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Article: Syntheses, crystal structures and magnetic properties of two honeycomb-layered bimetallic assemblies, K2[NiII(cyclam*)]3[FeII (CN)6]2 · 12H2O and [NiII(cyclam)]3[FeIII (CN)6]2 · 16H2O

TitleSyntheses, crystal structures and magnetic properties of two honeycomb-layered bimetallic assemblies, K2[NiII(cyclam*)]3[FeII (CN)6]2 · 12H2O and [NiII(cyclam)]3[FeIII (CN)6]2 · 16H2O
Authors
Issue Date2001
PublisherSpringer Verlag Dordrecht. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=0340-4285
Citation
Transition Metal Chemistry, 2001, v. 26 n. 3, p. 345-350 How to Cite?
AbstractTwo bimetallic assemblies, K2[NiII(cyclam)]3[FeII (CN)6]2 · 12H2O (1) and [NiII(cyclam)]3[FeIII (CN)6]2 · 16H2O (2) (cyclam = 1,4,8,11-tetraazacyclotetradecane), were obtained by reaction of K4[Fe(CN)6] and [Ni(cyclam)](ClO4)2 in aqueous media at different temperatures. Their crystals were structurally determined and magnetic properties were studied. Both of the compounds have honeycomb-layered structures, which are formed by Fe6Ni6 units linked through the cyanide bridges. Structure (1) consists of polyanions containing NiII-N≡C-FeII linkages and K+ cations, while structure (2) is a two-dimensional neutral layer containing NiII-N≡C-FeIII linkages. The magnetic properties of (1) and (2) have been investigated in the 5-300 K range. Compound (1) exhibits a weak antiferromagnetic interaction with Weiss constant Θ = -0.35 K; compound (2) shows ferromagnetic intralayer and antiferromagnetic interlayer interactions.
Persistent Identifierhttp://hdl.handle.net/10722/167688
ISSN
2015 Impact Factor: 1.465
2015 SCImago Journal Rankings: 0.398
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorShen, Zen_US
dc.contributor.authorZuo, JLen_US
dc.contributor.authorShi, FNen_US
dc.contributor.authorXu, Yen_US
dc.contributor.authorSong, Yen_US
dc.contributor.authorYou, XZen_US
dc.contributor.authorRaj, SSSen_US
dc.contributor.authorFun, HKen_US
dc.contributor.authorZhou, ZYen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:10:03Z-
dc.date.available2012-10-08T03:10:03Z-
dc.date.issued2001en_US
dc.identifier.citationTransition Metal Chemistry, 2001, v. 26 n. 3, p. 345-350en_US
dc.identifier.issn0340-4285en_US
dc.identifier.urihttp://hdl.handle.net/10722/167688-
dc.description.abstractTwo bimetallic assemblies, K2[NiII(cyclam)]3[FeII (CN)6]2 · 12H2O (1) and [NiII(cyclam)]3[FeIII (CN)6]2 · 16H2O (2) (cyclam = 1,4,8,11-tetraazacyclotetradecane), were obtained by reaction of K4[Fe(CN)6] and [Ni(cyclam)](ClO4)2 in aqueous media at different temperatures. Their crystals were structurally determined and magnetic properties were studied. Both of the compounds have honeycomb-layered structures, which are formed by Fe6Ni6 units linked through the cyanide bridges. Structure (1) consists of polyanions containing NiII-N≡C-FeII linkages and K+ cations, while structure (2) is a two-dimensional neutral layer containing NiII-N≡C-FeIII linkages. The magnetic properties of (1) and (2) have been investigated in the 5-300 K range. Compound (1) exhibits a weak antiferromagnetic interaction with Weiss constant Θ = -0.35 K; compound (2) shows ferromagnetic intralayer and antiferromagnetic interlayer interactions.en_US
dc.languageengen_US
dc.publisherSpringer Verlag Dordrecht. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=0340-4285en_US
dc.relation.ispartofTransition Metal Chemistryen_US
dc.titleSyntheses, crystal structures and magnetic properties of two honeycomb-layered bimetallic assemblies, K2[NiII(cyclam*)]3[FeII (CN)6]2 · 12H2O and [NiII(cyclam)]3[FeIII (CN)6]2 · 16H2Oen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1023/A:1007109130037en_US
dc.identifier.scopuseid_2-s2.0-0035371998en_US
dc.identifier.hkuros64713-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0035371998&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume26en_US
dc.identifier.issue3en_US
dc.identifier.spage345en_US
dc.identifier.epage350en_US
dc.identifier.isiWOS:000167436200019-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridShen, Z=13606179000en_US
dc.identifier.scopusauthoridZuo, JL=7202871908en_US
dc.identifier.scopusauthoridShi, FN=8092587000en_US
dc.identifier.scopusauthoridXu, Y=7406447917en_US
dc.identifier.scopusauthoridSong, Y=7404920898en_US
dc.identifier.scopusauthoridYou, XZ=36072101800en_US
dc.identifier.scopusauthoridRaj, SSS=7102810497en_US
dc.identifier.scopusauthoridFun, HK=34975048300en_US
dc.identifier.scopusauthoridZhou, ZY=7406096262en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US

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