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Article: High-Valent Complexes of Ruthenium and Osmium

TitleHigh-Valent Complexes of Ruthenium and Osmium
Authors
Issue Date1992
Citation
Advances In Inorganic Chemistry, 1992, v. 39 C, p. 233-325 How to Cite?
AbstractThe study of high-valent complexes of osmium (Os) and ruthenium (Ru), especially those involving multiple bonding to heteroatoms, has greatly expanded during the past decade. Osmium and ruthenium, being distinguished from other elements by the variety of the oxidation states they display in their complexes, have attracted a plethora of study on their coordination chemistry. The chapter focuses on the high oxidation state chemistry of osmium and ruthenium—that is, those complexes with oxidation states of + IV to + VIII. In this review, the materials have been organized according to the formal oxidation states of the metal and the discussions focus mainly on the structural as well as reactivity patterns of these complexes. The chapter discusses those complexes that may reasonably be considered to involve discrete molecular units, having metal–ligand multiple bonding. Polynuclear derivatives, in which the ligand bridges two or more metals, are also mentioned in the chapter. The chapter explains high-valent chemistry of ruthenium coordination complexes with various classes of ligands as comprehensive as possible.
Persistent Identifierhttp://hdl.handle.net/10722/168033
ISSN
2015 Impact Factor: 4.25
2015 SCImago Journal Rankings: 1.132
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorYam, VWWen_US
dc.date.accessioned2012-10-08T03:14:23Z-
dc.date.available2012-10-08T03:14:23Z-
dc.date.issued1992en_US
dc.identifier.citationAdvances In Inorganic Chemistry, 1992, v. 39 C, p. 233-325en_US
dc.identifier.issn0898-8838en_US
dc.identifier.urihttp://hdl.handle.net/10722/168033-
dc.description.abstractThe study of high-valent complexes of osmium (Os) and ruthenium (Ru), especially those involving multiple bonding to heteroatoms, has greatly expanded during the past decade. Osmium and ruthenium, being distinguished from other elements by the variety of the oxidation states they display in their complexes, have attracted a plethora of study on their coordination chemistry. The chapter focuses on the high oxidation state chemistry of osmium and ruthenium—that is, those complexes with oxidation states of + IV to + VIII. In this review, the materials have been organized according to the formal oxidation states of the metal and the discussions focus mainly on the structural as well as reactivity patterns of these complexes. The chapter discusses those complexes that may reasonably be considered to involve discrete molecular units, having metal–ligand multiple bonding. Polynuclear derivatives, in which the ligand bridges two or more metals, are also mentioned in the chapter. The chapter explains high-valent chemistry of ruthenium coordination complexes with various classes of ligands as comprehensive as possible.-
dc.languageengen_US
dc.relation.ispartofAdvances in Inorganic Chemistryen_US
dc.titleHigh-Valent Complexes of Ruthenium and Osmiumen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_OA_fulltexten_US
dc.identifier.doi10.1016/S0898-8838(08)60261-5en_US
dc.identifier.scopuseid_2-s2.0-33746675007en_US
dc.identifier.volume39en_US
dc.identifier.issueCen_US
dc.identifier.spage233en_US
dc.identifier.epage325en_US
dc.identifier.isiWOS:A1992MG05200004-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US

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