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Article: Synthesis and characterization of iron and manganese porphyrin complexes with amino-acid-esters as axial ligand

TitleSynthesis and characterization of iron and manganese porphyrin complexes with amino-acid-esters as axial ligand
以氨基酸酯為軸向配體的鐵、錳卟啉配合物的合成及表征
Authors
KeywordsAmino Acid Ester (氨基酸酯)
Iron Porphyrin (鐵卟啉)
Manganese Porphyrin (錳卟啉)
Systhesis Characterization (合成;表征)
Issue Date1997
Citation
Chinese Journal Of Inorganic Chemistry, 1997, v. 13 n. 3, p. 344-346 How to Cite?
無機化學學報, 1997, v. 13 n. 3, p. 344-346 How to Cite?
AbstractThe new six-coordinate complexes (TPP)Fe1 (Gly-OMe)2 C50H42FeN6O4 and (TPP)Fe1 (β-Ala-OMe)2(C52H46FeN6O 4) wbere TPP=meso-tetraphenyl porphyrinate, Gly-OMe=glycine methyl ester, β-Ala-OMe=β-alanine methyl ester and five-coordinte complex (TPP)Mn1 (Gly-OMe) (C47H35MnN5O2) have been prepared by sodium borohydride method. These complexes were characterized by UV-Vis, IR, ESR, spectra and by elemental analysis. The synthesized divalent iron porphyrins are d6 low spin states and their UV-Vis spectra are Hypso type; while divalent manganese porphyrin is d5 high spin state and its UV-Vis spectrum is pseudo-Normal type.
以氨基酸酯為軸向配體的鐵、錳卟啉配合物的合成及表徵穆林靜*邱曉航周永洽黃傑生申泮文(南開大學化學系,天津300071)關鍵詞:鐵卟啉錳卟啉氨基酸酯合成表徵氨基酸酯是一類最基本的生物分子,有廣泛形成配合物的能力。研究發現,二價鋅卟啉可識別氨基酸酯,三價的銠卟啉可與氨基酸的氨基、羧基作用[1,2]。研究中還發現, 制約P450酶催化活性的因素, 主要取決於與之鄰近的配體, 末端的氨基酸殘基和蛋白質本身[3] 。因此合成軸向為氨基酸酯的鐵、錳卟啉配合物對進一步瞭解P450酶具有一定意義。
Persistent Identifierhttp://hdl.handle.net/10722/167992
ISSN
2015 Impact Factor: 0.488
2015 SCImago Journal Rankings: 0.161
References

 

DC FieldValueLanguage
dc.contributor.authorMu, Len_US
dc.contributor.authorQiu, Xen_US
dc.contributor.authorZhou, Yen_US
dc.contributor.authorHuang, Jen_US
dc.contributor.authorShen, Pen_US
dc.date.accessioned2012-10-08T03:13:51Z-
dc.date.available2012-10-08T03:13:51Z-
dc.date.issued1997en_US
dc.identifier.citationChinese Journal Of Inorganic Chemistry, 1997, v. 13 n. 3, p. 344-346en_US
dc.identifier.citation無機化學學報, 1997, v. 13 n. 3, p. 344-346-
dc.identifier.issn1001-4861en_US
dc.identifier.urihttp://hdl.handle.net/10722/167992-
dc.description.abstractThe new six-coordinate complexes (TPP)Fe1 (Gly-OMe)2 C50H42FeN6O4 and (TPP)Fe1 (β-Ala-OMe)2(C52H46FeN6O 4) wbere TPP=meso-tetraphenyl porphyrinate, Gly-OMe=glycine methyl ester, β-Ala-OMe=β-alanine methyl ester and five-coordinte complex (TPP)Mn1 (Gly-OMe) (C47H35MnN5O2) have been prepared by sodium borohydride method. These complexes were characterized by UV-Vis, IR, ESR, spectra and by elemental analysis. The synthesized divalent iron porphyrins are d6 low spin states and their UV-Vis spectra are Hypso type; while divalent manganese porphyrin is d5 high spin state and its UV-Vis spectrum is pseudo-Normal type.en_US
dc.description.abstract以氨基酸酯為軸向配體的鐵、錳卟啉配合物的合成及表徵穆林靜*邱曉航周永洽黃傑生申泮文(南開大學化學系,天津300071)關鍵詞:鐵卟啉錳卟啉氨基酸酯合成表徵氨基酸酯是一類最基本的生物分子,有廣泛形成配合物的能力。研究發現,二價鋅卟啉可識別氨基酸酯,三價的銠卟啉可與氨基酸的氨基、羧基作用[1,2]。研究中還發現, 制約P450酶催化活性的因素, 主要取決於與之鄰近的配體, 末端的氨基酸殘基和蛋白質本身[3] 。因此合成軸向為氨基酸酯的鐵、錳卟啉配合物對進一步瞭解P450酶具有一定意義。-
dc.languagechien_US
dc.relation.ispartofChinese Journal of Inorganic Chemistryen_US
dc.relation.ispartof無機化學學報-
dc.subjectAmino Acid Ester (氨基酸酯)en_US
dc.subjectIron Porphyrin (鐵卟啉)en_US
dc.subjectManganese Porphyrin (錳卟啉)en_US
dc.subjectSysthesis Characterization (合成;表征)en_US
dc.titleSynthesis and characterization of iron and manganese porphyrin complexes with amino-acid-esters as axial liganden_US
dc.title以氨基酸酯為軸向配體的鐵、錳卟啉配合物的合成及表征-
dc.typeArticleen_US
dc.identifier.emailHuang, J:jshuang@hkucc.hku.hken_US
dc.identifier.authorityHuang, J=rp00709en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-3042970466en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-3042970466&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume13en_US
dc.identifier.issue3en_US
dc.identifier.spage344en_US
dc.identifier.epage346en_US
dc.identifier.scopusauthoridMu, L=7005437525en_US
dc.identifier.scopusauthoridQiu, X=7402545657en_US
dc.identifier.scopusauthoridZhou, Y=8047648700en_US
dc.identifier.scopusauthoridHuang, J=7407192639en_US
dc.identifier.scopusauthoridShen, P=7201767682en_US
dc.customcontrol.immutablecsl 130729-

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