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- Publisher Website: 10.1002/anie.200390159
- Scopus: eid_2-s2.0-0037415857
- PMID: 12569488
- WOS: WOS:000181379500011
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Article: [{N(PPh3)2}2{Os18 Pd3(μ6-C)2(CO)42}]: An osmium-palladium mixed-metal highnuclearity carbonyl cluster
Title | [{N(PPh3)2}2{Os18 Pd3(μ6-C)2(CO)42}]: An osmium-palladium mixed-metal highnuclearity carbonyl cluster |
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Authors | |
Keywords | Cluster compounds Electrochemistry Osmium Palladium Redox chemistry |
Issue Date | 2003 |
Publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home |
Citation | Angewandte Chemie - International Edition, 2003, v. 42 n. 5, p. 553-555 How to Cite? |
Abstract | Palladium-filled sandwiches: The reaction between the [Os10(μ6-C)(CO)24]2- ion and [Pd(NCMe)4](BF4)2 yields the osmiumpalladium mixed-metal cluster, [{N(PPh3)2}2{Os18 Pd3(μ6-C)2(CO)42}], which has the highest nuclearity known for such clusters, and has been shown by single-crystal X-ray analysis to be a "metal sandwich" with two Os9 units connected by a triangular Pd3 subcluster (see picture); five reversible cathodic waves have been observed through cyclic voltammetry. |
Persistent Identifier | http://hdl.handle.net/10722/167776 |
ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yung, KF | en_HK |
dc.contributor.author | Wong, WT | en_HK |
dc.date.accessioned | 2012-10-08T03:11:25Z | - |
dc.date.available | 2012-10-08T03:11:25Z | - |
dc.date.issued | 2003 | en_HK |
dc.identifier.citation | Angewandte Chemie - International Edition, 2003, v. 42 n. 5, p. 553-555 | en_HK |
dc.identifier.issn | 1433-7851 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/167776 | - |
dc.description.abstract | Palladium-filled sandwiches: The reaction between the [Os10(μ6-C)(CO)24]2- ion and [Pd(NCMe)4](BF4)2 yields the osmiumpalladium mixed-metal cluster, [{N(PPh3)2}2{Os18 Pd3(μ6-C)2(CO)42}], which has the highest nuclearity known for such clusters, and has been shown by single-crystal X-ray analysis to be a "metal sandwich" with two Os9 units connected by a triangular Pd3 subcluster (see picture); five reversible cathodic waves have been observed through cyclic voltammetry. | en_HK |
dc.language | eng | en_US |
dc.publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home | en_HK |
dc.relation.ispartof | Angewandte Chemie - International Edition | en_HK |
dc.subject | Cluster compounds | en_HK |
dc.subject | Electrochemistry | en_HK |
dc.subject | Osmium | en_HK |
dc.subject | Palladium | en_HK |
dc.subject | Redox chemistry | en_HK |
dc.title | [{N(PPh3)2}2{Os18 Pd3(μ6-C)2(CO)42}]: An osmium-palladium mixed-metal highnuclearity carbonyl cluster | en_HK |
dc.type | Article | en_HK |
dc.identifier.email | Yung, KF: kfyung@hkucc.hku.hk | en_HK |
dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
dc.identifier.authority | Yung, KF=rp00837 | en_HK |
dc.identifier.authority | Wong, WT=rp00811 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1002/anie.200390159 | en_HK |
dc.identifier.pmid | 12569488 | - |
dc.identifier.scopus | eid_2-s2.0-0037415857 | en_HK |
dc.identifier.hkuros | 76339 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0037415857&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 42 | en_HK |
dc.identifier.issue | 5 | en_HK |
dc.identifier.spage | 553 | en_HK |
dc.identifier.epage | 555 | en_HK |
dc.identifier.isi | WOS:000181379500011 | - |
dc.publisher.place | Germany | en_HK |
dc.identifier.scopusauthorid | Yung, KF=7006849172 | en_HK |
dc.identifier.scopusauthorid | Wong, WT=7403973084 | en_HK |
dc.identifier.issnl | 1433-7851 | - |