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Article: Transient resonance Raman and density functional theory investigation of the ultraviolet photolysis of dibromoacetonitrile in the solution phase

TitleTransient resonance Raman and density functional theory investigation of the ultraviolet photolysis of dibromoacetonitrile in the solution phase
Authors
Issue Date2001
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 2001, v. 350 n. 1-2, p. 78-85 How to Cite?
AbstractUltraviolet photolysis of dibromoacetonitrile in cyclohexane solution was investigated using transient resonance Raman spectroscopy. The experimental Raman vibrational frequencies were compared to those predicted from density functional theory calculations for several probable photoproduct species. Our results indicate that significant amounts of the Br-NCCHBr adduct is produced on the nanosecond time scale. We briefly discuss the probable mechanisms of formation of the Br-NCCHBr species and implications for using substituted dihaloalkanes as carbenoid agents in cyclopropanation reactions. © 2001 Elsevier Science B.V.
Persistent Identifierhttp://hdl.handle.net/10722/167826
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLi, YLen_US
dc.contributor.authorLee, CWen_US
dc.contributor.authorWang, Den_US
dc.contributor.authorLeung, KHen_US
dc.contributor.authorPhillips, DLen_US
dc.date.accessioned2012-10-08T03:12:00Z-
dc.date.available2012-10-08T03:12:00Z-
dc.date.issued2001en_US
dc.identifier.citationChemical Physics Letters, 2001, v. 350 n. 1-2, p. 78-85en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://hdl.handle.net/10722/167826-
dc.description.abstractUltraviolet photolysis of dibromoacetonitrile in cyclohexane solution was investigated using transient resonance Raman spectroscopy. The experimental Raman vibrational frequencies were compared to those predicted from density functional theory calculations for several probable photoproduct species. Our results indicate that significant amounts of the Br-NCCHBr adduct is produced on the nanosecond time scale. We briefly discuss the probable mechanisms of formation of the Br-NCCHBr species and implications for using substituted dihaloalkanes as carbenoid agents in cyclopropanation reactions. © 2001 Elsevier Science B.V.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_US
dc.relation.ispartofChemical Physics Lettersen_US
dc.titleTransient resonance Raman and density functional theory investigation of the ultraviolet photolysis of dibromoacetonitrile in the solution phaseen_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0009-2614(01)01279-9en_US
dc.identifier.scopuseid_2-s2.0-0042836731en_US
dc.identifier.hkuros73842-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0042836731&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume350en_US
dc.identifier.issue1-2en_US
dc.identifier.spage78en_US
dc.identifier.epage85en_US
dc.identifier.isiWOS:000173058300012-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridLi, YL=27168456500en_US
dc.identifier.scopusauthoridLee, CW=7410160954en_US
dc.identifier.scopusauthoridWang, D=7407071795en_US
dc.identifier.scopusauthoridLeung, KH=7401860609en_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US

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