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Article: Transient resonance Raman and density functional theory investigation of the ultraviolet photolysis of dibromoacetonitrile in the solution phase
Title | Transient resonance Raman and density functional theory investigation of the ultraviolet photolysis of dibromoacetonitrile in the solution phase |
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Authors | |
Issue Date | 2001 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett |
Citation | Chemical Physics Letters, 2001, v. 350 n. 1-2, p. 78-85 How to Cite? |
Abstract | Ultraviolet photolysis of dibromoacetonitrile in cyclohexane solution was investigated using transient resonance Raman spectroscopy. The experimental Raman vibrational frequencies were compared to those predicted from density functional theory calculations for several probable photoproduct species. Our results indicate that significant amounts of the Br-NCCHBr adduct is produced on the nanosecond time scale. We briefly discuss the probable mechanisms of formation of the Br-NCCHBr species and implications for using substituted dihaloalkanes as carbenoid agents in cyclopropanation reactions. © 2001 Elsevier Science B.V. |
Persistent Identifier | http://hdl.handle.net/10722/167826 |
ISSN | 2023 Impact Factor: 2.8 2023 SCImago Journal Rankings: 0.502 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Li, YL | en_US |
dc.contributor.author | Lee, CW | en_US |
dc.contributor.author | Wang, D | en_US |
dc.contributor.author | Leung, KH | en_US |
dc.contributor.author | Phillips, DL | en_US |
dc.date.accessioned | 2012-10-08T03:12:00Z | - |
dc.date.available | 2012-10-08T03:12:00Z | - |
dc.date.issued | 2001 | en_US |
dc.identifier.citation | Chemical Physics Letters, 2001, v. 350 n. 1-2, p. 78-85 | en_US |
dc.identifier.issn | 0009-2614 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167826 | - |
dc.description.abstract | Ultraviolet photolysis of dibromoacetonitrile in cyclohexane solution was investigated using transient resonance Raman spectroscopy. The experimental Raman vibrational frequencies were compared to those predicted from density functional theory calculations for several probable photoproduct species. Our results indicate that significant amounts of the Br-NCCHBr adduct is produced on the nanosecond time scale. We briefly discuss the probable mechanisms of formation of the Br-NCCHBr species and implications for using substituted dihaloalkanes as carbenoid agents in cyclopropanation reactions. © 2001 Elsevier Science B.V. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett | en_US |
dc.relation.ispartof | Chemical Physics Letters | en_US |
dc.title | Transient resonance Raman and density functional theory investigation of the ultraviolet photolysis of dibromoacetonitrile in the solution phase | en_US |
dc.type | Article | en_US |
dc.identifier.email | Phillips, DL:phillips@hku.hk | en_US |
dc.identifier.authority | Phillips, DL=rp00770 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/S0009-2614(01)01279-9 | en_US |
dc.identifier.scopus | eid_2-s2.0-0042836731 | en_US |
dc.identifier.hkuros | 73842 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0042836731&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 350 | en_US |
dc.identifier.issue | 1-2 | en_US |
dc.identifier.spage | 78 | en_US |
dc.identifier.epage | 85 | en_US |
dc.identifier.isi | WOS:000173058300012 | - |
dc.publisher.place | Netherlands | en_US |
dc.identifier.scopusauthorid | Li, YL=27168456500 | en_US |
dc.identifier.scopusauthorid | Lee, CW=7410160954 | en_US |
dc.identifier.scopusauthorid | Wang, D=7407071795 | en_US |
dc.identifier.scopusauthorid | Leung, KH=7401860609 | en_US |
dc.identifier.scopusauthorid | Phillips, DL=7404519365 | en_US |
dc.identifier.issnl | 0009-2614 | - |