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Article: Comparison of the LMCT resonance Raman spectra of PdCl2(PCy3)2 and PdCl2(PPh3)2: Effect of the phenyl versus cyclohexyl substituents on the LMCT excited state

TitleComparison of the LMCT resonance Raman spectra of PdCl2(PCy3)2 and PdCl2(PPh3)2: Effect of the phenyl versus cyclohexyl substituents on the LMCT excited state
Authors
Issue Date2000
PublisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.asp
Citation
Molecular Physics, 2000, v. 98 n. 17, p. 1323-1330 How to Cite?
AbstractResonance Raman spectra have been obtained at four excitation wavelengths within the A-band ligand to metal charge transfer (LMCT) absorption of trans-dichloro-bis(tricyclo-hexylphosphine) palladium(II) and a resonance Raman intensity analysis was done to elucidate the excited state structure relative to the ground state. Comparison of the present results for trans-dichlorobis(tricyclohexylphosphine) palladium(II) with those previously reported for trans-dichlorobis(triphenylphosphine) palladium(II) shows that the phenyl ligand appears to primarily affect the adjacent P-C vibrational reorganizational energy and does not significantly perturb the Pd-Cl or Pd-P vibrational reorganizational energies.
Persistent Identifierhttp://hdl.handle.net/10722/167921
ISSN
2015 Impact Factor: 1.837
2015 SCImago Journal Rankings: 0.781
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLeung, KHen_US
dc.contributor.authorSzulbinski, Wen_US
dc.contributor.authorPhillips, DLen_US
dc.date.accessioned2012-10-08T03:12:57Z-
dc.date.available2012-10-08T03:12:57Z-
dc.date.issued2000en_US
dc.identifier.citationMolecular Physics, 2000, v. 98 n. 17, p. 1323-1330en_US
dc.identifier.issn0026-8976en_US
dc.identifier.urihttp://hdl.handle.net/10722/167921-
dc.description.abstractResonance Raman spectra have been obtained at four excitation wavelengths within the A-band ligand to metal charge transfer (LMCT) absorption of trans-dichloro-bis(tricyclo-hexylphosphine) palladium(II) and a resonance Raman intensity analysis was done to elucidate the excited state structure relative to the ground state. Comparison of the present results for trans-dichlorobis(tricyclohexylphosphine) palladium(II) with those previously reported for trans-dichlorobis(triphenylphosphine) palladium(II) shows that the phenyl ligand appears to primarily affect the adjacent P-C vibrational reorganizational energy and does not significantly perturb the Pd-Cl or Pd-P vibrational reorganizational energies.en_US
dc.languageengen_US
dc.publisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.aspen_US
dc.relation.ispartofMolecular Physicsen_US
dc.titleComparison of the LMCT resonance Raman spectra of PdCl2(PCy3)2 and PdCl2(PPh3)2: Effect of the phenyl versus cyclohexyl substituents on the LMCT excited stateen_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1080/002689700413578en_US
dc.identifier.scopuseid_2-s2.0-18744364685en_US
dc.identifier.hkuros62396-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-18744364685&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume98en_US
dc.identifier.issue17en_US
dc.identifier.spage1323en_US
dc.identifier.epage1330en_US
dc.identifier.isiWOS:000088668400005-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridLeung, KH=7401860609en_US
dc.identifier.scopusauthoridSzulbinski, W=6602684427en_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US

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