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Article: High-valent dioxo-ruthenium(VI) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of trans-[RuVI(15-tmc)O2](ClO4)2(15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2(16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)

TitleHigh-valent dioxo-ruthenium(VI) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of trans-[RuVI(15-tmc)O2](ClO4)2(15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2(16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)
Authors
Issue Date1985
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1985 n. 14, p. 986-988 How to Cite?
Abstractfull title:High-valent dioxo-ruthenium(VI) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of trans-[Ru VI(15-tmc) O 2](ClO 4) 2 (15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru VI(16-tmc)O 2](ClO 4) 2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) The X-ray crystal structures of trans-[Ru VI(15-tmc)O 2](ClO 4) 2 (15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru VI(16-tmc)O 2](ClO 4) 2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9, 13-tetra-azacyclohexadecane) have been determined; the Ru=O bond distances in these two complexes, 1.718(5) and 1.705(7) Å respectively, appear to be insensitive to the ring size of the macrocycle.
Persistent Identifierhttp://hdl.handle.net/10722/167897
ISSN
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorMak, TCWen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorWong, KYen_US
dc.date.accessioned2012-10-08T03:12:41Z-
dc.date.available2012-10-08T03:12:41Z-
dc.date.issued1985en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1985 n. 14, p. 986-988en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/167897-
dc.description.abstractfull title:High-valent dioxo-ruthenium(VI) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of trans-[Ru VI(15-tmc) O 2](ClO 4) 2 (15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru VI(16-tmc)O 2](ClO 4) 2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) The X-ray crystal structures of trans-[Ru VI(15-tmc)O 2](ClO 4) 2 (15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru VI(16-tmc)O 2](ClO 4) 2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9, 13-tetra-azacyclohexadecane) have been determined; the Ru=O bond distances in these two complexes, 1.718(5) and 1.705(7) Å respectively, appear to be insensitive to the ring size of the macrocycle.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleHigh-valent dioxo-ruthenium(VI) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of trans-[RuVI(15-tmc)O2](ClO4)2(15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2(16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39850000986-
dc.identifier.scopuseid_2-s2.0-1542355665en_US
dc.identifier.issue14en_US
dc.identifier.spage986en_US
dc.identifier.epage988en_US
dc.identifier.isiWOS:A1985AMG0800034-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridMak, TCW=35230525700en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridWong, KY=7404760030en_US

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