Article: Luminescent platinum(II) complexes. Electronic spectroscopy of platinum(II) complexes of 2,2′:6′,2″-terpyridine (terpy) and p-substituted phenylterpyridines and crystal structure of [pt(terpy)Cl][CF3SO3]

File Download

No File Attached
The HKU Scholars Hub has contact details for these author(s).
- Professor Che, Chi Ming

Links for fulltext
(May Require Subscription)

Publisher Website: 10.1039/DT9930002933
Scopus: eid_2-s2.0-11244290038

Supplementary

Citations:
- Scopus:
- Web of Science:
- PubMed Central:
Item Statistics (The Hub)
Appears in Collections:
- Chemistry: Journal/Magazine Articles

Title	Luminescent platinum(II) complexes. Electronic spectroscopy of platinum(II) complexes of 2,2′:6′,2″-terpyridine (terpy) and p-substituted phenylterpyridines and crystal structure of [pt(terpy)Cl][CF3SO3]
Authors	Yip, HK1 Cheng, LK1 Cheung, KK1 Che, CM1
Issue Date	1993
Publisher	Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation	Journal Of The Chemical Society, Dalton Transactions, 1993 n. 19, p. 2933-2938 [How to Cite?] DOI: http://dx.doi.org/10.1039/DT9930002933
Abstract	The complexes [Pt(terpy)L′]n+ (terpy = 2,2′:6′,2″-terpyridine; L′ = Cl, Br, I, N3 or SCN-, n = 1; L′ = NH3, n = 2) have been prepared and their spectroscopic and emission properties studied. Absorption bands are found at 300-350 and at 370-450 nm, which are assigned to the intraligand and metal-to-ligand change-transfer (m.l.c.t.) transitions, respectively. The complexes [Pt(4′R-terpy)Cl]ClO4 (R′ = C6H4OMe-p,C6H4Me-p, C6H4Br-p or C6H4CN-p) were prepared by the reaction of K2[PtCl4] with 4′R-terpy in water-MeCN. Unlike [Pt(terpy)L′]n+ which show emission in the solid state only, [Pt(4′R-terpy)Cl]+ display 3m.l.c.t. emission in fluid solution at room temperature. The crystal structure of [Pt(terpy)Cl][CF3SO3] has been determined: monoclinic, space group P21/n, a = 13.808(4), b = 6.873(1), c = 19.477(5) Å, β = 105.54(2)°, and Z = 4. In the unit cell, two [Pt(terpy)Cl]+ cations stack in a head-to-tail fashion with an intermolecular Pt ⋯ Pt distance of 3.329(1) Å. The solid-state emission of [Pt(terpy)Cl][CF3SO3] is similar to that of the 3(dσ*πb) emission of the dinuclear complex [Pt2(terpy)2L][ClO4]3 (L = guadinate) having intramolecular Pt ⋯ Pt separations of 3.090(1) and 3.071(1) Å.
ISSN	1472-7773
DOI	http://dx.doi.org/10.1039/DT9930002933

DC Field	Value
dc.contributor.author	Yip, HK
dc.contributor.author	Cheng, LK
dc.contributor.author	Cheung, KK
dc.contributor.author	Che, CM
dc.date.accessioned	2012-10-08T03:12:27Z
dc.date.available	2012-10-08T03:12:27Z
dc.date.issued	1993
dc.description.abstract	The complexes [Pt(terpy)L′]n+ (terpy = 2,2′:6′,2″-terpyridine; L′ = Cl, Br, I, N3 or SCN-, n = 1; L′ = NH3, n = 2) have been prepared and their spectroscopic and emission properties studied. Absorption bands are found at 300-350 and at 370-450 nm, which are assigned to the intraligand and metal-to-ligand change-transfer (m.l.c.t.) transitions, respectively. The complexes [Pt(4′R-terpy)Cl]ClO4 (R′ = C6H4OMe-p,C6H4Me-p, C6H4Br-p or C6H4CN-p) were prepared by the reaction of K2[PtCl4] with 4′R-terpy in water-MeCN. Unlike [Pt(terpy)L′]n+ which show emission in the solid state only, [Pt(4′R-terpy)Cl]+ display 3m.l.c.t. emission in fluid solution at room temperature. The crystal structure of [Pt(terpy)Cl][CF3SO3] has been determined: monoclinic, space group P21/n, a = 13.808(4), b = 6.873(1), c = 19.477(5) Å, β = 105.54(2)°, and Z = 4. In the unit cell, two [Pt(terpy)Cl]+ cations stack in a head-to-tail fashion with an intermolecular Pt ⋯ Pt distance of 3.329(1) Å. The solid-state emission of [Pt(terpy)Cl][CF3SO3] is similar to that of the 3(dσ*πb) emission of the dinuclear complex [Pt2(terpy)2L][ClO4]3 (L = guadinate) having intramolecular Pt ⋯ Pt separations of 3.090(1) and 3.071(1) Å.
dc.description.nature	Link_to_subscribed_fulltext
dc.identifier.citation	Journal Of The Chemical Society, Dalton Transactions, 1993 n. 19, p. 2933-2938 [How to Cite?] DOI: http://dx.doi.org/10.1039/DT9930002933
dc.identifier.doi	http://dx.doi.org/10.1039/DT9930002933
dc.identifier.epage	2938
dc.identifier.issn	1472-7773
dc.identifier.issue	19
dc.identifier.scopus	eid_2-s2.0-11244290038
dc.identifier.spage	2933
dc.identifier.uri	http://hdl.handle.net/10722/167880
dc.language	eng
dc.publisher	Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
dc.publisher.place	United Kingdom
dc.relation.ispartof	Journal of the Chemical Society, Dalton Transactions
dc.title	Luminescent platinum(II) complexes. Electronic spectroscopy of platinum(II) complexes of 2,2′:6′,2″-terpyridine (terpy) and p-substituted phenylterpyridines and crystal structure of [pt(terpy)Cl][CF3SO3]
dc.type	Article

<?xml encoding="utf-8" version="1.0"?><item><contributor.author>Yip, HK</contributor.author><contributor.author>Cheng, LK</contributor.author><contributor.author>Cheung, KK</contributor.author><contributor.author>Che, CM</contributor.author><date.accessioned>2012-10-08T03:12:27Z</date.accessioned><date.available>2012-10-08T03:12:27Z</date.available><date.issued>1993</date.issued><identifier.citation>Journal Of The Chemical Society, Dalton Transactions, 1993 n. 19, p. 2933-2938</identifier.citation><identifier.issn>1472-7773</identifier.issn><identifier.uri>http://hdl.handle.net/10722/167880</identifier.uri><description.abstract>The complexes [Pt(terpy)L&#8242;]n+ (terpy = 2,2&#8242;:6&#8242;,2&#8243;-terpyridine; L&#8242; = Cl, Br, I, N3 or SCN-, n = 1; L&#8242; = NH3, n = 2) have been prepared and their spectroscopic and emission properties studied. Absorption bands are found at 300-350 and at 370-450 nm, which are assigned to the intraligand and metal-to-ligand change-transfer (m.l.c.t.) transitions, respectively. The complexes [Pt(4&#8242;R-terpy)Cl]ClO4 (R&#8242; = C6H4OMe-p,C6H4Me-p, C6H4Br-p or C6H4CN-p) were prepared by the reaction of K2[PtCl4] with 4&#8242;R-terpy in water-MeCN. Unlike [Pt(terpy)L&#8242;]n+ which show emission in the solid state only, [Pt(4&#8242;R-terpy)Cl]+ display 3m.l.c.t. emission in fluid solution at room temperature. The crystal structure of [Pt(terpy)Cl][CF3SO3] has been determined: monoclinic, space group P21/n, a = 13.808(4), b = 6.873(1), c = 19.477(5) &#197;, &#946; = 105.54(2)&#176;, and Z = 4. In the unit cell, two [Pt(terpy)Cl]+ cations stack in a head-to-tail fashion with an intermolecular Pt &#8943; Pt distance of 3.329(1) &#197;. The solid-state emission of [Pt(terpy)Cl][CF3SO3] is similar to that of the 3(d&#963;*&#960;b) emission of the dinuclear complex [Pt2(terpy)2L][ClO4]3 (L = guadinate) having intramolecular Pt &#8943; Pt separations of 3.090(1) and 3.071(1) &#197;.</description.abstract><language>eng</language><publisher>Royal Society of Chemistry. The Journal&apos;s web site is located at http://www.rsc.org/dalton</publisher><relation.ispartof>Journal of the Chemical Society, Dalton Transactions</relation.ispartof><title>Luminescent platinum(II) complexes. Electronic spectroscopy of platinum(II) complexes of 2,2&#8242;:6&#8242;,2&#8243;-terpyridine (terpy) and p-substituted phenylterpyridines and crystal structure of [pt(terpy)Cl][CF3SO3]</title><type>Article</type><description.nature>Link_to_subscribed_fulltext</description.nature><identifier.doi>10.1039/DT9930002933</identifier.doi><identifier.scopus>eid_2-s2.0-11244290038</identifier.scopus><identifier.issue>19</identifier.issue><identifier.spage>2933</identifier.spage><identifier.epage>2938</identifier.epage><publisher.place>United Kingdom</publisher.place></item>

Author Affiliations

The University of Hong Kong

Article: Luminescent platinum(II) complexes. Electronic spectroscopy of platinum(II) complexes of 2,2′:6′,2″-terpyridine (terpy) and p-substituted phenylterpyridines and crystal structure of [pt(terpy)Cl][CF3SO3]

The HKU Scholars Hub has contact details for these author(s).