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Article: Tuning the reactivity of dioxoruthenium(VI) porphyrins toward an arylimine by altering porphyrin substituants

TitleTuning the reactivity of dioxoruthenium(VI) porphyrins toward an arylimine by altering porphyrin substituants
Authors
Issue Date2005
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2005, v. 44 n. 11, p. 3780-3788 How to Cite?
AbstractReaction of dioxoruthenium(VI) porphyrins [RuVI(Por)O 2] with arylimine HN=CPh2 in dichloromethane afforded bis-(methyleneamido)ruthenium(IV) porphyrins [RuIV(Por)(N=CPh 2)2] for Por = 4-CI-TPP and TMP; (methyleneamido)- hydroxoruthenium(IV) porphyrins [RuVI(Por)(N=CPh2)(OH)] for Por = TPP and TIP; and bis(arylimine)ruthenium(II) porphyrins [Ru II(Por)(HN=CPh2)2] for Por = 3,5-Cl 2TPP and 3,5-(CF3)2TPP. In dichloromethane solution exposed to air, complex [RuII(3,5-Cl2TPP)(HN= CPh2)2] underwent oxidative deprotonation.to form [Ru IV(3,5-Cl2TPP)(N= CPh2)2]. The new ruthenium porphyrins were identified by 1H NMR, UV-vis, IR, and mass spectroscopy, along with elemental analysis. X-ray crystal structure determinations of [RuIV(4-Cl-TPP)(N=CPh2)2], [RuIV(TPP)(N=CPh2)-(OH)], and [RuII(3,5- (CF3)2TPP)(HN=CPh2)2] revealed the Ru-N(methyleneamido) or Ru-N(arylimine) distances of 1.897(5) Å (average), 1.808(4) Å, and 2.044(2) Å (average), respectively. © 2005 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/167931
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorHuang, JSen_HK
dc.contributor.authorLeung, SKYen_HK
dc.contributor.authorZhou, ZYen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2012-10-08T03:13:04Z-
dc.date.available2012-10-08T03:13:04Z-
dc.date.issued2005en_HK
dc.identifier.citationInorganic Chemistry, 2005, v. 44 n. 11, p. 3780-3788en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/167931-
dc.description.abstractReaction of dioxoruthenium(VI) porphyrins [RuVI(Por)O 2] with arylimine HN=CPh2 in dichloromethane afforded bis-(methyleneamido)ruthenium(IV) porphyrins [RuIV(Por)(N=CPh 2)2] for Por = 4-CI-TPP and TMP; (methyleneamido)- hydroxoruthenium(IV) porphyrins [RuVI(Por)(N=CPh2)(OH)] for Por = TPP and TIP; and bis(arylimine)ruthenium(II) porphyrins [Ru II(Por)(HN=CPh2)2] for Por = 3,5-Cl 2TPP and 3,5-(CF3)2TPP. In dichloromethane solution exposed to air, complex [RuII(3,5-Cl2TPP)(HN= CPh2)2] underwent oxidative deprotonation.to form [Ru IV(3,5-Cl2TPP)(N= CPh2)2]. The new ruthenium porphyrins were identified by 1H NMR, UV-vis, IR, and mass spectroscopy, along with elemental analysis. X-ray crystal structure determinations of [RuIV(4-Cl-TPP)(N=CPh2)2], [RuIV(TPP)(N=CPh2)-(OH)], and [RuII(3,5- (CF3)2TPP)(HN=CPh2)2] revealed the Ru-N(methyleneamido) or Ru-N(arylimine) distances of 1.897(5) Å (average), 1.808(4) Å, and 2.044(2) Å (average), respectively. © 2005 American Chemical Society.en_HK
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.titleTuning the reactivity of dioxoruthenium(VI) porphyrins toward an arylimine by altering porphyrin substituantsen_HK
dc.typeArticleen_HK
dc.identifier.emailHuang, JS: jshuang@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ic0484102en_HK
dc.identifier.pmid15907102-
dc.identifier.scopuseid_2-s2.0-20444461694en_HK
dc.identifier.hkuros103780-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-20444461694&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume44en_HK
dc.identifier.issue11en_HK
dc.identifier.spage3780en_HK
dc.identifier.epage3788en_HK
dc.identifier.isiWOS:000229381600005-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridHuang, JS=7407192639en_HK
dc.identifier.scopusauthoridLeung, SKY=36546285500en_HK
dc.identifier.scopusauthoridZhou, ZY=7406096262en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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