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Article: Observation of intramolecular C-H⋯F-C contacts in non-metallocene polyolefin catalysts: Model for weak attractive interactions between polymer chain and noninnocent ligand

TitleObservation of intramolecular C-H⋯F-C contacts in non-metallocene polyolefin catalysts: Model for weak attractive interactions between polymer chain and noninnocent ligand
Authors
KeywordsFluorine
Hydrogen bonds
Polymerization
Through-space interactions
Zirconium
Issue Date2003
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie - International Edition, 2003, v. 42 n. 14, p. 1628-1632 How to Cite?
AbstractAttracting attention! The existence of attractive interactions between a functionalized ancillary ligand and a growing alkyl chain is a highly novel concept in olefin polymerization reactions (see scheme). Such interactions must be very weak so that the chain-propagation process is not perturbed, and "controversial" hydrogen bonds with strong dispersive character, such as CH⋯FC, are therefore ideal in this role (see scheme).
Persistent Identifierhttp://hdl.handle.net/10722/167780
ISSN
2015 Impact Factor: 11.709
2015 SCImago Journal Rankings: 6.229
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorKui, SCFen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorChan, MCWen_HK
dc.date.accessioned2012-10-08T03:11:28Z-
dc.date.available2012-10-08T03:11:28Z-
dc.date.issued2003en_HK
dc.identifier.citationAngewandte Chemie - International Edition, 2003, v. 42 n. 14, p. 1628-1632en_HK
dc.identifier.issn1433-7851en_HK
dc.identifier.urihttp://hdl.handle.net/10722/167780-
dc.description.abstractAttracting attention! The existence of attractive interactions between a functionalized ancillary ligand and a growing alkyl chain is a highly novel concept in olefin polymerization reactions (see scheme). Such interactions must be very weak so that the chain-propagation process is not perturbed, and "controversial" hydrogen bonds with strong dispersive character, such as CH⋯FC, are therefore ideal in this role (see scheme).en_HK
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_HK
dc.relation.ispartofAngewandte Chemie - International Editionen_HK
dc.subjectFluorineen_HK
dc.subjectHydrogen bondsen_HK
dc.subjectPolymerizationen_HK
dc.subjectThrough-space interactionsen_HK
dc.subjectZirconiumen_HK
dc.titleObservation of intramolecular C-H⋯F-C contacts in non-metallocene polyolefin catalysts: Model for weak attractive interactions between polymer chain and noninnocent liganden_HK
dc.typeArticleen_HK
dc.identifier.emailKui, SCF: stevenku@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.authorityKui, SCF=rp00715en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/anie.200219832en_HK
dc.identifier.pmid12698461-
dc.identifier.scopuseid_2-s2.0-0037432907en_HK
dc.identifier.hkuros93656-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037432907&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume42en_HK
dc.identifier.issue14en_HK
dc.identifier.spage1628en_HK
dc.identifier.epage1632en_HK
dc.identifier.isiWOS:000182496200012-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridKui, SCF=6506763660en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridChan, MCW=7402598116en_HK

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