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Article: Synthesis, emission and molecular orbital studies of luminescent zirconium thiolate complexes. Crystal structure of [Zr(η5-C5Me5)2-(SBu n)2]
Title | Synthesis, emission and molecular orbital studies of luminescent zirconium thiolate complexes. Crystal structure of [Zr(η5-C5Me5)2-(SBu n)2] |
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Authors | |
Issue Date | 1998 |
Citation | Journal Of The Chemical Society - Dalton Transactions, 1998 n. 11, p. 1819-1823 How to Cite? |
Abstract | A series of luminescent zirconium thiolate complexes [Zr(η5-C5Me5)2(ER)2] (E = S, R = Bun, C6H4But-p, C6H4Cl-p or Ph; E = Se, R = Ph) have been synthesized by the reaction of [Zr(η5-C5Me5)2Cl2] with NaER, and shown to exhibit rich luminescence behavior. The crystal structure of [Zr(η5-C5Me5)2(SBu n)2] has been determined. Fenske-Hall molecular orbital calculations on the zirconium thiolate complexes revealed a thiolate-based HOMO and a LUMO that is mainly composed of zirconium d character. |
Persistent Identifier | http://hdl.handle.net/10722/168042 |
ISSN | |
References |
DC Field | Value | Language |
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dc.contributor.author | Yam, VWW | en_US |
dc.contributor.author | Qi, GZ | en_US |
dc.contributor.author | Cheung, KK | en_US |
dc.date.accessioned | 2012-10-08T03:14:29Z | - |
dc.date.available | 2012-10-08T03:14:29Z | - |
dc.date.issued | 1998 | en_US |
dc.identifier.citation | Journal Of The Chemical Society - Dalton Transactions, 1998 n. 11, p. 1819-1823 | en_US |
dc.identifier.issn | 0300-9246 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168042 | - |
dc.description.abstract | A series of luminescent zirconium thiolate complexes [Zr(η5-C5Me5)2(ER)2] (E = S, R = Bun, C6H4But-p, C6H4Cl-p or Ph; E = Se, R = Ph) have been synthesized by the reaction of [Zr(η5-C5Me5)2Cl2] with NaER, and shown to exhibit rich luminescence behavior. The crystal structure of [Zr(η5-C5Me5)2(SBu n)2] has been determined. Fenske-Hall molecular orbital calculations on the zirconium thiolate complexes revealed a thiolate-based HOMO and a LUMO that is mainly composed of zirconium d character. | en_US |
dc.language | eng | en_US |
dc.relation.ispartof | Journal of the Chemical Society - Dalton Transactions | en_US |
dc.title | Synthesis, emission and molecular orbital studies of luminescent zirconium thiolate complexes. Crystal structure of [Zr(η5-C5Me5)2-(SBu n)2] | en_US |
dc.type | Article | en_US |
dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_US |
dc.identifier.authority | Yam, VWW=rp00822 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/A800122G | - |
dc.identifier.scopus | eid_2-s2.0-33748515909 | en_US |
dc.identifier.hkuros | 31391 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-33748515909&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.issue | 11 | en_US |
dc.identifier.spage | 1819 | en_US |
dc.identifier.epage | 1823 | en_US |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_US |
dc.identifier.scopusauthorid | Qi, GZ=8300870200 | en_US |
dc.identifier.scopusauthorid | Cheung, KK=7402406613 | en_US |
dc.identifier.issnl | 0300-9246 | - |