg; X = Cl; X′ = Cl, ClO 4 or HgCl 3). Crystal structures of [RuZn(μ-2-Ph 2PC 5H 4N) 2(CO) 3Cl 2] 2, [RuCd(μ-2-Ph 2PC 5H 4N)2(CO) 3Cl 2]·MeOH 3· MeOH, [RuCd(μ-2-Ph 2PC 5H 4N) 2(CO) 3(ClO 4) 2]·CHCl 3 4·CHCl 3 and [RuHg(μ-Ph 2PC 5H 4N) 2(CO) 3Cl][HgCl 3] 5 were determined with Ru-Zn (2), Ru-Cd (3), Ru-Cd (4) and Ru-Hg (5) distances being 2.659(1), 2.771(1), 2.705(1) and 2.622(1) Å, respectively. Different co-ordination modes are present in these heterometallic complexes and their spectroscopic properties were studied. The donor-acceptor bonding interactions of complexes 2-5 are discussed.en_US
dc.languageengen_US
dc.relation.ispartofJournal of the Chemical Society - Dalton Transactionsen_US
dc.titleCo-ordination chemistry of the organometallic tridentate ligand trans-[Ru(2-Ph2PC5H4N-P)2(CO)3] and crystal structures of metal complex derivativesen_US
dc.typeArticleen_US
dc.identifier.emailChan, WH:waichan@hku.hken_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChan, WH=rp00667en_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/a706958h-
dc.identifier.scopuseid_2-s2.0-33749116756en_US
dc.identifier.hkuros32038-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33749116756&selection=ref&src=s&origin=recordpageen_US
dc.identifier.issue5en_US
dc.identifier.spage803en_US
dc.identifier.epage809en_US
dc.identifier.isiWOS:000072655000013-
dc.identifier.scopusauthoridChan, WH=13310083000en_US
dc.identifier.scopusauthoridZhang, ZZ=13405280100en_US
dc.identifier.scopusauthoridMak, TCW=7401931058en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US

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