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Article: Syntheses, photophysics, and photochemistry of trinuclear copper(I) thiolate and hexanuclear copper(I) selenolate complexes: X-ray crystal structures of [Cu6(μ3-dppm) 4(μ3-SePh)4](BF4)2 and [Cu6{μ-(Ph2P)2NH}4(μ3-SePh)4](BF4)2

TitleSyntheses, photophysics, and photochemistry of trinuclear copper(I) thiolate and hexanuclear copper(I) selenolate complexes: X-ray crystal structures of [Cu6(μ3-dppm) 4(μ3-SePh)4](BF4)2 and [Cu6{μ-(Ph2P)2NH}4(μ3-SePh)4](BF4)2
Authors
Issue Date2001
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2001, v. 40 n. 14, p. 3435-3442 How to Cite?
AbstractA series of trinuclear copper(I) thiolate complexes, [Cu 3(μ-dppm) 3(μ 3-SR) 2] BF 4 (R = C 6H 4Cl-4, C 6H 4CH 3-4, C 6H 4OCH 3-4, C 6H 4(OCH 3) 2-3,4, C 6H 4-benzo-15-crown-5, or ′Bu), [Cu 3(μ-dppm) 3(μ 3-S′Bu)] (BF 4) 2, and [Cu 3(μ-dppm) 3(μ 3-SR) (μ 3-Cl)]BF 4 (R = C 6H 4CH 3-4, C 6H 4′Bu-4, or C 6H 4(CH 3) 3-2,4,6) and two hexanuclear copper(I) selenolate complexes, [Cu 6(μ-PP) 4(μ 3-SePh) 4](BF 4) 2 (PP = dppm, (Ph 2P) 2NH), have been synthesized, and their photophysical properties have been studied. The X-ray crystal structures of both copper(I) selenolate complexes have been determined. These complexes have been shown to exhibit long-lived low-energy emission in solution, attributed to an excited state of predominantly ligand-to-metal charge-transfer [chalcogenolate to copper(I)] origin.
Persistent Identifierhttp://hdl.handle.net/10722/167695
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorLam, CHen_US
dc.contributor.authorFung, KMen_US
dc.contributor.authorCheung, KKen_US
dc.date.accessioned2012-10-08T03:10:08Z-
dc.date.available2012-10-08T03:10:08Z-
dc.date.issued2001en_US
dc.identifier.citationInorganic Chemistry, 2001, v. 40 n. 14, p. 3435-3442en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/10722/167695-
dc.description.abstractA series of trinuclear copper(I) thiolate complexes, [Cu 3(μ-dppm) 3(μ 3-SR) 2] BF 4 (R = C 6H 4Cl-4, C 6H 4CH 3-4, C 6H 4OCH 3-4, C 6H 4(OCH 3) 2-3,4, C 6H 4-benzo-15-crown-5, or ′Bu), [Cu 3(μ-dppm) 3(μ 3-S′Bu)] (BF 4) 2, and [Cu 3(μ-dppm) 3(μ 3-SR) (μ 3-Cl)]BF 4 (R = C 6H 4CH 3-4, C 6H 4′Bu-4, or C 6H 4(CH 3) 3-2,4,6) and two hexanuclear copper(I) selenolate complexes, [Cu 6(μ-PP) 4(μ 3-SePh) 4](BF 4) 2 (PP = dppm, (Ph 2P) 2NH), have been synthesized, and their photophysical properties have been studied. The X-ray crystal structures of both copper(I) selenolate complexes have been determined. These complexes have been shown to exhibit long-lived low-energy emission in solution, attributed to an excited state of predominantly ligand-to-metal charge-transfer [chalcogenolate to copper(I)] origin.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_US
dc.relation.ispartofInorganic Chemistryen_US
dc.titleSyntheses, photophysics, and photochemistry of trinuclear copper(I) thiolate and hexanuclear copper(I) selenolate complexes: X-ray crystal structures of [Cu6(μ3-dppm) 4(μ3-SePh)4](BF4)2 and [Cu6{μ-(Ph2P)2NH}4(μ3-SePh)4](BF4)2en_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ic0012322en_US
dc.identifier.pmid11421689-
dc.identifier.scopuseid_2-s2.0-0035796180en_US
dc.identifier.hkuros69063-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0035796180&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume40en_US
dc.identifier.issue14en_US
dc.identifier.spage3435en_US
dc.identifier.epage3442en_US
dc.identifier.isiWOS:000169550700026-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridLam, CH=24525955200en_US
dc.identifier.scopusauthoridFung, KM=37161213100en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US

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