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Article: A novel luminescent iridium(I)-cadmium(II) binuclear complex displaying a long-lived metal-to-ligand charge-transfer excited state. Synthesis and structural characterisation of I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine]

TitleA novel luminescent iridium(I)-cadmium(II) binuclear complex displaying a long-lived metal-to-ligand charge-transfer excited state. Synthesis and structural characterisation of I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine]
Authors
Issue Date1997
Citation
Journal Of The Chemical Society - Dalton Transactions, 1997 n. 19, p. 3409-3410 How to Cite?
AbstractThe first binuclear IrI-CdII complex to be structurally characterised, I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine], has a donor-acceptor metal-metal bond of length 2.784(1) Å; at room temperature, excitation of a solid sample of the complex with UV light led to a red emission at 739 nm with a lifetime of 6.48 μs that presumably originates from a 3MLCT excited state.
Persistent Identifierhttp://hdl.handle.net/10722/168054
ISSN
1999 Impact Factor: 2.31
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorKuang, SMen_US
dc.contributor.authorXue, Fen_US
dc.contributor.authorZhang, ZZen_US
dc.contributor.authorXue, WMen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorMak, TCWen_US
dc.date.accessioned2012-10-08T03:14:36Z-
dc.date.available2012-10-08T03:14:36Z-
dc.date.issued1997en_US
dc.identifier.citationJournal Of The Chemical Society - Dalton Transactions, 1997 n. 19, p. 3409-3410en_US
dc.identifier.issn0300-9246en_US
dc.identifier.urihttp://hdl.handle.net/10722/168054-
dc.description.abstractThe first binuclear IrI-CdII complex to be structurally characterised, I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine], has a donor-acceptor metal-metal bond of length 2.784(1) Å; at room temperature, excitation of a solid sample of the complex with UV light led to a red emission at 739 nm with a lifetime of 6.48 μs that presumably originates from a 3MLCT excited state.en_US
dc.languageengen_US
dc.relation.ispartofJournal of the Chemical Society - Dalton Transactionsen_US
dc.titleA novel luminescent iridium(I)-cadmium(II) binuclear complex displaying a long-lived metal-to-ligand charge-transfer excited state. Synthesis and structural characterisation of I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine]en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/A705431I-
dc.identifier.scopuseid_2-s2.0-33749113214en_US
dc.identifier.hkuros32010-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33749113214&selection=ref&src=s&origin=recordpageen_US
dc.identifier.issue19en_US
dc.identifier.spage3409en_US
dc.identifier.epage3410en_US
dc.identifier.isiWOS:A1997YB26400004-
dc.identifier.scopusauthoridKuang, SM=7006330379en_US
dc.identifier.scopusauthoridXue, F=15052685300en_US
dc.identifier.scopusauthoridZhang, ZZ=13405280100en_US
dc.identifier.scopusauthoridXue, WM=7103165059en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridMak, TCW=35230525700en_US

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