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Article: Generation of binuclear (d8·d8)pσ platinum and rhodium complexes by pulse radiolysis

TitleGeneration of binuclear (d8·d8)pσ platinum and rhodium complexes by pulse radiolysis
Authors
Issue Date1984
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal Of The American Chemical Society, 1984, v. 106 n. 18, p. 5143-5145 How to Cite?
AbstractTwo (d8·d8)pσ binuclear complexes, Pt2(pop)4 5- (pop = P2O5H2 2-) and Rh2(TMB)4 + (TMB = 2,5-dimethyl-2,5-diisocyanohexane), have been generated by pulse radiolysis of aqueous and acetonitrile solutions, respectively, of the corresponding d8·d8 species. An intense absorption system attributable to the allowed dσ* → pσ transition is observed in the spectrum of each of the transients (420 nm, Pt2(pop)4 5-; 570 nm, Rh2(TMB)4 +). © 1984 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/167881
ISSN
2015 Impact Factor: 13.038
2015 SCImago Journal Rankings: 7.123
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorAtherton, SJen_US
dc.contributor.authorButler, LGen_US
dc.contributor.authorGray, HBen_US
dc.date.accessioned2012-10-08T03:12:30Z-
dc.date.available2012-10-08T03:12:30Z-
dc.date.issued1984en_US
dc.identifier.citationJournal Of The American Chemical Society, 1984, v. 106 n. 18, p. 5143-5145en_US
dc.identifier.issn0002-7863en_US
dc.identifier.urihttp://hdl.handle.net/10722/167881-
dc.description.abstractTwo (d8·d8)pσ binuclear complexes, Pt2(pop)4 5- (pop = P2O5H2 2-) and Rh2(TMB)4 + (TMB = 2,5-dimethyl-2,5-diisocyanohexane), have been generated by pulse radiolysis of aqueous and acetonitrile solutions, respectively, of the corresponding d8·d8 species. An intense absorption system attributable to the allowed dσ* → pσ transition is observed in the spectrum of each of the transients (420 nm, Pt2(pop)4 5-; 570 nm, Rh2(TMB)4 +). © 1984 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.htmlen_US
dc.relation.ispartofJournal of the American Chemical Societyen_US
dc.titleGeneration of binuclear (d8·d8)pσ platinum and rhodium complexes by pulse radiolysisen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ja00330a018-
dc.identifier.scopuseid_2-s2.0-11644276299en_US
dc.identifier.volume106en_US
dc.identifier.issue18en_US
dc.identifier.spage5143en_US
dc.identifier.epage5145en_US
dc.identifier.isiWOS:A1984TH18100018-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridAtherton, SJ=7007168730en_US
dc.identifier.scopusauthoridButler, LG=35480504200en_US
dc.identifier.scopusauthoridGray, HB=36047602600en_US

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