File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1021/ic026063v
- Scopus: eid_2-s2.0-0038674726
- PMID: 12716195
- WOS: WOS:000182650400029
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Synthesis, characterization, and theoretical studies of group 4 amido hydrotris(pyrazolyl)borate complexes
Title | Synthesis, characterization, and theoretical studies of group 4 amido hydrotris(pyrazolyl)borate complexes |
---|---|
Authors | |
Issue Date | 2003 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic |
Citation | Inorganic Chemistry, 2003, v. 42 n. 9, p. 3008-3015 How to Cite? |
Abstract | Titanium and zirconium amido complexes containing a hydrotris(pyrazolyl)borate (Tp) or hydrotris(3,5-dimethylpyrazolyl)borate (Tp*) ligand TpM(NMe2)3 (M = Ti, 1; M = Zr, 2) and Tp*M(NMe2)3 (M = Ti, 3; M = Zr, 4) were prepared by the reactions of M(NMe2)3Cl (M = Ti, Zr) with sodium hydridotris(pyrazol-1-yl)borate and potassium hydridotris(3,5-dimethylpyrazol-1-yl)borate, respectively. The structures of 1, 2, and 4·CH2Cl2 were determined by X-ray diffraction and show octahedral coordination geometry around the metal centers. Density functional theory calculations at the B3PW91 level were performed to understand the orientations and the rotational behavior of amido ligands in these metal complexes. |
Persistent Identifier | http://hdl.handle.net/10722/167803 |
ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 0.928 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Cai, H | en_US |
dc.contributor.author | Lam, WH | en_US |
dc.contributor.author | Yu, X | en_US |
dc.contributor.author | Liu, X | en_US |
dc.contributor.author | Wu, ZZ | en_US |
dc.contributor.author | Chen, T | en_US |
dc.contributor.author | Lin, Z | en_US |
dc.contributor.author | Chen, XT | en_US |
dc.contributor.author | You, XZ | en_US |
dc.contributor.author | Xue, Z | en_US |
dc.date.accessioned | 2012-10-08T03:11:50Z | - |
dc.date.available | 2012-10-08T03:11:50Z | - |
dc.date.issued | 2003 | en_US |
dc.identifier.citation | Inorganic Chemistry, 2003, v. 42 n. 9, p. 3008-3015 | en_US |
dc.identifier.issn | 0020-1669 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167803 | - |
dc.description.abstract | Titanium and zirconium amido complexes containing a hydrotris(pyrazolyl)borate (Tp) or hydrotris(3,5-dimethylpyrazolyl)borate (Tp*) ligand TpM(NMe2)3 (M = Ti, 1; M = Zr, 2) and Tp*M(NMe2)3 (M = Ti, 3; M = Zr, 4) were prepared by the reactions of M(NMe2)3Cl (M = Ti, Zr) with sodium hydridotris(pyrazol-1-yl)borate and potassium hydridotris(3,5-dimethylpyrazol-1-yl)borate, respectively. The structures of 1, 2, and 4·CH2Cl2 were determined by X-ray diffraction and show octahedral coordination geometry around the metal centers. Density functional theory calculations at the B3PW91 level were performed to understand the orientations and the rotational behavior of amido ligands in these metal complexes. | en_US |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | en_US |
dc.relation.ispartof | Inorganic Chemistry | en_US |
dc.title | Synthesis, characterization, and theoretical studies of group 4 amido hydrotris(pyrazolyl)borate complexes | en_US |
dc.type | Article | en_US |
dc.identifier.email | Lam, WH:chsue@hku.hk | en_US |
dc.identifier.authority | Lam, WH=rp00719 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/ic026063v | en_US |
dc.identifier.pmid | 12716195 | - |
dc.identifier.scopus | eid_2-s2.0-0038674726 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0038674726&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 42 | en_US |
dc.identifier.issue | 9 | en_US |
dc.identifier.spage | 3008 | en_US |
dc.identifier.epage | 3015 | en_US |
dc.identifier.isi | WOS:000182650400029 | - |
dc.publisher.place | United States | en_US |
dc.identifier.scopusauthorid | Cai, H=7202853408 | en_US |
dc.identifier.scopusauthorid | Lam, WH=26642862800 | en_US |
dc.identifier.scopusauthorid | Yu, X=7404110746 | en_US |
dc.identifier.scopusauthorid | Liu, X=7409286468 | en_US |
dc.identifier.scopusauthorid | Wu, ZZ=7501411157 | en_US |
dc.identifier.scopusauthorid | Chen, T=7405542559 | en_US |
dc.identifier.scopusauthorid | Lin, Z=7404230177 | en_US |
dc.identifier.scopusauthorid | Chen, XT=15031954600 | en_US |
dc.identifier.scopusauthorid | You, XZ=36072101800 | en_US |
dc.identifier.scopusauthorid | Xue, Z=7203058536 | en_US |
dc.identifier.issnl | 0020-1669 | - |