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Article: Novel epoxidation reaction of olefins using the combination of Chloramine-M, benzaldehyde, and BTEAC
Title | Novel epoxidation reaction of olefins using the combination of Chloramine-M, benzaldehyde, and BTEAC |
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Authors | |
Issue Date | 1999 |
Publisher | American Chemical Society. The Journal's web site is located at http://www.chemistry.org/portal/a/c/s/1/acsdisplay.html?DOC=meetingspast.html |
Citation | Acs National Meeting Book Of Abstracts, 1999, v. PART 2, p. ORGN-522 How to Cite? |
Abstract | The combination of Chloramine-M (CH3SO2NClNa), benzaldehyde and BTEAC epoxidized olefins with good yield. While the novel reaction was electrophilic, epoxidation of cis-olefins such as cis-β-methylstyrene, cis-stilbene, and 4-cis-octene yielded trans-epoxides as major products. Several experiments were performed to study the reaction mechanism. Cis-N-sulfonyl-oxaziridine A was suggested as a reactive intermediate in this epoxidation reaction. |
Persistent Identifier | http://hdl.handle.net/10722/167923 |
ISSN |
DC Field | Value | Language |
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dc.contributor.author | Zhang, C | en_US |
dc.contributor.author | Yang, D | en_US |
dc.contributor.author | Wang, XC | en_US |
dc.date.accessioned | 2012-10-08T03:12:59Z | - |
dc.date.available | 2012-10-08T03:12:59Z | - |
dc.date.issued | 1999 | en_US |
dc.identifier.citation | Acs National Meeting Book Of Abstracts, 1999, v. PART 2, p. ORGN-522 | en_US |
dc.identifier.issn | 0065-7727 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167923 | - |
dc.description.abstract | The combination of Chloramine-M (CH3SO2NClNa), benzaldehyde and BTEAC epoxidized olefins with good yield. While the novel reaction was electrophilic, epoxidation of cis-olefins such as cis-β-methylstyrene, cis-stilbene, and 4-cis-octene yielded trans-epoxides as major products. Several experiments were performed to study the reaction mechanism. Cis-N-sulfonyl-oxaziridine A was suggested as a reactive intermediate in this epoxidation reaction. | en_US |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://www.chemistry.org/portal/a/c/s/1/acsdisplay.html?DOC=meetingspast.html | en_US |
dc.relation.ispartof | ACS National Meeting Book of Abstracts | en_US |
dc.title | Novel epoxidation reaction of olefins using the combination of Chloramine-M, benzaldehyde, and BTEAC | en_US |
dc.type | Article | en_US |
dc.identifier.email | Yang, D:yangdan@hku.hk | en_US |
dc.identifier.authority | Yang, D=rp00825 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.scopus | eid_2-s2.0-18744427817 | en_US |
dc.identifier.volume | PART 2 | en_US |
dc.identifier.spage | ORGN | en_US |
dc.identifier.epage | 522 | en_US |
dc.publisher.place | United States | en_US |
dc.identifier.scopusauthorid | Zhang, C=7405494641 | en_US |
dc.identifier.scopusauthorid | Yang, D=7404800756 | en_US |
dc.identifier.scopusauthorid | Wang, XC=9744761800 | en_US |
dc.identifier.issnl | 0065-7727 | - |