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Article: Synthesis and reactivity of cobalt boryl complexes

TitleSynthesis and reactivity of cobalt boryl complexes
Authors
Issue Date2006
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Dalton Transactions, 2006, v. 6 n. 11, p. 1370-1373 How to Cite?
AbstractThe synthesis and reactivity of phosphine-cobalt boryls, were investigated. The reactivity studies have shown that alkyne diboration takes place and borylation of aryl bromides is possible with low selectivity. Boryl transfer was investigated initially by carrying out reactions between equimolar amounts of B2(cat)2, [Co (PMe3)4] and a 4-substituted aryl bromide in THF at room temperature. The results show that paramagnetic Co (II) bisboryls can be formed from Co (0) precursors and diborane (4) compounds.
Persistent Identifierhttp://hdl.handle.net/10722/168008
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorAdams, CJen_US
dc.contributor.authorBaber, RAen_US
dc.contributor.authorBatsanov, ASen_US
dc.contributor.authorBramham, Gen_US
dc.contributor.authorCharmant, JPHen_US
dc.contributor.authorHaddow, MFen_US
dc.contributor.authorHoward, JAKen_US
dc.contributor.authorLam, WHen_US
dc.contributor.authorLin, Zen_US
dc.contributor.authorMarder, TBen_US
dc.contributor.authorNorman, NCen_US
dc.contributor.authorOrpen, AGen_US
dc.date.accessioned2012-10-08T03:14:03Z-
dc.date.available2012-10-08T03:14:03Z-
dc.date.issued2006en_US
dc.identifier.citationDalton Transactions, 2006, v. 6 n. 11, p. 1370-1373en_US
dc.identifier.issn1477-9226en_US
dc.identifier.urihttp://hdl.handle.net/10722/168008-
dc.description.abstractThe synthesis and reactivity of phosphine-cobalt boryls, were investigated. The reactivity studies have shown that alkyne diboration takes place and borylation of aryl bromides is possible with low selectivity. Boryl transfer was investigated initially by carrying out reactions between equimolar amounts of B2(cat)2, [Co (PMe3)4] and a 4-substituted aryl bromide in THF at room temperature. The results show that paramagnetic Co (II) bisboryls can be formed from Co (0) precursors and diborane (4) compounds.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofDalton Transactionsen_US
dc.titleSynthesis and reactivity of cobalt boryl complexesen_US
dc.typeArticleen_US
dc.identifier.emailLam, WH:chsue@hku.hken_US
dc.identifier.authorityLam, WH=rp00719en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/b516594fen_US
dc.identifier.pmid16518504-
dc.identifier.scopuseid_2-s2.0-33644771345en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33644771345&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume6en_US
dc.identifier.issue11en_US
dc.identifier.spage1370en_US
dc.identifier.epage1373en_US
dc.identifier.isiWOS:000236280100012-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridAdams, CJ=7402375848en_US
dc.identifier.scopusauthoridBaber, RA=8235380500en_US
dc.identifier.scopusauthoridBatsanov, AS=35448086200en_US
dc.identifier.scopusauthoridBramham, G=12767045800en_US
dc.identifier.scopusauthoridCharmant, JPH=7004139923en_US
dc.identifier.scopusauthoridHaddow, MF=8948446800en_US
dc.identifier.scopusauthoridHoward, JAK=35444331700en_US
dc.identifier.scopusauthoridLam, WH=26642862800en_US
dc.identifier.scopusauthoridLin, Z=7404230177en_US
dc.identifier.scopusauthoridMarder, TB=7006433068en_US
dc.identifier.scopusauthoridNorman, NC=7005094633en_US
dc.identifier.scopusauthoridOrpen, AG=7004717067en_US

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