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Article: [{N(PPh3)2}2{Os18 Pd3(μ6-C)2(CO)42}]: An osmium-palladium mixed-metal highnuclearity carbonyl cluster

Title[{N(PPh3)2}2{Os18 Pd3(μ6-C)2(CO)42}]: An osmium-palladium mixed-metal highnuclearity carbonyl cluster
Authors
KeywordsCluster compounds
Electrochemistry
Osmium
Palladium
Redox chemistry
Issue Date2003
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie - International Edition, 2003, v. 42 n. 5, p. 553-555 How to Cite?
AbstractPalladium-filled sandwiches: The reaction between the [Os10(μ6-C)(CO)24]2- ion and [Pd(NCMe)4](BF4)2 yields the osmiumpalladium mixed-metal cluster, [{N(PPh3)2}2{Os18 Pd3(μ6-C)2(CO)42}], which has the highest nuclearity known for such clusters, and has been shown by single-crystal X-ray analysis to be a "metal sandwich" with two Os9 units connected by a triangular Pd3 subcluster (see picture); five reversible cathodic waves have been observed through cyclic voltammetry.
Persistent Identifierhttp://hdl.handle.net/10722/167776
ISSN
2015 Impact Factor: 11.709
2015 SCImago Journal Rankings: 6.229
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYung, KFen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2012-10-08T03:11:25Z-
dc.date.available2012-10-08T03:11:25Z-
dc.date.issued2003en_HK
dc.identifier.citationAngewandte Chemie - International Edition, 2003, v. 42 n. 5, p. 553-555en_HK
dc.identifier.issn1433-7851en_HK
dc.identifier.urihttp://hdl.handle.net/10722/167776-
dc.description.abstractPalladium-filled sandwiches: The reaction between the [Os10(μ6-C)(CO)24]2- ion and [Pd(NCMe)4](BF4)2 yields the osmiumpalladium mixed-metal cluster, [{N(PPh3)2}2{Os18 Pd3(μ6-C)2(CO)42}], which has the highest nuclearity known for such clusters, and has been shown by single-crystal X-ray analysis to be a "metal sandwich" with two Os9 units connected by a triangular Pd3 subcluster (see picture); five reversible cathodic waves have been observed through cyclic voltammetry.en_HK
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_HK
dc.relation.ispartofAngewandte Chemie - International Editionen_HK
dc.subjectCluster compoundsen_HK
dc.subjectElectrochemistryen_HK
dc.subjectOsmiumen_HK
dc.subjectPalladiumen_HK
dc.subjectRedox chemistryen_HK
dc.title[{N(PPh3)2}2{Os18 Pd3(μ6-C)2(CO)42}]: An osmium-palladium mixed-metal highnuclearity carbonyl clusteren_HK
dc.typeArticleen_HK
dc.identifier.emailYung, KF: kfyung@hkucc.hku.hken_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityYung, KF=rp00837en_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/anie.200390159en_HK
dc.identifier.pmid12569488-
dc.identifier.scopuseid_2-s2.0-0037415857en_HK
dc.identifier.hkuros76339-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037415857&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume42en_HK
dc.identifier.issue5en_HK
dc.identifier.spage553en_HK
dc.identifier.epage555en_HK
dc.identifier.isiWOS:000181379500011-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridYung, KF=7006849172en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK

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