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Article: Synthesis, characterization, and theoretical studies of group 4 amido hydrotris(pyrazolyl)borate complexes

TitleSynthesis, characterization, and theoretical studies of group 4 amido hydrotris(pyrazolyl)borate complexes
Authors
Issue Date2003
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2003, v. 42 n. 9, p. 3008-3015 How to Cite?
AbstractTitanium and zirconium amido complexes containing a hydrotris(pyrazolyl)borate (Tp) or hydrotris(3,5-dimethylpyrazolyl)borate (Tp*) ligand TpM(NMe2)3 (M = Ti, 1; M = Zr, 2) and Tp*M(NMe2)3 (M = Ti, 3; M = Zr, 4) were prepared by the reactions of M(NMe2)3Cl (M = Ti, Zr) with sodium hydridotris(pyrazol-1-yl)borate and potassium hydridotris(3,5-dimethylpyrazol-1-yl)borate, respectively. The structures of 1, 2, and 4·CH2Cl2 were determined by X-ray diffraction and show octahedral coordination geometry around the metal centers. Density functional theory calculations at the B3PW91 level were performed to understand the orientations and the rotational behavior of amido ligands in these metal complexes.
Persistent Identifierhttp://hdl.handle.net/10722/167803
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorCai, Hen_US
dc.contributor.authorLam, WHen_US
dc.contributor.authorYu, Xen_US
dc.contributor.authorLiu, Xen_US
dc.contributor.authorWu, ZZen_US
dc.contributor.authorChen, Ten_US
dc.contributor.authorLin, Zen_US
dc.contributor.authorChen, XTen_US
dc.contributor.authorYou, XZen_US
dc.contributor.authorXue, Zen_US
dc.date.accessioned2012-10-08T03:11:50Z-
dc.date.available2012-10-08T03:11:50Z-
dc.date.issued2003en_US
dc.identifier.citationInorganic Chemistry, 2003, v. 42 n. 9, p. 3008-3015en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/10722/167803-
dc.description.abstractTitanium and zirconium amido complexes containing a hydrotris(pyrazolyl)borate (Tp) or hydrotris(3,5-dimethylpyrazolyl)borate (Tp*) ligand TpM(NMe2)3 (M = Ti, 1; M = Zr, 2) and Tp*M(NMe2)3 (M = Ti, 3; M = Zr, 4) were prepared by the reactions of M(NMe2)3Cl (M = Ti, Zr) with sodium hydridotris(pyrazol-1-yl)borate and potassium hydridotris(3,5-dimethylpyrazol-1-yl)borate, respectively. The structures of 1, 2, and 4·CH2Cl2 were determined by X-ray diffraction and show octahedral coordination geometry around the metal centers. Density functional theory calculations at the B3PW91 level were performed to understand the orientations and the rotational behavior of amido ligands in these metal complexes.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_US
dc.relation.ispartofInorganic Chemistryen_US
dc.titleSynthesis, characterization, and theoretical studies of group 4 amido hydrotris(pyrazolyl)borate complexesen_US
dc.typeArticleen_US
dc.identifier.emailLam, WH:chsue@hku.hken_US
dc.identifier.authorityLam, WH=rp00719en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ic026063ven_US
dc.identifier.pmid12716195-
dc.identifier.scopuseid_2-s2.0-0038674726en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0038674726&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume42en_US
dc.identifier.issue9en_US
dc.identifier.spage3008en_US
dc.identifier.epage3015en_US
dc.identifier.isiWOS:000182650400029-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridCai, H=7202853408en_US
dc.identifier.scopusauthoridLam, WH=26642862800en_US
dc.identifier.scopusauthoridYu, X=7404110746en_US
dc.identifier.scopusauthoridLiu, X=7409286468en_US
dc.identifier.scopusauthoridWu, ZZ=7501411157en_US
dc.identifier.scopusauthoridChen, T=7405542559en_US
dc.identifier.scopusauthoridLin, Z=7404230177en_US
dc.identifier.scopusauthoridChen, XT=15031954600en_US
dc.identifier.scopusauthoridYou, XZ=36072101800en_US
dc.identifier.scopusauthoridXue, Z=7203058536en_US

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