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Article: Synthesis and characterization of the first transition-metal fullerene complexes containing bis(η6-benzene)chromium moieties
Title | Synthesis and characterization of the first transition-metal fullerene complexes containing bis(η6-benzene)chromium moieties |
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Authors | |
Keywords | [60]Fullerene Bis(η 6-diphenylphosphinobenzene)chromium Crystal structures Molybdenum Palladium Platinum |
Issue Date | 2006 |
Publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem |
Citation | Journal Of Organometallic Chemistry, 2006, v. 691 n. 4, p. 787-792 How to Cite? |
Abstract | While photochemical reaction of C60 with an equimolar amount of Mo(CO)4(η6-Ph2PC6H 5)2Cr (1) in toluene at room temperature produced bimetallic Mo/Cr fullerene complex fac/mer-(η2-C 60)Mo(CO)3[(η6-Ph2PC 6H5)2Cr] (2) in 87% yield, the thermal reaction of an equimolar mixture of C60, M(dba)2 (M = Pd, Pt; dba = dibenzylideneacetone) and (η6-Ph2PC 6H5)2Cr (3) in toluene at room temperature afforded bimetallic M/Cr fullerene complexes (η2-C 60)M[(η6-Ph2PC6H 5)2Cr] (4, M = Pd; 5, M = Pt) in 88% and 92% yields, respectively. Products 2, 4 and 5 are the first transition-metal fullerene complexes containing bis(η6-benzene)chromium moieties. While 2, 4 and 5 were characterized by elemental analysis and spectroscopy, the crystal molecular structures of 4 along with the starting materials 1 and 3 have been determined by X-ray diffraction techniques. © 2005 Elsevier B.V. All rights reserved. |
Persistent Identifier | http://hdl.handle.net/10722/167993 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Song, LC | en_HK |
dc.contributor.author | Yu, GA | en_HK |
dc.contributor.author | Hu, QM | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.contributor.author | Zhu, N | en_HK |
dc.contributor.author | Huang, JS | en_HK |
dc.date.accessioned | 2012-10-08T03:13:51Z | - |
dc.date.available | 2012-10-08T03:13:51Z | - |
dc.date.issued | 2006 | en_HK |
dc.identifier.citation | Journal Of Organometallic Chemistry, 2006, v. 691 n. 4, p. 787-792 | en_HK |
dc.identifier.issn | 0022-328X | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/167993 | - |
dc.description.abstract | While photochemical reaction of C60 with an equimolar amount of Mo(CO)4(η6-Ph2PC6H 5)2Cr (1) in toluene at room temperature produced bimetallic Mo/Cr fullerene complex fac/mer-(η2-C 60)Mo(CO)3[(η6-Ph2PC 6H5)2Cr] (2) in 87% yield, the thermal reaction of an equimolar mixture of C60, M(dba)2 (M = Pd, Pt; dba = dibenzylideneacetone) and (η6-Ph2PC 6H5)2Cr (3) in toluene at room temperature afforded bimetallic M/Cr fullerene complexes (η2-C 60)M[(η6-Ph2PC6H 5)2Cr] (4, M = Pd; 5, M = Pt) in 88% and 92% yields, respectively. Products 2, 4 and 5 are the first transition-metal fullerene complexes containing bis(η6-benzene)chromium moieties. While 2, 4 and 5 were characterized by elemental analysis and spectroscopy, the crystal molecular structures of 4 along with the starting materials 1 and 3 have been determined by X-ray diffraction techniques. © 2005 Elsevier B.V. All rights reserved. | en_HK |
dc.language | eng | en_US |
dc.publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem | en_HK |
dc.relation.ispartof | Journal of Organometallic Chemistry | en_HK |
dc.subject | [60]Fullerene | en_HK |
dc.subject | Bis(η 6-diphenylphosphinobenzene)chromium | en_HK |
dc.subject | Crystal structures | en_HK |
dc.subject | Molybdenum | en_HK |
dc.subject | Palladium | en_HK |
dc.subject | Platinum | en_HK |
dc.title | Synthesis and characterization of the first transition-metal fullerene complexes containing bis(η6-benzene)chromium moieties | en_HK |
dc.type | Article | en_HK |
dc.identifier.email | Che, CM: cmche@hku.hk | en_HK |
dc.identifier.email | Zhu, N: nzhu@hkucc.hku.hk | en_HK |
dc.identifier.email | Huang, JS: jshuang@hku.hk | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.identifier.authority | Zhu, N=rp00845 | en_HK |
dc.identifier.authority | Huang, JS=rp00709 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/j.jorganchem.2005.10.020 | en_HK |
dc.identifier.scopus | eid_2-s2.0-30844462971 | en_HK |
dc.identifier.hkuros | 114272 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-30844462971&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 691 | en_HK |
dc.identifier.issue | 4 | en_HK |
dc.identifier.spage | 787 | en_HK |
dc.identifier.epage | 792 | en_HK |
dc.identifier.isi | WOS:000235126800033 | - |
dc.publisher.place | Switzerland | en_HK |
dc.identifier.scopusauthorid | Song, LC=7402537505 | en_HK |
dc.identifier.scopusauthorid | Yu, GA=8252045600 | en_HK |
dc.identifier.scopusauthorid | Hu, QM=7403214461 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.scopusauthorid | Zhu, N=7201449530 | en_HK |
dc.identifier.scopusauthorid | Huang, JS=7407192639 | en_HK |
dc.identifier.issnl | 0022-328X | - |