File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Synthesis and characterization of the first transition-metal fullerene complexes containing bis(η6-benzene)chromium moieties

TitleSynthesis and characterization of the first transition-metal fullerene complexes containing bis(η6-benzene)chromium moieties
Authors
Keywords[60]Fullerene
Bis(η 6-diphenylphosphinobenzene)chromium
Crystal structures
Molybdenum
Palladium
Platinum
Issue Date2006
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal Of Organometallic Chemistry, 2006, v. 691 n. 4, p. 787-792 How to Cite?
AbstractWhile photochemical reaction of C60 with an equimolar amount of Mo(CO)4(η6-Ph2PC6H 5)2Cr (1) in toluene at room temperature produced bimetallic Mo/Cr fullerene complex fac/mer-(η2-C 60)Mo(CO)3[(η6-Ph2PC 6H5)2Cr] (2) in 87% yield, the thermal reaction of an equimolar mixture of C60, M(dba)2 (M = Pd, Pt; dba = dibenzylideneacetone) and (η6-Ph2PC 6H5)2Cr (3) in toluene at room temperature afforded bimetallic M/Cr fullerene complexes (η2-C 60)M[(η6-Ph2PC6H 5)2Cr] (4, M = Pd; 5, M = Pt) in 88% and 92% yields, respectively. Products 2, 4 and 5 are the first transition-metal fullerene complexes containing bis(η6-benzene)chromium moieties. While 2, 4 and 5 were characterized by elemental analysis and spectroscopy, the crystal molecular structures of 4 along with the starting materials 1 and 3 have been determined by X-ray diffraction techniques. © 2005 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/167993
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorSong, LCen_HK
dc.contributor.authorYu, GAen_HK
dc.contributor.authorHu, QMen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorHuang, JSen_HK
dc.date.accessioned2012-10-08T03:13:51Z-
dc.date.available2012-10-08T03:13:51Z-
dc.date.issued2006en_HK
dc.identifier.citationJournal Of Organometallic Chemistry, 2006, v. 691 n. 4, p. 787-792en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/167993-
dc.description.abstractWhile photochemical reaction of C60 with an equimolar amount of Mo(CO)4(η6-Ph2PC6H 5)2Cr (1) in toluene at room temperature produced bimetallic Mo/Cr fullerene complex fac/mer-(η2-C 60)Mo(CO)3[(η6-Ph2PC 6H5)2Cr] (2) in 87% yield, the thermal reaction of an equimolar mixture of C60, M(dba)2 (M = Pd, Pt; dba = dibenzylideneacetone) and (η6-Ph2PC 6H5)2Cr (3) in toluene at room temperature afforded bimetallic M/Cr fullerene complexes (η2-C 60)M[(η6-Ph2PC6H 5)2Cr] (4, M = Pd; 5, M = Pt) in 88% and 92% yields, respectively. Products 2, 4 and 5 are the first transition-metal fullerene complexes containing bis(η6-benzene)chromium moieties. While 2, 4 and 5 were characterized by elemental analysis and spectroscopy, the crystal molecular structures of 4 along with the starting materials 1 and 3 have been determined by X-ray diffraction techniques. © 2005 Elsevier B.V. All rights reserved.en_HK
dc.languageengen_US
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subject[60]Fullereneen_HK
dc.subjectBis(η 6-diphenylphosphinobenzene)chromiumen_HK
dc.subjectCrystal structuresen_HK
dc.subjectMolybdenumen_HK
dc.subjectPalladiumen_HK
dc.subjectPlatinumen_HK
dc.titleSynthesis and characterization of the first transition-metal fullerene complexes containing bis(η6-benzene)chromium moietiesen_HK
dc.typeArticleen_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailHuang, JS: jshuang@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/j.jorganchem.2005.10.020en_HK
dc.identifier.scopuseid_2-s2.0-30844462971en_HK
dc.identifier.hkuros114272-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-30844462971&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume691en_HK
dc.identifier.issue4en_HK
dc.identifier.spage787en_HK
dc.identifier.epage792en_HK
dc.identifier.isiWOS:000235126800033-
dc.publisher.placeSwitzerlanden_HK
dc.identifier.scopusauthoridSong, LC=7402537505en_HK
dc.identifier.scopusauthoridYu, GA=8252045600en_HK
dc.identifier.scopusauthoridHu, QM=7403214461en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridHuang, JS=7407192639en_HK

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats