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Article: Synthesis, emission and molecular orbital studies of luminescent zirconium thiolate complexes. Crystal structure of [Zr(η5-C5Me5)2-(SBu n)2]

TitleSynthesis, emission and molecular orbital studies of luminescent zirconium thiolate complexes. Crystal structure of [Zr(η5-C5Me5)2-(SBu n)2]
Authors
Issue Date1998
Citation
Journal Of The Chemical Society - Dalton Transactions, 1998 n. 11, p. 1819-1823 How to Cite?
AbstractA series of luminescent zirconium thiolate complexes [Zr(η5-C5Me5)2(ER)2] (E = S, R = Bun, C6H4But-p, C6H4Cl-p or Ph; E = Se, R = Ph) have been synthesized by the reaction of [Zr(η5-C5Me5)2Cl2] with NaER, and shown to exhibit rich luminescence behavior. The crystal structure of [Zr(η5-C5Me5)2(SBu n)2] has been determined. Fenske-Hall molecular orbital calculations on the zirconium thiolate complexes revealed a thiolate-based HOMO and a LUMO that is mainly composed of zirconium d character.
Persistent Identifierhttp://hdl.handle.net/10722/168042
ISSN
1999 Impact Factor: 2.31
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorQi, GZen_US
dc.contributor.authorCheung, KKen_US
dc.date.accessioned2012-10-08T03:14:29Z-
dc.date.available2012-10-08T03:14:29Z-
dc.date.issued1998en_US
dc.identifier.citationJournal Of The Chemical Society - Dalton Transactions, 1998 n. 11, p. 1819-1823en_US
dc.identifier.issn0300-9246en_US
dc.identifier.urihttp://hdl.handle.net/10722/168042-
dc.description.abstractA series of luminescent zirconium thiolate complexes [Zr(η5-C5Me5)2(ER)2] (E = S, R = Bun, C6H4But-p, C6H4Cl-p or Ph; E = Se, R = Ph) have been synthesized by the reaction of [Zr(η5-C5Me5)2Cl2] with NaER, and shown to exhibit rich luminescence behavior. The crystal structure of [Zr(η5-C5Me5)2(SBu n)2] has been determined. Fenske-Hall molecular orbital calculations on the zirconium thiolate complexes revealed a thiolate-based HOMO and a LUMO that is mainly composed of zirconium d character.en_US
dc.languageengen_US
dc.relation.ispartofJournal of the Chemical Society - Dalton Transactionsen_US
dc.titleSynthesis, emission and molecular orbital studies of luminescent zirconium thiolate complexes. Crystal structure of [Zr(η5-C5Me5)2-(SBu n)2]en_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/A800122G-
dc.identifier.scopuseid_2-s2.0-33748515909en_US
dc.identifier.hkuros31391-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33748515909&selection=ref&src=s&origin=recordpageen_US
dc.identifier.issue11en_US
dc.identifier.spage1819en_US
dc.identifier.epage1823en_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridQi, GZ=8300870200en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US

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